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This book provides a detailed overview and comprehensive analysis of the main theoretical and experimental advances on free surface thin film and jet flows of soft matter. The book outlines the basic equations and boundary conditions and the derivation of low-dimensional models for the evolution of the free surface. At the experimental front, a variety of recent experimental developments is outlined and the link between theory and experiments is illustrated.
The properties of soft-matter thin films (e.g. liquid films, polymer coatings, Langmuir-Blodgett multilayers) nowadays play an important role in materials science. They are also very exciting with respect to fundamental questions: In thin films, liquids and polymers may be considered as trapped in a quasi-two-dimensional geometry. This confined geometry is expected to alter the properties and structures of these materials considerably. This volume is dedicated to the scattering of x-rays by soft-matter interfaces. X-ray scattering under grazing angles is the only tool to investigating these materials on atomic and mesoscopic length scales. A review of the field is presented with many examples.
Ch. 1. Block copolymer thin films / J.-Y. Wang, S. Park and T. P. Russell -- ch. 2. Equilibration of block copolymer films on chemically patterned surfaces / G. S. W. Craig, H. Kang and P. F. Nealey -- ch. 3. Structure formation and evolution in confined cylinder-forming block copolymers / G. J. A. Sevink and J. G. E. M. Fraaije -- ch. 4. Block copolymer lithography for magnetic device fabrication / J. Y. Cheng and C. A. Ross -- ch. 5. Hierarchical structuring of polymer nanoparticles by self-organization / M. Shimomura ... [et al.] -- ch. 6. Wrinkling polymers for surface structure control and functionality / E. P. Chan and A. J. Crosby -- ch. 7. Crystallization in polymer thin films: morphology and growth / R. M. Van Horn and S. Z. D. Cheng -- ch. 8. Friction at soft polymer surface / M. K. Chaudhury, K. Vorvolakos and D. Malotky -- ch. 9. Relationship between molecular architecture, large-strain mechanical response and adhesive performance of model, block copolymer-based pressure sensitive adhesives / C. Creton and K. R. Shull -- ch. 10. Stability and dewetting of thin liquid films / K. Jacobs, R. Seemann and S. Herminghaus -- ch. 11. Anomalous dynamics of polymer Films / O. K. C. Tsui.
In a liquid crystal watch, the molecules contained within a thin film of the screen are reorientated each second by extremely weak electrical signals. Here is a fine example of soft matter: molecular systems giving a strong response to a very weak command signal. They can be found almost everywhere. Soft magnetic materials used in transformers exhibit a strong magnetic moment under the action of a weak magnetic field. Take a completely different domain: gelatin, formed from col lagen fibres dissolved in hot water. When we cool below 37°C, gelation occurs, the chains joining up at various points to form a loose and highly deformable network. This is a natural example of soft matter. Going further, rather than consider a whole network, we could take a single chain of flexible polymer, such as polyoxyethylene [POE = (CH CH O)N, 2 2 5 where N rv 10 ], for example, in water. Such a chain is fragile and may break under flow. Even though hydrodynamic forces are very weak on the molecular scale, their cumulated effect may be significant. Think of a rope pulled from both ends by two groups of children. Even if each girl and boy cannot pull very hard, the rope can be broken when there are enough children pulling.
This book covers the experimental and theoretical understanding of surface and thin film processes. It presents a unique description of surface processes in adsorption and crystal growth, including bonding in metals and semiconductors. Emphasis is placed on the strong link between science and technology in the description of, and research for, new devices based on thin film and surface science. Practical experimental design, sample preparation and analytical techniques are covered, including detailed discussions of Auger electron spectroscopy and microscopy. Thermodynamic and kinetic models of structure are emphasised throughout. The book provides extensive leads into practical and research literature, as well as resources on the World Wide Web (see http://venables.asu.edu/book). Each chapter contains problems which aim to develop awareness of the subject and the methods used. Aimed as a graduate textbook, this book will also be useful as a sourcebook for graduate students, researchers and practitioners in physics, chemistry, materials science and engineering.
