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This state-of-the-art guide presents a systematic methodology for applying thermodynamics principles in the many areas of the hydrocarbon energy industry Thermodynamics and Applications in Hydrocarbon Energy Production lays out a unified view of classical thermodynamics and teaches how to effectively put those theories to work in fuel exploration, preparation, and refinement. Shale gas and oil development is a relatively new subject in petroleum engineering and is the main focus of the U.S. energy industry—this book addresses these important issues. The use of thermodynamics in reservoir, transportation system, surface facility, and refinery development is covered in full detail. Advanced chapters explain leading-edge techniques, including molecular simulation. High-quality illustrations and tables are featured throughout Each chapter includes examples, theory extensions, and problems Provides practical solutions to key engineering problems Written by a world-renowned petroleum reservoir engineering expert
Homogeneous closed systems - Heterogeneous closed systems - P-V-T data and correlations - Equations of state - Corresponding states methods - Pure component properties - Thermodynamic properties charts - Vapor-liquid equilibrium processes - Vapor-liquid equilibrium k-values and graphical correlations.
Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.
Written by an author with over 38 years of experience in the chemical and petrochemical process industry, this handbook will present an analysis of the process steps used to produce industrial hydrocarbons from various raw materials. It is the first book to offer a thorough analysis of external factors effecting production such as: cost, availability and environmental legislation. An A-Z list of raw materials and their properties are presented along with a commentary regarding their cost and availability. Specific processing operations described in the book include: distillation, thermal cracking and coking, catalytic methods, hydroprocesses, thermal and catalytic reforming, isomerization, alkylation processes, polymerization processes, solvent processes, water removal, fractionation and acid gas removal. - Flow diagrams and descriptions of more than 250 leading-edge process technologies - An analysis of chemical reactions and process steps that are required to produce chemicals from various raw materials - Properties, availability and environmental impact of various raw materials used in hydrocarbon processing
Paraffin waxes make up the majority of commercial waxes. Waxes are characterized by the carbon number, hardness, crystal shape, composition, and molecular weight. These characteristics determine the condition of separating the wax. Paraffin wax is widely used in different industries such as ink, paper, cosmetics, ceramics using powder injection molding and energy storage as phase change materials. Consumption of wax products has increased in the world; especially for food, pharmaceutical products, cosmetics, as well as specialty products. The increase of profitability of wax production will lie in the improvement of blending and modification techniques for macro and micro-crystalline waxes used as the base materials.
The precipitation and deposition of solids are a major challenge in the production of oil and gas. Flow assurance solids are formed because of unavoidable changes in temperature, pressure and composition of the oil-gas-water flowstream, from reservoir conditions to processing conditions. The advent of subsea production and the increased exploitation of heavy crudes have made flow assurance issues dominant in ensuring efficient and safe exploitation of hydrocarbon assets. Five troublesome flow assurance solids are described in the book: asphaltene, paraffin wax, natural gas hydrate, naphthenate and inorganic scale. These big-five solids are presented in stand-alone chapters. Each chapter is designed to be readable without clutter. Derivations of equations and descriptions of supporting details are given in several appendices. The book is intended for professional engineers and natural scientist working in E&P companies, engineering companies, service companies and specialized companies. An understanding of the big-five solids is required throughout the lifetime of oil and gas assets, from early development to abandonment. The technical, safety and environmental risks associated with deposition problems in near-wellbore formations, production tubing, wellhead equipment, flowlines and processing facilities, are relevant for decisions in the oil and gas industry and in outside regulatory and financial entities.
Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Using the principle that extracting energy from the environment always involves some type of impact on the environment, The Future of Energy discusses the sources, technologies, and tradeoffs involved in meeting the world's energy needs. A historical, scientific, and technical background set the stage for discussions on a wide range of energy sources, including conventional fossil fuels like oil, gas, and coal, as well as emerging renewable sources like solar, wind, geothermal, and biofuels. Readers will learn that there are no truly "green" energy sources—all energy usage involves some tradeoffs—and will understand these tradeoffs and other issues involved in using each energy source. - Each potential energy source includes discussions of tradeoffs in economics, environmental, and policy implications - Examples and cases of implementing each technology are included throughout the book - Technical discussions are supported with equations, graphs, and tables - Includes discussions of carbon capture and sequestration as emerging technologies to manage carbon dioxide emissions
Confined Fluid Phase Behavior and CO2 Sequestration in Shale Reservoirs delivers the calculation components to understand pore structure and absorption capacity involving unconventional reservoirs. Packed with experimental procedures, step-by-step instructions, and published data, the reference explains measurements for capillary pressure models, absorption behavior in double nano-pore systems, and the modeling of interfacial tension in C02/CH4/brine systems. Rounding out with conclusions and additional literature, this reference gives petroleum engineers and researchers the knowledge to maximize productivity in shale reservoirs. - Helps readers gain advanced understanding of methods of adsorption behavior in shale gas - Presents theories and calculations for measuring and computing by providing step-by-step instructions, including flash calculation for phase equilibrium - Includes advances in shale fluid behavior, along with well-structured experiments and flow charts
Although the focus of this textbook is on traditional thermodynamics topics, the book is concerned with introducing the thermal-fluid sciences as well. It is designed for the instructor to select topics and seamlessly combine them with material from other chapters. Pedagogical devices include: learning objectives, chapter overviews and summaries, historical perspectives, and numerous examples, questions, problems and lavish illustrations. Students are encouraged to use the National Institute of Science and Technology (NIST) online properties database.