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Completely rewritten and reorganized to reflect the latest developments in estimating the properties of gases and liquids, this new edition of the highly regarded reference presents a comprehensive survey of the most reliable estimation methods in use today. It provides instantly usable information on estimating both physical and thermodynamic properties when experimental data are not available (for example, constants such as critical temperature, critical pressure, acentric factor, and others); thermodynamic properties of gases and liquids, both pure and mixtures, including enthalpies, entropies, fugacity coefficients, heat capacities, and critical points; vapor-liquid and liquid-liquid equilibria as needed in separation operations such as distillation, absorption, and extraction. An invaluable reference that provides property values for more than 600 pure chemicals, this is the only book in its field to include a critical analysis of existing methods as well as practical recommendations.
A thoroughly revised edition of the go-to chemical engineering reference Fully updated for the latest advances, this must-have chemical engineering guide serves as a single source for up-to-date physical data, chemical data, and predictive and estimation methods. The Properties of Gases and Liquids, Sixth Edition provides the latest curated data on over 480 compounds and includes a special section devoted to the interpretation of uncertainty in physical property estimation. You will get new coverage of advanced EOSs, advanced computational methods, quantum density functional theory, and semi-empirical combinations. Clear explanations and sample calculations are provided throughout this all-inclusive resource. Coverage includes: Traditional and non-traditional estimation methods Uncertainty Critical properties and related constants Ideal gas properties Saturation properties and virial coefficients Equations of state for pure compounds Equations of state for mixture properties Vapor-liquid, liquid-liquid, and solid-liquid equilibria Infinite dilution activity coefficients Viscosity and thermal conductivity Diffusivity and surface tension