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This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling-Benedict-Webb-Rubin equation of state was used. This report contains a brief description, flowchart, listing and required equations for each subroutine.
Thermophysical Properties of Individual Hydrocarbons of Petroleum and Natural Gases: Properties, Methods, and Low-Carbon Technologies is a go-to data source for engineers who need derive property data on everyday components. Providing more precise data improves existing oil and gas processing systems and creates opportunities for more sustainable operations and equipment, such as hydrogen and carbon capture. Covering modern equations of state, this source discusses detailed descriptions of experimental apparatus, methods of measurement, corrections and error estimates as well as results of previous experiments. Generalized predictive methods for calculating viscosity and thermal conductivity are also covered. Rounding out with property databases and lower-carbon technology advances, the book gives today’s engineers a detailed study of methods for more sustainable experimental research of thermophysical properties. Teaches approaches for the measurement and modeling of thermophysical properties for future sustainability growth, including hydrogen and carbon capture Provides exact property data of natural gas and their main components, including saturated properties Gives readers new knowledge in experimental measurement procedures and guidelines for calculating thermophysical properties, along with updates on applications
The simulation and optimization of processes assumes that the thermodynamic properties and phase equilibria of the mixtures concerned are well known. This knowledge is still based upon experimentation, but it is also the result of calculation methods based on the principles of thermodynamics that govern them, insure their coherence, and confer upon them a wide range of application. This text is concerned primarily with the description of these methods and their evolution. It devotes extensive space to fundamental concepts and places particular emphasis on the models that, although based on simplified concepts of the subject matter at the molecular level, have predictive character. Computational examples are used to explain the application of these concepts and models. Contents: 1. Principles. Thermodynamic functions. The ideal gas. 2. Properties of pure substances. 3. Predicting thermodynamic properties of pure substances. General principles. Corresponding states. Group contributions. 4. Equations of state. 5. Characterization of mixtures. 6. Mixtures: liquid-vapor equilibria. 7. Deviations from ideality in the liquid phase. 8. Application of equations of state to mixtures. Calculation of liquid-vapor equilibria under pressure. 9. Liquid-liquid and liquid-liquid-vapor equilibria. 10. Fluid-solid equilibria. Crystallization. Hydrates. 11. Polymer solutions and alloys. 12. Multicomponent mixtures. 13. Chemical reactions. Appendixes. Index. Bibliography.