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This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.
The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be extended to mixtures, which are treated as pure systems. Furthermore, the author discusses current progress, and shows technicians how to derive practical equations from molecular modeling. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids is the ideal handbook for those in chemical science and engineering related to energy, environment, natural gas, and petroleum.* Describes the origins and applications from a universal viewpoint* Includes experimental data for comparisons * Suitable for researchers, applied engineers, and those interested in the corresponding states theory
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]
"Tile; D'apC:Tile; l. DpWTa ()coi 7rpo7rapod)w £ D'T}K,mi'. "between us and Goodness the gods have placed the sweat of our brows". This quote from Isiodos, the first lyrical poet, is jotted on a sheet of paper found among the papers of Heike Kamerlingh Onnes at the Boerhaave Museum, Leiden. On this same sheet, one can also read quotes from Schiller, Goethe, Shakespeare, Homer, Pindar and Dante. Each quote is for somebody or something. It appears to have been a game played at least by Ehrenfest and Crommelin -an unmistakable sign of these two physicists's deep culture. This particular quote was for the "Werkplaats", the Physical Laboratory of the University of Leiden. Our purpose in putting together the Selected Papers of its first Director, Kamerlingh Onnes (1853-1926), is to try and articulate the dominant trends of a different type of culture at Leiden: its physics culture during the years that established low temperature physics as a distinct branch of physics. Our aims in choosing the particular papers are threefold. First, we wish to present the interconnectedness among the different research programs of Kamerlingh Onnes and to bring out the decisive role of the work initiated by van der Waals in determining the direction of nearly all of these research programs.
This much-cited thesis by J. D. van der Waals, the recipient of the 1910 Nobel Prize in physics, is accompanied by an introductory essay by J. S. Rowlinson and another work by van der Waals on the theory of liquid mixtures. 1988 edition.
This book considers molecular structural information, statistical methods and thermodynamic measurements, and the ways in which the relative role of each differs from another. By putting together selected papers in a single publication, the book highlights the cohesive aspects of certain advances through time and development, and can aid historical studies. Several papers from journals not widely circulated can also be found in this selection of papers.
Fundamentals of Chemical Engineering Thermodynamics is the clearest and most well-organized introduction to thermodynamics theory and calculations for all chemical engineering undergraduates. This brand-new text makes thermodynamics far easier to teach and learn. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas organizes the text for more effective learning, focuses on "why" as well as "how," offers imagery that helps students conceptualize the equations, and illuminates thermodynamics with relevant examples from within and beyond the chemical engineering discipline. Matsoukas presents solved problems in every chapter, ranging from basic calculations to realistic safety and environmental applications.
Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers