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The study of surfaces has experienced dramatic growth over the past decade. Now, the editors of the internationally celebrated series Advances in Chemical Physics have brought together in this self-contained, special topic volume contributions from leading researchers in the field treating some of the most crucial aspects of the experimental and theoretical study of surfaces. This work delves into such core issues as: * Kinetics and dynamics of hydrogen adsorption on silicon surfaces. * Potential energy surfaces of transition- metal-catalyzed chemical reactions. * High-resolution helium atom scattering as a proof of surface vibrations. * Ordering and phase transitions in adsorbed monolayers of diatomic molecules. * The influence of dimensionality on static and dynamic properties of a system. * New applications to fields as varied as catalysts and the passage of molecules through membranes. This valuable resource provides important insights into the current state of knowledge about surface properties. Prigogine and Rice's latest work will stimulate the imagination and motivate the exploration of other aspects of this fascinating subject.
A quiet revolution in industry has happened over the last 50 or so years due to the use of diamond and cubic boron nitride (CBN) in many applications. Joining of diamonds to various materials via brazing is very specific compared with conventional brazing due to the unique nature of diamond. This chapter describes the properties of diamond and CBN, and their wetting by and interaction with metals and alloys; factors that affect these interactions; and practical aspects of diamonds and CBN joining. Some properties of brazed joints of diamond and CBN with different metals, as well as cemented carbide inserts, are presented and discussed. Finally, application examples are provided.
Recent breakthroughs in the synthesis of diamond have led to increased availability at lower cost. This has spurred R&D into its characterization and application in machine tools, optical coatings, X-ray windows and light-emitting optoelectronic devices. This book draws together expertise from some 60 researchers in Europe and the USA working on bulk and thin film diamond. All fully refereed, the contributions are combined to form a highly structured volume with reviews, evaluations, tables and illustrative material, together with expert guidance to the literature.
This book presents the latest research from around the world on diamond materials as well as related materials. These include cubic boron nitride and materials with characteristics and properties approaching or possibly exceeding those of diamond.
Recent discoveries enabling the growth of crystalline diamond by chemical vapor deposition offer the potential for a wide variety of new applications. This new book examines the state of the technology arising from these discoveries in relation to other allied materials, such as high-pressure diamond and cubic boron nitride. Most of the potential defense, space, and commercial applications are related to diamond's hardness, but some utilize its other qualities, such as optical and electronic properties. The authors review growth processes and discuss techniques for characterizing the resulting materials' properties. Crystalline diamond is emphasized, but other diamond-like materials (e.g. silicon carbide and amorphous carbon containing hydrogen) are also examined. In addition, the authors identify scientific, technical, and economic problems that could impede the rapid exploitation of these materials, and present recommendations covering broad areas of research and development.
This book gathers research from across the globe in the study of the properties, synthesis and applications of diamonds. Topics discussed in this compilation include amperometric biosensors based on boron-doped diamond electrodes; optical properties of diamond like carbon thin films; dynamic friction polishing of diamond surfaces; boron-doped diamond as a versatile electrode material; diamond deposition process and its application to substrates and specific defects induced by molecular beam implantation into a diamond.