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Pergamon Texts in Inorganic Chemistry, Volume 14: The Chemistry of Germanium, Tin, and Lead focuses on the properties, characteristics, transformations, and reactions of lead, germanium, and tin. The book focuses on germanium and compounds of Ge(I) and Ge(II). Discussions focus on germanium(II) compounds of phosphorus and arsenic, germanium(II) imide and nitride, monohalides, analytical determination, biological activity, chemical behavior of germanium, and production and industrial use of germanium. The text then elaborates on organogermanium compounds, complexes of germanium(IV), and tin. Topics include nuclear magnetic resonance, chemical properties of tin metal, isotopes of tin, occurrence and distribution of tin, and fluorogermanates and chlorogermanates. The manuscript takes a look at nuclear magnetic resonance, extraction, industrial and commercial utilization, toxicity, and chemical properties of metallic lead. The publication is a vital source of data for researchers interested in the chemistry of lead, germanium, and tin.
Organic compounds of Ge, Sn, and Pb have many properties that can be useful for such things as microbiocides, pesticides, anticancer treatments, octane number enhancers, and anti-foaming agents. This supplementary volume covers the most recent advances in the fields of photochemistry and structural chemistry. The authors also discuss the complex formation of these compounds. Written by key researchers in the field A supplement to The Chemistry of Organic Germanium Provides organic chemists with an invaluable reference source
Organic compounds of Ge, Sn, and Pb have many properties that can be useful for such things as microbiocides, pesticides, anticancer treatments, octane number enhancers, and anti-foaming agents. This supplementary volume covers the most recent advances in the fields of photochemistry and structural chemistry. The authors also discuss the complex formation of these compounds. Written by key researchers in the field A supplement to The Chemistry of Organic Germanium Provides organic chemists with an invaluable reference source
The present volume opens the Gmelin series on organogermanium compounds, that is, those compounds containing at least one germanium-to-carbon bond. This whole series is being coordinated by Professor J. Satge of the Universite Paul Sabatier in Toulouse. Germanium is of historical interest because its existence was predicted by Newlands in 1864 and by Mendeleeff in 1871 although it was not isolated until1887 by Winkler. Mendeleeff's predictions of the properties of germanium and its compounds by comparison with what was known of the chemistry of its neighbors, silicon and tin, proved remarkably accurate and included predictions of the existence of organic derivatives GeR and of their properties. 4 Although significant applications are as yet lacking for organogermanium compounds in contrast to organo-silicon, -tin, and -lead compounds there has been considerable interest in the parallel development of its chemistry. Up to 1983 about 1500 publications have appeared on organogermanium chemistry. The material of the present series will be grouped in a similar way as for the organotin series beginning with compounds containing only one germanium atom (mononuclear com pounds) and continuing with binuclear up to polynuclear compounds. Within each group the compounds are arranged by the kind of non-carbon substituents rather than by following the usual Gmelin principle of the last position using the Gmelin system of elements.
This is the first book to deal with C-Ge, C-Sn and C-Pb bonds asfunctional groups. This concept helps to better understand thechemistry of these compounds, which find an increasing amount ofapplications. The volume concentrates on analytical aspects, and onsafety and toxicology in the environment. This volume is now available in electronic format from BooksOnline.