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This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.
This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.
'Organometallics 2' examines the interaction of transition metals with unsaturated molecules. This topic has led to fundamental insights in the nature of the chemical bond which, in turn, has provided the basis of important present-day applications such as transition metal mediated synthesis or homogeneous and heterogeneous catalysis. This book outlines the chemistry and discusses the bonding in of some of the most important classes of organometallic compounds: the complexes of transition metals with Pi-ligands such as alkenes, alkynes, arenes, and cyclopentadienyl and allyl ligands.
The interaction of transition metals with unsaturated organic molecules has led to fundamental insights in the nature of the chemical bond which, in turn, have provided the basis of important present-day applications such as transition metal mediated synthesis or homogeneous and heterogeneous catalysis. This slim volume outlines the chemistry and discusses the bonding in some of the most important classes of organometallic compounds: the complexes of transition metals with [pi]-ligands such as alkenes, alkynes, arenes, and cyclopentadienyl and allyl ligands. The material covered follows on from Organometallics 1 which covers the chemistry of complexes with metal-carbon [sigma]-bonds. Synthetic and reactivity aspects of each class of compounds are illustrated with pertinent examples from the recent chemical literature. Highlighted excursions relate the fundamental chemistry to current synthetic or catalytic applications.
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.