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This book discusses the theory, general principles, and energy source conditions allowing for the emergence of life in planetary systems. The author examines the material conditions found in natural hydrothermal sites, the appropriate analogs of prebiotic environments on early Earth. He provides an overview of current laboratory experiments in prebiotic materials chemistry and substantiation of a new direction for the experiments in the origin of life field. Describes thermodynamic inversion and how it relates to the living cell; Examines the current direction of experiments on prebiotic materials chemistry; Introduces and substantiates necessary conditions for the emergence of life.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
A concise treatment of the fundamentals of thermodynamics is presented in this book. In particular, emphasis is placed on discussions of the second law, a unique feature of thermodynamics, which states the limitations of converting thermal energy into mechanical energy. The entropy function that permits the loss in the potential of a real thermodynamic process to be assessed, the maximum possible work in a process, and irreversibility and equilibrium are deduced from the law through physical and intuitive considerations. They are applicable in mitigating waste heat and are useful for solving energy, power, propulsion and climate-related issues. The treatment is not restricted to properties and functions of ideal gases. The ideal gas assumption is invoked as a limiting case. Reversible paths between equilibrium states are obtained using reversible heat engines and reversible heat pumps between environment and systems to determine the entropy changes and the maximum work. The conditions of thermodynamic equilibrium comprising mechanical, thermal, chemical and phase equilibrium are addressed and the species formed at equilibrium in a chemical reaction at a given temperature and pressure are obtained. The molecular basis for the laws of thermodynamics, temperature, internal energy changes, entropy, reversibility and equilibrium are briefly discussed. The book serves as a reference for undergraduate and graduate students alongside thermodynamics textbooks.
Fundamentals of Engineering Thermodynamics, 9th Edition sets the standard for teaching students how to be effective problem solvers. Real-world applications emphasize the relevance of thermodynamics principles to some of the most critical problems and issues of today, including topics related to energy and the environment, biomedical/bioengineering, and emerging technologies.
This book, now in its second edition, continues to provide a comprehensive introduction to the principles of chemical engineering thermodynamics and also introduces the student to the application of principles to various practical areas. The book emphasizes the role of the fundamental principles of thermodynamics in the derivation of significant relationships between the various thermodynamic properties. The initial chapter provides an overview of the basic concepts and processes, and discusses the important units and dimensions involved. The ensuing chapters, in a logical presentation, thoroughly cover the first and second laws of thermodynamics, the heat effects, the thermodynamic properties and their relations, refrigeration and liquefaction processes, and the equilibria between phases and in chemical reactions. The book is suitably illustrated with a large number of visuals. In the second edition, new sections on Quasi-Static Process and Entropy Change in Reversible and Irreversible Processes are included. Besides, new Solved Model Question Paper and several new Multiple Choice Questions are also added that help develop the students’ ability and confidence in the application of the underlying concepts. Primarily intended for the undergraduate students of chemical engineering and other related engineering disciplines such as polymer, petroleum and pharmaceutical engineering, the book will also be useful for the postgraduate students of the subject as well as professionals in the relevant fields.
Recent years have seen a growing interest in the field of thermodynamic properties of solids due to the development of advanced experimental and modeling tools. Predicting structural phase transitions and thermodynamic properties find important applications in condensed matter and materials science research, as well as in interdisciplinary research involving geophysics and Earth Sciences. The present edited book, with contributions from leading researchers around the world, is aimed to meet the need of academic and industrial researchers, graduate students and non-specialists working in these fields. The book covers various experimental and theoretical techniques relevant to the subject.
This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Néel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This textbook is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.
"This textbook addresses the key questions in both classical thermodynamics and statistical thermodynamics: Why are the thermodynamic properties of a nano-sized system different from those of a macroscopic system of the same substance? Why and how is entropy defined in thermodynamics, and how is the entropy change calculated when dissipative heat is involved? What is an ensemble and why is its theory so successful?" "Translated from a highly successful Chinese book, this expanded English edition containsmany updated sections and several new ones. They include the introduction of the grand canonical ensemble, the grand partition function and its application to ideal quantum gases, a discussion of the mean field theory of the Ising model and the phenomenon of ferromagnetism, as well as a more detailed discussion of ideal quantum gases near T = 0, for both Fermi and Bose gases."--BOOK JACKET.