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Excerpt from Transactions of the American Institute of Chemical Engineers, Vol. 13: Part II, 1920-21 Sulphur plays a more basic role in chemical industry than any other element. Either as elementary sulphur or combined as a metallic sulphide, it is the source of all sulphuric acid. Hence any changes in the sulphur industry Should be of great interest to the chemical engineering profession. America now dominates the sulphur industry and virtually all the American sulphur is produced by three companies - viz., the Union Sulphur Co., the Freeport Sulphur co. And the Texas Gulf Sulphur Co. These three companies produce not only virtually all the sulphur used in the United States but also a considerable surplus which is exported. The only other sulphur which normally enters the American market in quantity comes from Japan1 and its per centage calculated on the consumption of the United States is small and is not likely to increase. Rising costs of living have meant much higher wages in Japan, as well as in other parts Of the world; in fact, the percentage increase has probably been greatest in Japan, due not only to world conditions affecting all countries but to the rising standards of living of the Japanese. These facts, together with present higher transportation costs, will make it increasingly difficult for Japanese sulphur to compete on our Pacific Coast with the American product. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.
Excerpt from Transactions of the American Institute of Chemical Engineers, 1912, Vol. 5 If we first produce the pure crystalline phenol-alcohol, contain ing no excess of phenol, for instance crystalline saligenin or oxybenzyl-alcohol, and if we heat it gently, it will simply dehydrate and be transformed in a fusible mass which on cooling, solidifies to a resinous product - a fusible saliretin resin. The latter, submitted to the further action of heat, polymerizes and becomes an infusible, insoluble saliretin. This polymerization is facilitated, by the pres ence of small amounts of catalyzers, for instance, hydrochloric acid. The presence of an excess of phenol retards polymerization; hence the infusibility induced by polymerization will be retarded, and this, until some way or another the excess of phenol has been expelled. The infusible polymerized saliretin Obtained by heating phenol-alcohols containing no free phenol, or by heating fusible saliretin containing no free phenol, is insoluble in alcohol, but swells in acetone; it softens decidedly on heating, although it is no longer fusible. Longer heating does not harden it further, nor make it more resistive. It is harder, stronger, and more resistant to physical and chemical agents than the fusible saliretin from which it is derived; in this respect, it surpasses even more the soluble fusible resins described by Blumer, delaire, Baekeland, and called phenol resin by Aylesworth.17 But even after polymerization or hardening has been carried as far as possible, it is considerably less hard and less strong and less resistant to physical and chemical agents than the polymerization products resulting from the reaction of phenol on a sufficiently large proportion of formaldehyde or equivalent substances. In order to obtain the latter polymerization products of maxi mum strength. Hardness, and maximum resistivity. An adequately larger amount of methylen group must be introduced before or dur ing the act of polymerization. The introduction of this methylen group may be accomplished by at least three distinct methods. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.
This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.