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Working Guide to Vapor-Liquid Phase Equilibria Calculations offers a practical guide for calculations of vapor-phase equilibria. The book begins by introducing basic concepts such as vapor pressure, vapor pressure charts, equilibrium ratios, and flash calculations. It then presents methods for predicting the equilibrium ratios of hydrocarbon mixtures: Wilson's correlation, Standing's correlation, convergence pressure method, and Whitson and Torp correlation. The book describes techniques to determine equilibrium ratios of the plus fraction, including Campbell's method, Winn's method, and Katz's method. The remaining chapters cover the solution of phase equilibrium problems in reservoir and process engineering; developments in the field of empirical cubic equations of state (EOS) and their applications in petroleum engineering; and the splitting of the plus fraction for EOS calculations. - Includes explanations of formulas - Step by step calculations - Provides examples and solutions
The last three chapters of this book deal with application of methods presented in previous chapters to estimate various thermodynamic, physical, and transport properties of petroleum fractions. In this chapter, various methods for prediction of physical and thermodynamic properties of pure hydrocarbons and their mixtures, petroleum fractions, crude oils, natural gases, and reservoir fluids are presented. As it was discussed in Chapters 5 and 6, properties of gases may be estimated more accurately than properties of liquids. Theoretical methods of Chapters 5 and 6 for estimation of thermophysical properties generally can be applied to both liquids and gases; however, more accurate properties can be predicted through empirical correlations particularly developed for liquids. When these correlations are developed with some theoretical basis, they are more accurate and have wider range of applications. In this chapter some of these semitheoretical correlations are presented. Methods presented in Chapters 5 and 6 can be used to estimate properties such as density, enthalpy, heat capacity, heat of vaporization, and vapor pressure. Characterization methods of Chapters 2-4 are used to determine the input parameters needed for various predictive methods. One important part of this chapter is prediction of vapor pressure that is needed for vapor-liquid equilibrium calculations of Chapter 9.
A timely treatment of distillationcombining steady-state designand dynamic controllability As the world continues to seek new sources of energy, the distillation process remains one of the most important separation methods in the chemical, petroleum, and energy industries. And as new renewable sources of energy and chemical feedstocks become more universally utilized, the issues of distillation design and control will remain vital to a future sustainable lifestyle. Distillation Design and Control Using Aspen Simulation introduces the current status and future implications of this vital technology from the dual perspectives of steady-state design and dynamics. Where traditional design texts have focused mainly on the steady-state economic aspects of distillation design, William Luyben also addresses such issues as dynamic performance in the face of disturbances. Utilizing the commercial simulators Aspen Plus and Aspen Dynamics, the text guides future and practicing chemical engineers first in the development of optimal steady-state designs of distillation systems, and then in the development of effective control structures. Unique features of the text include: * In-depth coverage of the dynamics of column design to help develop effective control structures for distillation columns * Development of rigorous simulations of single distillation columns and sequences of columns * Coverage of design and control of petroleum fractionators Encompassing nearly four decades of research and practical developments in this dynamic field, the text represents an important reference for both students and experienced engineers faced with distillation problems.
This new edition of the Standard Handbook of Petroleum and Natural Gas Engineering provides you with the best, state-of-the-art coverage for every aspect of petroleum and natural gas engineering. With thousands of illustrations and 1,600 information-packed pages, this text is a handy and valuable reference. Written by over a dozen leading industry experts and academics, the Standard Handbook of Petroleum and Natural Gas Engineering provides the best, most comprehensive source of petroleum engineering information available. Now in an easy-to-use single volume format, this classic is one of the true "must haves" in any petroleum or natural gas engineer's library. - A classic for the oil and gas industry for over 65 years! - A comprehensive source for the newest developments, advances, and procedures in the petrochemical industry, covering everything from drilling and production to the economics of the oil patch - Everything you need - all the facts, data, equipment, performance, and principles of petroleum engineering, information not found anywhere else - A desktop reference for all kinds of calculations, tables, and equations that engineers need on the rig or in the office - A time and money saver on procedural and equipment alternatives, application techniques, and new approaches to problems
Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs delivers information on the role of PVT (pressure-volume-temperature) tests/data in various aspects, in particular reserve estimation, reservoir modeling, flow assurance, and enhanced oil recovery for both conventional and unconventional reservoirs. This must-have reference also prepares engineers on the importance of PVT tests, how to evaluate the data, develop an effective management plan for flow assurance, and gain perspective of flow characterization, with a particular focus on shale oil, shale gas, gas hydrates, and tight oil making. This book is a critical resource for today's reservoir engineer, helping them effectively manage and maximize a company's oil and gas reservoir assets. - Provides tactics on reservoir phase behavior and dynamics with new information on shale oil and gas hydrates - Helps readers Improve on the effect of salt concentration and application to C02-Acid Gas Disposal with content on water-hydrocarbon systems - Provides practical experience with PVT and tuning of EOS with additional online excel spreadsheet examples
Understanding the phase behavior of the various fluids present in a petroleum reservoir is essential for achieving optimal design and cost-effective operations in a petroleum processing plant. Taking advantage of the authors' experience in petroleum processing under challenging conditions, Phase Behavior of Petroleum Reservoir Fluids introdu
Building on the foundation set by its best-selling predecessors, the Groundwater Chemicals Desk Reference, Fourth Edition is both a broad, comprehensive desk reference and a guide for field research. This fourth edition contains more than 1,700 additional references, including adsorption data for more than 800 organic compounds and metals, s
This book addresses conventional and new predictive methodologies for estimating thermophysical properties of heavy petroleum fluids. For the unidentifiable fractions forming the fluids, chemical structures are calculated so that property estimation methods for mixtures of identifiable components are now available for such fractions. Chemical and multiphase equilibriums are of utmost importance; hence, the most significant ones involving heavy petroleum fluids are determined and illustrated using advanced equations of state such as sPC-SAFT and EoS/GE. The included phase equilibriums are phase envelopes of reservoir fluids, asymmetric mixtures between light solvents and bitumen including the presence of water and asphaltenes, among others. Besides, heavy petroleum fluids are analyzed from the Newtonian and non-Newtonian viewpoints, exploring their complex rheological behavior. Finally, complemented by online an Excel program for the thermodynamic characterization of unidentifiable petroleum fractions, this book is a useful resource for engineers and researchers in the petroleum industry and is also of interest to students studying chemical and petroleum engineering.