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In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick’s laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion. Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories.
Bridging a gap in the literature, Professor Ericksen has drawn on his experience in research on solids to devise a series of lectures for graduates that introduce and illustrate uses of various important ideas with analysis which can be done using elementary mathematics. Simple strategies are discussed for thermoelastic bars and an ideal gas-solid mixture. Illustrative examples of thermodynamic stability theory include rudimentary analysis of cold-drawing in polymers, martensitic transformations in plates, instabilities in rubber balloons and sheets, peeling tapes, breaking bars, buckling of beams and instabilities produced by electromagnetic fields in liquid crystals. Non-equilibrium theory is illustrated by head conduction in rigid and deformable bars, including a fairly common way of using the Clausius-Duhem inequality to obtain thermodynamic restrictions on constitutive equations. Also covered is some elementary one-dimensional theory of shock waves and slower-moving phase boundaries. Finally, drawing on all these experiences, the last chapter treats general ideas in a more abstract way.
The main aim of this volume is to introduce and illustrate current practice in research on nonlinear phenomena encountered in solids. Strategies for designing experiments to determine equations of state are discussed, as are examples of thermodynamic stability theory.
Recent years have seen a growing interest in the field of thermodynamic properties of solids due to the development of advanced experimental and modeling tools. Predicting structural phase transitions and thermodynamic properties find important applications in condensed matter and materials science research, as well as in interdisciplinary research involving geophysics and Earth Sciences. The present edited book, with contributions from leading researchers around the world, is aimed to meet the need of academic and industrial researchers, graduate students and non-specialists working in these fields. The book covers various experimental and theoretical techniques relevant to the subject.
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of—and subsequent ability to assess and apply—principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change. Includes fully updated as well as new chapters on kinetic phase diagrams, thermokinetics in DTA experiments, and crystallization kinetics Discusses the influence of key derivatives such as thermostatics, thermodynamics, thermotics, and thermokinetics Helps readers understand and describe reaction kinetics in solids, both in terms of simplified descriptions of the reaction mechanism models and averaged descriptions using fractals
Integrates fundamental concepts with experimental data and practical applications, including worked examples and end-of-chapter problems.
This 1980 monograph develops from first principles the description of finite deformations of solids under stress and the forces acting, and also the expression of internal forces in terms of stress tensors. The important feature of the book is that elastic properties are discussed and developed consistently from classical thermodynamics. In other books, this point of view is acknowledged only by assuming the existence of an elastic energy function, thus restricting their range mainly to the problem of the spatial distribution of stresses and strains. Topics discussed as applications of the theory include thermal expansion, specific heats, stiffness and complicances, the effects of symmetry on thermodynamic properties, diffusion in a stressed solid, equilibrium in contact with a solution of the solid, phase stability, solid state phase transitions and twinning.