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TYPIX is a critical compilation of crystallographic data prepared by E. Parthé at the University of Geneva. It contains over 3200 compounds representative of the structure types found among inorganic compounds. This work contains condensed crystal chemical information about individual structure types as well as an extensive chapter on the crystal chemistry of particular structure families. The aim of the compilation is to clarify and classify published data for intermetallic and other inorganic structures (types found exclusively with halides or oxides are only included for a few special cases). It provides a tool for additional crystal chemical studies and the development of new materials.
The crystaLLographer usuaLLy needs, as a compLement to his experimentaL work, a smaLL structure data compiLation. My first, some 25 years ago, was a hand-written List of structure types containing space group, unit ceLL data and positionaL atom coordinates. Some 20 years ago, when computers had become a more easiLy accessibLe tooL, a smaLL computer test fiLe was created with the help of Dr. Jan Portheine, which was LabeLLed TYPIX. Assisted by Dr. KLaus Yvon I inserted in the fiLe the somewhat more than 200 inorganic crystaL structure types which were of interest for our research or with which I was famiLiar from my previous experimentaL crystaL structure studies on intermetalLics and tetrahedraL structure compounds. We soon stopped our work on TYPIX because we reaLized that simpLy storing structure data copied from the Literature did not serve our finaL objective. I had, for exampLe, Listed the structures of certain isotypic compounds as separate distinct structure types because, due to a different setting or description given in the originaL Literature, I missed their isotypism. In other cases, with good Luck, I found the isotypism and succeeded in correctLy transforming one description to the other but then did not know which of the different but equivaLent descriptions I shouLd retain in my data coLLection.
TYPIX is a critical compilation of crystallographic data prepared by E. Parthé at the University of Geneva. It contains over 3200 compounds representative of the structure types found among inorganic compounds. This work contains condensed crystal chemical information about individual structure types as well as an extensive chapter on the crystal chemistry of particular structure families. The aim of the compilation is to clarify and classify published data for intermetallic and other inorganic structures (types found exclusively with halides or oxides are only included for a few special cases). It provides a tool for additional crystal chemical studies and the development of new materials.
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973
The Special Edition 'Compounds with Polar Metallic Bonding' is a collection of eight original research reports presenting a broad variety of chemical systems, analytical methods, preparative pathways and theoretical descriptions of bonding situations, with the common aim of understanding the complex interplay of conduction electrons in intermetallic compounds that possess different types of dipoles. Coulombic dipoles introduced by electronegativity differences, electric or magnetic dipoles, polarity induced by symmetry reduction—all the possible facets of the term 'polarity'—can be observed in polar intermetallic phases and have their own and, in most cases, unique consequences on the physical and chemical behaviour. Elucidation of the structure–property relationships in compounds with polar metallic bonding is a modern and growing scientific field which combines solid state physics, preparative chemistry, metallurgy, modern analytic methods, crystallography, theoretical calculations of the electronic state and many more disciplines.