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The present volume Uranium C12 covers the binary and polynary carbides of uranium, including ternary carbides with nonmetals like the carbide oxides and carbide nitrides U(C,O) and U(C,N). The binary carbide UC and especially the mixed carbide (UO.80PUO.20)C are of special importance due to their potential as the fuel for advanced .. Fast Breeder Reactors" because of properties such as the short doubling time, the high fissionable material density, and the good thermal conductivity. On the other hand, the dicarbide UC is of interest for .. High 2 Temperature Reactors", especially in the form of the mixed carbide (U . Th . )C . For O80 o20 2 the first time, India used mixed uranium-plutonium carbide (U . PU .)C as the fuel for its O3 O7 own newly developed 15 MW Fast Breeder Reactor at Kalpakkam, south of Madras. el Because of the technological importance of the uranium carbides a lot of data were published only in reports. In most cases, it was the aim of these less-scientifically based studies to promote the carbide fuel development on an economical basis. The lack of analyti cal data on the purity of the samples, missing characterization of the present phases, etc., hQINever, does not allow the discussion of the results of such references in this handbook. Therefore, only reliable publications were cited. For the technical fabrication of uranium carbides and their irradiation behavior, see Volumes A3 and A4 of this Handbook.
Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'