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The aim of this volume is to draw together state-of-the-art reviews of knowledge onlevels of heavy metals in marine environments (particularly in marine animals), the dynamicprocesses in these systems, toxic effects, and threats presented by heavy metals in foods ofmarine origin.All heavy metals, whether biologically essential or not, have the potential to be toxicto organisms at a threshold bioavailability. Such threshold concentrations vary betweenmetals, between species and with the physicochemical characteristics of the medium, somelike copper being particularly toxic even though essential in trace amounts. Responses ofanimals to metals in their medium or food depend to a large extent on the ability of speciesto regulate levels attained in their tissues. Higher animals have the capacity to regulate levelsof many metals, while marine invertebrates can regulate some within certain limits. Whereanimals cannot regulate physiological levels of metals, an alternative strategy is to detoxifyand store metals in relatively harmless forms. Knowledge of the manner in which animals deal with potentially toxic concentrations of heavy metals is of fundamental importance in the assessment of metal pollution by analysis of metal levels in biological samples. The interaction of heavy metals with biological materials is a key theme running through this volume. Toxic effects may be reflected at the individual, population, or ecosystem level, affecting species composition and production levels, or may be of direct dietary significance to man. The global cycling of metals through the marine environment is crucially affected by biological processes.
Aquatic chemistry is becoming both a rewarding and substantial area of inquiry and is drawing many prominent scientists to its fold. Its literature has changed from a compilation of compositional tables to studies of the chemical reactions occurring within the aquatic environments. But more than this is the recognition that human society in part is determining the nature of aquatic systems. Since rivers deliver to the world ocean most of its dissolved and particulate components, the interactions of these two sets of waters determine the vitality of our coastal waters. This significant vol ume provides not only an introduction to the dynamics of aquatic chem istries but also identifies those materials that jeopardize the resources of both the marine and fluvial domains. Its very title provides its emphasis but clearly not its breadth in considering natural processes. The book will be of great value to those environmental scientists who are dedicated to keeping the resources of the hydrosphere renewable. As the size of the world population becomes larger in the near future and as the uses of materials and energy show parallel increases, the rivers and oceans must be considered as a resource to accept some of the wastes of society. The ability of these waters and the sediments below them to accommodate wastes must be assessed continually. The key questions relate to the capacities of aqueous systems to carry one or more pollutants.
The increasing production of industrial goods, heat, and energy, as well as traffic, has led to the release of considerable amounts of toxic trace metals to the atmosphere. The result is elevated concentrations of toxic metals in local populations and eco systems. Recently the problem of atmospheric long-range transport of trace metals has also been recognized. Significant amounts of these pollutants are disposed and deposited both on regional and global scales. In the atmosphere they may influence the chemical reactions. Of particular interest is their catalytic effect on the oxidation prosesses taking place in water droplets or on the surface of wet particles (e. g. the oxidation of sulphur dioxide to sulphate), however, the main environmental impact starts when the atmospheric trace metals are deposited on ground and vegetation and subsequently brought into the water circulation. During the later years significant progress has been made in the development of equipment to reduce and control the atmospheric emissions of toxic trace metals. This particularly applies to electrostatic precipitators and wet scrubbers for the collection of fine particles. The main objective of the workshop was to survey present knowledge concerning the sources, atmospheric fluxes, sinks and chemical impact of the atmospheric trace metals, and to review the developments of emission control equipment and the perspectives to reduce the potential risks from toxic metals. During the first two days of the meeting, 15 invited review papers were presented.
Metal Metabolism in Aquatic Environments is a synthesis of recent developments in the field of metal ecotoxicology and features a number of contemporary issues arising from the interaction of metals and biota, such as pathways of assimilation and food chain transfer, metal accumulation and detoxification in humans and biotransformation of elements such as mercury and arsenic.