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This book is intended to be a comprehensive survey of irreversible phenomena in liquid metals. Experiments and special theoretical consid erations can be brought into a general scheme by means of the phenome nological theory of thermodynamics of irreversible processes. In this way well-investigated phenomena such as electrolysis in liquid alloys, and new fields of research such as isotopic separation in liquid metals by action of an electrical direct current, can be given the same theo retical foundation. The goal in this book is to deduce the theory of a special phenomenon as well as to describe experiments connected with the resulting effects. On the other hand no kinetic theory is given since to date no general kinetic theory exists for liquids as it does exist for gases. In general, kinetic models seem to agree with experiments only if the results of the measurements are known beforehand. In Chapter 1 the Onsager symmetry relations are deduced in general. Chapter 2 gives the general phenomenological theory of liquid metals. These two chapters serve as a foundation for the remaining chapters, where the general theory is applied to sO. me cases of special physical interest. The scalar phenomena of relaxation are given in Chapter 3 for the case of nuclear magnetic resonance. Vector phenomena are discussed in Chapters 4 -6. Chapter 7 deals with viscosity effects as examples of tensor effects.
Originally published in 1985, this textbook provides a thorough and comprehensive coverage of a wide range of topics in stoichiometry and thermodynamics with special emphasis on applications to metallurgical processes. This book will be welcomed as a text for courses in elementary and advanced thermodynamics and stoichiometry.
Thermodiffusion in Multicomponent Mixtures presents the computational approaches that are employed in the study of thermodiffusion in various types of mixtures, namely, hydrocarbons, polymers, water-alcohol, molten metals, and so forth. We present a detailed formalism of these methods that are based on non-equilibrium thermodynamics or algebraic correlations or principles of the artificial neural network. The book will serve as single complete reference to understand the theoretical derivations of thermodiffusion models and its application to different types of multi-component mixtures. An exhaustive discussion of these is used to give a complete perspective of the principles and the key factors that govern the thermodiffusion process.
The peaceful use of space flight systems for research and technological devel opments in the context of promoting European and international cooperation represents the essential motivation for the programmes of the European Space Agency (ESA). One of ESA's programmes is dedicated to microgravity research, which is now an established discipline in Europe, with a dedicated group of scientists participating. The Challenger disaster has resulted in a serious dis continuity of flight opportunities in the next few years but the forthcoming International Space Station, new launchers and reentry vehicles are expected to provide ample opportunities for microgravity research in the long term. Meanwhile parabolic aircraft flights, sounding rockets as well as the delayed Shuttle-dependent missions, Spacelab D-2, the IML-missions and EURECA I, will be employed to keep microgravity experimenters reasonably busy in the interim period. To prepare the ground for these activities, both regarding research and experiment facilities, an in-depth analysis of the state of the art is an essential requirement at this time. Such an analysis is presented in this volume. It ad dresses all of the topics that have been identified to be of relevance. Besides a presentation of the fundamental aspects justifying microgravity research, the results of experiments already performed are reviewed and recommendations for future activities are made. Close to fifty European scientists have cooper ated in the preparation of this volume and their dedicated and concerted effort is greatly appreciated.
In a microgravity experiment, the conditions prevalent in fluid phases can be substantially different from those on the ground and can be exploited to improve different processes. Fluid physics research in microgravity is important for the advancement of all microgravity scients: life, material, and engineering. Space flight provides a unique laboratory that allows scientists to improve their understanding of the behaviour of fluids in low gravity, allowing the investigation of phenomena and processes normally masked by the effects of gravity and thus difficult to study on Earth. Physics of Fluids in Microgravity provides a clear view of recent research and progress in the different fields of fluid research in space. The topics presented include bubles and drops dynamics, Maragoni flows, diffustion and thermodiffusion, solidfication,a nd crystal growth. The results obtained so far are, in some cases, to be confirmed by extensive research activities on the International Space station, where basic and applied microgravity experimentation will take place in the years to come.
These Proceedings contain invited lectures presented at the third Interna tional Conference on "Irreversible Processes and Dissipative Structures" in Kiihlungsborn (German Democratic Republic) in March, 1985. These con ferences, the first of which was held in Rostock in 1977 and the second in Berlin in 1982, are devoted to the study of irreversible processes far from thermal equilibrium and to the phenomena of selforganization. The meet ing in Kiihlungsborn brought together some 160 mathematicians, physicists, chemists and biologists from 10 countries, who are all interested in the inter disciplinary field of synergetics. The main topics of the conference were basic concepts of selforganization and evolution, such as entropy, instabilities, nucleation, dissipative struc tures, chaos and turbulence. The contributions cover methods from ther modynamics, the theory of dynamic systems, stochastic and statistic theory, the method of Green's functions, the fluctuation-dissipation theorem, etc. Several problems are studied in more detail, e.g., the kinetics of nucleation especially in finite systems, the dynamics of interfaces, reaction-diffusion sys tems, chemical and biochemical pattern formation and information process ing. Further, several contributions are devoted to the development of the concepts of chaos and turbulence. The editors hope that the contributions collected in this volume will pro vide some new information about the field of selforganization, which is in full development now.