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It is known that the Chapman-Jouguet theory of detonation is based on the assumption of an instantaneous and complete transformation of explosives into detonation products in the wave front. Therefore, one should not expect from the theory any interpretations of the detonation limits, such as shock initiation of det onation and kinetic instability and propagation (failure diameter). The Zeldovich-Von Neuman-Doring (ZND) theory of detonation appeared, in fact, as a response to the need for a theory capable of interpreting such limits, and the ZND detonation theory gave qualitative interpretations to the detonation limits. These interpretations were based essentially on the theoretical notion that the mechanism of explosives transformation at detonation is a combustion of a layer of finite thickness of shock-compressed explosive behind the wave shock front with the velocity of the front. However, some experimental findings turned out to be inconsistent with the the ory. A very small change of homogeneous (liquid) explosives detonation velocity with explosive charge diameter near the rather sizable failure diameter is one of the findings. The elucidation of the nature of this finding has led to the discovery of a new phenomenon. This phenomenon has come to be known as the breakdown (BD) of the explosive self-ignition behind the front of shock waves under the effect of rarefaction waves.
Combustion, Flames, and Explosions of Gases, Second Edition focuses on the processes, methodologies, and reactions involved in combustion phenomena. The publication first offers information on theoretical foundations, reaction between hydrogen and oxygen, and reaction between carbon monoxide and oxygen. Discussions focus on the fundamentals of reaction kinetics, elementary and complex reactions in gases, thermal reaction, and combined hydrogen-carbon monoxide-oxygen reaction. The text then elaborates on the reaction between hydrocarbons and oxygen and combustion waves in laminar flow. The manuscript tackles combustion waves in turbulent flow and air entrainment and burning of jets of fuel gases. Topics include effect of turbulence spectrum and turbulent wrinkling on combustion wave propagation; ignition of high-velocity streams by hot solid bodies; burners with primary air entrainment; and description of jet flames. The book then takes a look at detonation waves in gases; emission spectra, ionization, and electric-field effects in flames; and methods of flame photography and pressure recording. The publication is a valuable reference for readers interested in combustion phenomena.
This book introduces the detonation phenomenon in explosives. It is ideal for engineers and graduate students with a background in thermodynamics and fluid mechanics. The material is mostly qualitative, aiming to illustrate the physical aspects of the phenomenon. Classical idealized theories of detonation waves are presented first. These permit detonation speed, gas properties ahead of and behind the detonation wave, and the distribution of fluid properties within the detonation wave itself to be determined. Subsequent chapters describe in detail the real unstable structure of a detonation wave. One-, two-, and three-dimensional computer simulations are presented along with experimental results using various experimental techniques. The important effects of confinement and boundary conditions and their influence on the propagation of a detonation are also discussed. The final chapters cover the various ways detonation waves can be formed and provide a review of the outstanding problems and future directions in detonation research.
Combustion Theory delves deeper into the science of combustion than most other texts and gives insight into combustions from a molecular and a continuum point of view. The book presents derivations of the basic equations of combustion theory and contains appendices on the background of subjects of thermodynamics, chemical kinetics, fluid dynamics, and transport processes. Diffusion flames, reactions in flows with negligible transport and the theory of pre-mixed flames are treated, as are detonation phenomena, the combustion of solid propellents, and ignition, extinction, and flamibility pehnomena.
The book describes the science and technology of formulation and manufacturing of non-nitroglycerine explosives with ammonium nitrate as the main ingredient. Based on the author's industry experience of more than thirty years, it provides an unparalleled treatment of one of the commercially most important classes of explosives and therefore stimulates further research and development efforts in the field of explosives for civil applications.
The 24th International Symposium on Shock Waves (ISSW24) was held at the Beijing Friendship Hotel during July 11-16, 2004, in Beijing. It was a great pleasure for the Local Organizing Committee to organize the ISSW in China for the first time, because forty-seven years have passed since the First Shock Tube Symposium was held in 1957 at Albuquerque. The ISSW24 had to be postponed for one year because of the SARS outbreak in Beijing shortly before the Symposium was scheduled to be held in 2003, but it has achieved success due to the continuous support and kind understanding from all the delegates. It is very heart-warming to have had such an experience and I am very happy to have served as chairman for the Symposium. I would like to thank all for the contributions and help that they have given us over the past three years, without which we would not have had the Symposium. A total of 460 abstracts were submitted to the ISSW24. Each of the abstracts was evaluated by three members of the Scientific Review Committee and the decision on acceptance wasmade based on the reviewers' reports. 195oral papers,including 9plenary lectures, wereaccepted to be presented in three parallel sessions, and 135poster papers in three dedicated poster sessions. Topics discussed in these papers cover all aspects ofshock wave research.
This graduate-level textbook treats the basic chemistry of high energy materials - primary and secondary explosives, propellants, rocket fuel and pyrotechnics - and provides a review of new research developments. Applications in both military and civil fields are discussed. The book also offers new insights into "green" chemistry requirements and strategies for military applications. This work should be of interest to advanced students in chemistry, materials science and engineering, as well as all those working in defense technology.