Roberto Piazza says: “Physics should be made simple enough to be amusing, but not so trivial as to spoil the fun.” This is exactly the approach of this book in making the science of ‘soft matter’ relevant to everyday life things such as the food we eat, the plastic we use, the concrete we build with, the cells we are made of.
This book is a treatise on the thermodynamic and dynamic properties of thin liquid films at solid surfaces and, in particular, their rupture instabilities. For the quantitative study of these phenomena, polymer thin films (sometimes referred to as “ultrathin”) have proven to be an invaluable experimental model system. What is it that makes thin film instabilities special and interesting? First, thin polymeric films have an important range of applications. An understanding of their instabilities is therefore of practical relevance for the design of such films. The first chapter of the book intends to give a snapshot of current applications, and an outlook on promising future ones. Second, thin liquid films are an interdisciplinary research topic, which leads to a fairly heterogeneous community working on the topic. It justifies attempting to write a text which gives a coherent presentation of the field which researchers across their specialized communities might be interested in. Finally, thin liquid films are an interesting laboratory for a theorist to confront a well-established theory, hydrodynamics, with its limits. Thin films are therefore a field in which a highly fruitful exchange and collaboration exists between experimentalists and theorists. The book stretches from the more concrete to more abstract levels of study: we roughly progress from applications via theory and experiment to rigorous mathematical theory. For an experimental scientist, the book should serve as a reference and guide to what is the current consensus of the theoretical underpinnings of the field of thin film dynamics. Controversial problems on which such a consensus has not yet been reached are clearly indicated in the text, as well as discussed in a final chapter. From a theoretical point of view, the field of dewetting has mainly been treated in a mathematically ‘light’ yet elegant fashion, often making use of scaling arguments. For the untrained researcher, this approach is not always easy to follow. The present book attempts to bridge between the ‘light’ and the ‘rigorous’, always with the ambition to enhance insight and understanding - and to not let go the elegance of the theory.
The study of "soft matter" materials with complex properties has raised a number of interesting problems in basic physics, biology, and materials science, all of which promise new and important technological applications. After a review of chemical bonds and phase transitions, the authors treat topics such as surface phenomena, stability of colloidal systems, structural properties of polymers, and topological defects. The monograph's emphasis on underlying physical principles offers a coherent treatment of the great variety of research in the field.
Thin films have an extremely broad range of applications from electronics and optics to new materials and devices. Collaborative and multidisciplinary efforts from physicists, materials scientists, engineers and others have established and advanced a field with key pillars constituting (i) the synthesis and processing of thin films, (ii) the understanding of physical properties in relation to the nanometer scale, (iii) the design and fabrication of nano-devices or devices with thin film materials as building blocks, and (iv) the design and construction of novel tools for characterization of thin films.Against the backdrop of the increasingly interdisciplinary field, this book sets off to inform the basics of thin film physics and thin film devices. Readers are systematically introduced to the synthesis, processing and application of thin films; they will also study the formation of thin films, their structure and defects, and their various properties — mechanical, electrical, semiconducting, magnetic, and superconducting. With a primary focus on inorganic thin film materials, the book also ventures on organic materials such as self-assembled monolayers and Langmuir-Blodgett films.This book will be effective as a teaching or reference material in the various disciplines, ranging from Materials Science and Engineering, Electronic Science and Engineering, Electronic Materials and Components, Semiconductor Physics and Devices, to Applied Physics and more. The original Chinese publication has been instrumental in this purpose across many Chinese universities and colleges.
Chemical Solution Synthesis for Materials Design and Thin Film Device Applications presents current research on wet chemical techniques for thin-film based devices. Sections cover the quality of thin films, types of common films used in devices, various thermodynamic properties, thin film patterning, device configuration and applications. As a whole, these topics create a roadmap for developing new materials and incorporating the results in device fabrication. This book is suitable for graduate, undergraduate, doctoral students, and researchers looking for quick guidance on material synthesis and device fabrication through wet chemical routes. Provides the different wet chemical routes for materials synthesis, along with the most relevant thin film structured materials for device applications Discusses patterning and solution processing of inorganic thin films, along with solvent-based processing techniques Includes an overview of key processes and methods in thin film synthesis, processing and device fabrication, such as nucleation, lithography and solution processing