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In this book, Samohýl and Pekař offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model – the linear fluid – and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohýl and Pekař take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.
This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed.· Systematic exposition of fluctuating hydrodynamics and its applications· First book on nonequilibrium fluctuations in fluids· Fluctuating Boussinesq equations and nonequilibrium fluids· Fluid layers and onset of convection· Rayleigh scattering and Brillouin scattering in fluids· Shadowgraph technique for measuring fluctuations· Fluctuations near hydrodynamic instabilities
This first volume discusses fluid mechanical concepts and their applications to ideal and viscous processes. It describes the fundamental hydrostatics and hydrodynamics, and includes an almanac of flow problems for ideal fluids. The book presents numerous exact solutions of flows in simple configurations, each of which is constructed and graphically supported. It addresses ideal, potential, Newtonian and non-Newtonian fluids. Simple, yet precise solutions to special flows are also constructed, namely Blasius boundary layer flows, matched asymptotics of the Navier-Stokes equations, global laws of steady and unsteady boundary layer flows and laminar and turbulent pipe flows. Moreover, the well-established logarithmic velocity profile is criticised.
Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Despite a long tradition of sophisticated, creative materials synthesis among quantum materials researchers, a sense of broader community has been lacking. In initiating the Fundamentals of Quantum Materials Winter School held annually at the University of Maryland, we wanted to bring together the next generation of growers to learn techniques and pointers directly from senior scientists, and it turns out that we were not alone. The enthusiasm from both students and teachers has been both gratifying and invigorating. Four schools later, we can confidently say that physicists, chemists, and materials scientists, experimentalists and theorists alike, all want to know how to make a good sample. With this in mind, we asked our lecturers to record their most important ideas and share their expertise with a broader audience. This resource is a compilation of fundamental and practical guides on the modern methods of materials synthesis utilized by these experts. We hope that you enjoy reading their essential guidance and state-of-the-art techniques as you explore the Fundamentals of Quantum Materials.
This four-volume handbook gives a state-of-the-art overview of porous materials, from synthesis and characterization and simulation all the way to manufacturing and industrial applications. The editors, coming from academia and industry, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 37 expert authors in 14 chapters, they construct the story of porous carbons, ceramics, zeolites and polymers from varied viewpoints: surface and colloidal science, materials science, chemical engineering, and energy engineering. Volumes 1 and 2 cover the fundamentals of preparation, characterisation, and simulation of porous materials. Working from the fundamentals all the way to the practicalities of industrial production processes, the subjects include hierarchical materials, in situ and operando characterisation using NMR, X-Ray scattering and tomography, state-of-the-art molecular simulations of adsorption and diffusion in crystalline nanoporous materials, as well as the emerging areas of bio-artificing and drug delivery. Volume 3 focuses on porous materials in industrial separation applications, including adsorption separation, membrane separation, and osmotic distillation. Finally, and highly relevant to tomorrow's energy challenges, Volume 4 explains the energy engineering aspects of applying porous materials in supercapacitors, fuel cells, batteries, electrolysers and sub-surface energy applications.The text contains many high-quality colourful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with porous materials.Related Link(s)
This volume contains the Proceedings of the RILEM TC 252-CMB International Symposium on the Chemo-Mechanical Characterization of Bituminous Materials. The Symposium was attended by researchers and practitioners from different fields presenting the latest findings in the chemical, mechanical, and microstructural characterization of bituminous materials. The book offers new and cutting edge papers on innovative techniques for the characterization of bituminous materials, gaining new insights into current issues such as effects of aging, moisture, and temperature.