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Why would we wish to start a 2nd edition of “Percolation theory for ?ow in porous media” only two years after the ?rst one was ?nished? There are essentially three reasons: 1) Reviews in the soil physics community have pointed out that the introductory material on percolation theory could have been more accessible. Our additional experience in teaching this material led us to believe that we could improve this aspect of the book. In the context of rewriting the ?rst chapter, however, we also expanded the discussion of Bethe lattices and their relevance for “classical” - ponents of percolation theory, thus giving more of a basis for the discussion of the relevance of hyperscaling. This addition, though it will not tend to make the book more accessible to hydrologists, was useful in making it a more complete reference, and these sections have been marked as being possible to omit in a ?rst reading. It also forced a division of the ?rst chapter into two. We hope that physicists without a background in percolation theory will now also ?nd the - troductory material somewhat more satisfactory. 2) We have done considerable further work on problems of electrical conductivity, thermal conductivity, and electromechanical coupling.
Percolation theory describes the effects of the connectivity of microscopic or small-scale elements of a complex medium to its macroscopic or large-scale properties. It also describes the conditions under which there may be a continuously connected path of local elements across the medium. The point at which the path is formed is called the percolation threshold. Percolation theory also predicts that many macroscopic properties of complex media follow universal power laws near the percolation threshold that are independent of many microscopic features of such media. There are many applications of percolation theory across the natural sciences, from porous materials, to composite solids, complex networks, and biological systems. This book presents the essential elements of percolation theory, covers the problem of calculating the exponents that characterize the power laws that the percolation quantities follow near the percolation threshold, provides a clear description of the geometry of percolation clusters of the connected paths, and addresses several variations of percolation theory. In particular, bootstrap percolation, explosive percolation, and invasion percolation are featured, which expand the range of natural systems to which percolation may be applicable. In addition, coverage includes several important applications of percolation theory to a range of phenomena, ranging from electrical conductivity, thermopower, the Hall effect, and photoconductivity of disordered semiconductors, to flow, transport and reaction in porous media, geochemistry, biology, and ecology.
This monograph presents, for the first time, a unified and comprehensive introduction to some of the basic transport properties of porous media, such as electrical and hydraulic conductivity, air permeability and diffusion. The approach is based on critical path analysis and the scaling of transport properties, which are individually described as functions of saturation. At the same time, the book supplies a tutorial on percolation theory for hydrologists, providing them with the tools for solving actual problems. In turn, a separate chapter serves to introduce physicists to some of the language and complications of groundwater hydrology necessary for successful modeling. The end-of-chapter problems often indicate open questions, which young researchers entering the field can readily start working on. This significantly revised and expanded third edition includes in particular two new chapters: one on advanced fractal-based models, and one devoted to the discussion of various open issues such as the role of diffusion vs. advection, preferential flow vs. critical path, universal vs. non-universal exponents for conduction, and last but not least, the overall influence of the experimental apparatus in data collection and theory validation. "The book is suitable for advanced graduate courses, with selected problems and questions appearing at the end of each chapter. [...] I think the book is an important work that will guide soil scientists, hydrologists, and physicists to gain a better qualitative and quantitative understanding of multitransport properties of soils." (Marcel G. Schaap, Soil Science Society of America Journal, May-June, 2006)