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For the practical application of thermochemistry to the development and control of tech nical processes, the data for as many substances as possible are needed in conjunction with rapid and simple methods of calculating equilibrium constants, heat balances and the EMF of galvanic cells. For these three types of calculation the following three ther modynamic functions are suitable: The Planck function, the enthalpy and the Gibbs free energy, which are here defined and tabulated as unambigous functions of temperature for pure substances. The first edition of the tables was published in 1973 under the title "Thermochemical Properties of Inorganic Substances". The present supplementary volume contains the data and functions for a further 800 inorganic substances. In addition, the data for about 250 substances from the first volume have been up-dated. These usually small corrections produce better consistency with the data from more recent publications. The comments of users and reviewers of the first volume have largely been concerned with the difference between the present thermodynamic functions and the system used in the JANAF tables, the somewhat unconventional handling of heat balances adopted here, the notation of cell reactions, the description of non-stoichiometric phases and the accuracy of the tabulated data. To answer these questions and criticims the theore tical concepts and the practical use of the tables are dealt with in more detail in the introduction, following the recommendation of some reviewers.
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This volume presents a collection of critically assessed data on inorganic compounds which are of special interest in nuclear reactor safety studies. Thermodynamic equilibrium calculations are an important and widely used instrument in the understanding of the chemical behaviour and release of fission products in the course of nuclear reactor accidents. The reliability of such calculations is, nevertheless, limited by the availability of accurate input data for relevant compounds. The present work examines a wide variety of elements and compounds (oxides, hydroxides, actinides, iodides, tellurides, alloys, and ternary oxides) relevant to light water and fast nuclear reactors, in their condensed and gaseous state, many of which have been evaluated here for the first time. Recommended values, obtained from a critical evaluation of the literature, are given in an extensive explanatory text, and compiled in thermochemical tables from 298 to 3000 K. Special attention is also given to the crystallographic properties of the condensed phases.
This definitive work is the most uptodate compendium on tungsten in over twenty years. Wolf-Dieter Schubert's scientific career and extensive research activities combined with Erik Lassner's long-term industrial and development knowledge make this an essential resource on the current status of tungsten science and technology. Consolidating new knowledge previously presented at seminars or in the technical press, Tungsten is a significant contribution to the broader acceptance of the most recent innovations in the field. The text is enhanced by over 300 illustrations.
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.