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The climate crisis that we are facing has galvanized the scientific and engineering communities and has led to the rapid development of new, efficient, environmentally-friendly devices. One of the most promising classes of materials for such applications are transition metal oxides. This is due to the fact that by controlling the oxygen content in these crystals by means of reduction and oxidation, the material properties can be tuned in a wide range of values. Thus, the transition metal oxides, such as the model crystals, titanium dioxide (TiO2) and strontium titanate (SrTiO3), find use in so many different fields, from photocatalysis, to energy storage (solid oxide fuel cells), information technology (memristors) and even healthcare (antibacterial films). This PhD thesis is an investigation into the effect of reduction and oxidation on the electronic properties of transition metal oxides. These processes were studied at nanoscale using a multitude of techniques to provide a thorough characterization of the changes that occur in the studied systems, i.e. TiO2 and SrTiO3. Moreover, the experiments were performed in both ultra high vacuum (UHV) conditions, as well as in oxygen, and even in atmospheric air, in order to comprehensively describe the changes in properties and to bring the results closer to applications. The goal of the dissertation was to study the evolution of the electronic properties, i.e. the work function and conductivity, due to redox processes, and to add to the general understanding of these processes. The experiments revealed that the electronic properties may be tuned. In case of using reduction by means of annealing in UHV, ion sputtering, and repeated ion sputtering and annealing, and for oxidation by exposure to oxygen or air at room temperature, and annealing in oxygen. Using this range of methods, the conductivity of TiO2 can be changed from semiconductive-like to metallic-like. Furthermore, the work function of the transition metal oxides can be tuned in a wide range, from 3.4 eV to 5.0 eV for TiO2, and from 2.9 eV to 4.5 eV for SrTiO3. This is associated with changes in surface and subsurface composition, crystallography, morphology and even with the growth of new oxide phases. The key findings in the field of surface science were the description of the changes in electronic properties due to repeated sputtering and annealing, and the presence of oxygen getter substances. These results are important, because they touch upon the very basis of every experiment in the field, i.e. the preparation of crystals. This work can be used to foster greater reproducibility of experiments, as well to provide new means of designing experiments. Another object of the study was the technologically interesting system of conductive nanowires on semiconductive SrTiO3 substrate. It was shown that the nanostructures are composed of a TiO core covered with a layer of Ti3O5. The evolution of the system, starting from atomically flat strontium titanate, through nanowire-covered substrate to a crystal with a layer of porous titanium suboxides was described. The effect of annealing in oxygen on wire-covered surface was been investigated.
Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution, Second Edition provides a compilation of tables that summarize relevant data recorded in the literature up to the end of 1980 for the ionization constants of inorganic acids and bases in aqueous solution. This book includes references to acidity functions for strong acids and bases, as well as details about the formation of polynuclear species. This text then explains the details of each column of the tables, wherein column 1 gives the name of the substance and the negative logarithm of the ionization constant and column 2 gives the temperature of measurements in degree Celsius. This book presents as well the method of measurement and the literature references that are listed alphabetically at the end of the tables. Chemists will find this book useful.
2D Functional Nanomaterials Outlines the latest developments in 2D heterojunction nanomaterials with energy conversion applications In 2D Functional Nanomaterials: Synthesis, Characterization, and Applications, Dr. Ganesh S. Kamble presents an authoritative overview of the most recent progress in the rational design and synthesis of 2D nanomaterials and their applications in semiconducting catalysts, biosensors, electrolysis, batteries, and solar cells. This interdisciplinary volume is a valuable resource for materials scientists, electrical engineers, nanoscientists, and solid-state physicists looking for up-to-date information on 2D heterojunction nanomaterials. The text summarizes the scientific contributions of international experts in the fabrication and application of 2D nanomaterials while discussing the importance and impact of 2D nanomaterials on future economic growth, novel manufacturing processes, and innovative products. Provides thorough coverage of graphene chemical derivatives synthesis and applications, including state-of-the-art developments and perspectives Describes 2D/2D graphene oxide-layered double hydroxide nanocomposites for immobilization of different radionuclides Covers 2D nanomaterials for biomedical applications and novel 2D nanomaterials for next-generation photodetectors Discusses applications of 2D nanomaterials for cancer therapy and recent trends ingraphene-latex nanocomposites Perfect for materials scientists, inorganic chemists, and electronics engineers, 2D Functional Nanomaterials: Synthesis, Characterization, and Applications is also an essential resource for solid-state physicists seeking accurate information on recent progress in two-dimensional heterojunction materials with energy conversion applications.
Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. - Presents case studies in each chapter that provide a focus on the industrial applications - Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource - Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications
This book describes the rapidly expanding field of two-dimensional (2D) transition metal carbides and nitrides (MXenes). It covers fundamental knowledge on synthesis, structure, and properties of these new materials, and a description of their processing, scale-up and emerging applications. The ways in which the quickly expanding family of MXenes can outperform other novel nanomaterials in a variety of applications, spanning from energy storage and conversion to electronics; from water science to transportation; and in defense and medical applications, are discussed in detail.
This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.
This book presents studies and discussions on anionic redox, which can be used to boost the capacities of cathode electrodes by providing extra electron transfer. This theoretically and practically significant book facilitates the implementation of anionic redox in electrodes for real-world use and accelerates the development of high-energy-density lithium-ion batteries. Lithium-ion batteries, as energy storage systems, are playing a more and more important role in powering modern society. However, their energy density is still limited by the low specific capacity of the cathode electrodes. Based on a profound understanding of band theory, the author has achieved considerable advances in tuning the redox process of lithium-rich electrodes to obtain enhanced electrochemical performance, identifying both the stability mechanism of anionic redox in lithium-rich cathode materials, and its activation mechanism in these electrode systems.
30% discount for members of The Mineralogical Society of Britain and Ireland This text summarises the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject, whilst highlighting most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review the fast developing field of mineral surfaces.
This book presents advanced synthesis techniques adopted to fabricate two-dimensional (2D) transition metal dichalcogenides (TMDs) materials with its enhanced properties towards their utilization in various applications such as, energy storage devices, photovoltaics, electrocatalysis, electronic devices, photocatalysts, sensing and biomedical applications. It provides detailed coverage on everything from the synthesis and properties to the applications and future prospects of research in 2D TMD nanomaterials.