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Perovskite Metal Oxides: Synthesis, Properties and Applications provides an overview on the topic, including the synthesis of various types of perovskites, their properties, characterization and application. The book reviews the applications of this category of materials for photovoltaics, electronics, biomedical, fuel cell, photocatalyst, sensor, energy storage and catalysis, along with processing techniques of perovskite metal oxides with a focus on low-cost and high-efficiency methods, including various properties and probable applications in academia and industry. Other sections discuss strategies to improve the functionality of perovskite metal oxide materials, including chemical methods and controlling the size, shape and structure of the materials. Finally, applications of perovskite metal oxides in energy conversion and storage, sensing and electronics are covered. - Provides an overview of perovskite metal oxides, with an emphasis on synthesis, fabrication and characterization methods - Discusses strategies to improve the functionality of perovskite metal oxide materials, including chemical methods and controlling the size, shape and structure of the materials - Reviews applications of perovskite metal oxides in energy conversion and storage, sensing and electronics
The Electrocaloric Effect: Materials and Applications reviews the fundamentals of the electrocaloric effect, the most relevant electrocaloric materials, and electrocaloric measurements and device applications. The book introduces the electrocaloric effect, along with modeling and simulations of this effect. Then, it addresses the latest advances in synthesis, characterization and optimization of the most relevant electrocaloric materials, including ferroelectric materials, liquid materials, lead-free materials, polymers and composites. Finally, there is a review of the latest techniques in measurement and applications in refrigeration and cooling and a discussion of the advantages, challenges and perspectives of the future of electrocaloric refrigeration. - Provides a comprehensive introduction to the electrocaloric effect including experimental techniques to measure, model, and simulate the effect - Reviews the most relevant electrocaloric materials such as composites, polymers, metal oxides, ferroelectric materials, and more - Touches on the design and application of electrocaloric materials for devices with potential cooling and refrigeration applications
This book shows how a small toolbox of experimental techniques, physical chemistry concepts as well as quantum/classical mechanics and statistical methods can be used to understand, explain and even predict extraordinary applications of these advanced engineering materials and biomolecules. It highlights how improving the material foresight by design, including the fundamental understanding of their physical and chemical properties, can provide new technological levels in the future.
As the finite capacity and pollution problems of fossil fuels grow more pressing, new sources of more sustainable energy are being developed. Materials for energy conversion devices summarises the key research on new materials which can be used to generate clean and renewable energy or to help manage problems from existing energy sources. The book discusses the range of materials that can be used to harness and convert solar energy in particular, including the properties of oxide materials and their use in producing hydrogen fuel. It covers thermoelectric materials and devices for power generation, ionic conductors and new types of fuel cell. There are also chapters on the use of such materials in the immobilisation of nuclear waste and as electrochemical gas sensors for emission control. With its distinguished editors and international team of contributors, Materials for energy conversion devices is a standard reference for all those researching and developing a new generation of materials and technologies for our energy need. Detailed coverage of solar energy and thermoelectric conversion Comprehensive survey of new developments in this exciting field Edited by leading experts in the field with contributions from an international team of authors
Recent advances in solid-state chemistry have resulted in substantial progress towards achieving a better understanding of the solid state, and have even led to the development of new predictive capabilities in crystal chemistry. Entirely new ways of studying and preparing advanced materials have been the result of pursuing the so-called "soft chemistry" approach to materials science.
Nonstoichiometric Oxides discusses the thermodynamic and structural studies of nonstoichiometric oxides. This eight-chapter text also covers the defect-defect interactions in these compounds. The introductory chapters describe the thermodynamic properties of nonstoichiometric oxides in terms of defect complexes using the classical thermodynamic principles and from a statistical thermodynamics point of view. These chapters also include statistical thermodynamic models that indicate the ordered nonstoichiometric phase range in these oxides. The subsequent chapters examine the transport properties, such as diffusion and electrical conductivity. Diffusion theories and experimental diffusion coefficients for several systems, as well as the electrical properties of the highly defective ionic and mixed oxide conductor, are specifically tackled in these chapters. The concluding chapters present the pertinent results obtained in nonstoichiometric oxide structural studies using high-resolution electron microscopy and X-ray and neutron diffraction. Inorganic chemists and inorganic chemistry teachers and students will greatly appreciate this book.
This book, based on the lectures and contributions of the NATO ASI on "Functional Properties of Nanostructured Materials", gives a broad overview on its topic, as it combines basic theoretical articles, papers dealing with experimental techniques, and contributions on advanced and up-to-date applications in fields such as microelectronics, optoelectronics, electrochemistry, sensorics, and biotechnology.
This is the first text to cover all aspects of solution processed functional oxide thin-films. Chemical Solution Deposition (CSD) comprises all solution based thin- film deposition techniques, which involve chemical reactions of precursors during the formation of the oxide films, i. e. sol-gel type routes, metallo-organic decomposition routes, hybrid routes, etc. While the development of sol-gel type processes for optical coatings on glass by silicon dioxide and titanium dioxide dates from the mid-20th century, the first CSD derived electronic oxide thin films, such as lead zirconate titanate, were prepared in the 1980’s. Since then CSD has emerged as a highly flexible and cost-effective technique for the fabrication of a very wide variety of functional oxide thin films. Application areas include, for example, integrated dielectric capacitors, ferroelectric random access memories, pyroelectric infrared detectors, piezoelectric micro-electromechanical systems, antireflective coatings, optical filters, conducting-, transparent conducting-, and superconducting layers, luminescent coatings, gas sensors, thin film solid-oxide fuel cells, and photoelectrocatalytic solar cells. In the appendix detailed “cooking recipes” for selected material systems are offered.