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The thermodynamic limit is a mathematical technique for modeling crystals or other macroscopic objects by considering them as infinite periodic arrays of molecules. The technique allows models in solid state physics to be derived directly from models in quantum chemistry. This book presents new results, many previously unpublished, for a large class of models and provides a survey of the mathematics of thermodynamic limit problems. The authors both work closely with Fields Medal-winner Pierre-Louis Lion, and the book will be a valuable tool for applied mathematicians and mathematical physicists studying nonlinear partial differential equations.
The book is devoted to the study of the correlation effects in many-particle systems. It presents the advanced methods of quantum statistical mechanics (equilibrium and nonequilibrium), and shows their effectiveness and operational ability in applications to problems of quantum solid-state theory, quantum theory of magnetism and the kinetic theory. The book includes description of the fundamental concepts and techniques of analysis following the approach of N N Bogoliubov's school, including recent developments. It provides an overview that introduces the main notions of quantum many-particle physics with the emphasis on concepts and models.This book combines the features of textbook and research monograph. For many topics the aim is to start from the beginning and to guide the reader to the threshold of advanced researches. Many chapters include also additional information and discuss many complex research areas which are not often discussed in other places. The book is useful for established researchers to organize and present the advanced material disseminated in the literature. The book contains also an extensive bibliography.The book serves undergraduate, graduate and postgraduate students, as well as researchers who have had prior experience with the subject matter at a more elementary level or have used other many-particle techniques.
While most introductions to statistical mechanics are either too mathematical or too physical, Colin Thompson's book combines mathematical rigor with familiar physical materials. Following introductory chapters on kinetic theory, thermodynamics, the Gibbs ensembles, and the thermodynamic limit, later chapters discuss the classical theories of phase transitions, the Ising model, algebraic methods and combinatorial methods for solving the two-dimensional model in zero field, and some applications of the Ising model to biology. Originally published in 1979. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.
On the occasion of the fourth International Conference on Industrial and Applied Mathematics!, we decided to organize a sequence of 4 minisymposia devoted to the mathematical aspects and the numerical aspects of Quantum Chemistry. Our goal was to bring together scientists from different communities, namely mathematicians, experts at numerical analysis and computer science, chemists, just to see whether this heterogeneous set of lecturers can produce a rather homogeneous presentation of the domain to an uninitiated audience. To the best of our knowledgde, nothing of this kind had never been tempted so far. It seemed to us that it was the good time for doing it, both . because the interest of applied mathematicians into the world of computational chemistry has exponentially increased in the past few years, and because the community of chemists feels more and more concerned with the numerical issues. Indeed, in the early years of Quantum Chemistry, the pioneers (Coulson, Mac Weeny, just to quote two of them) used to solve fundamental equations modelling toy systems which could be simply numerically handled in view of their very limited size. The true difficulty arose with the need to model larger systems while possibly taking into account their interaction with their environment. Hand calculations were no longer possible, and computing science came into the picture.
The book focuses on the study of the temporal behavior of complex many-particle systems. The phenomenon of time and its role in the temporal evolution of complex systems is a remaining mystery. The book presents the necessity of the interdisciplinary point of view regarding on the phenomenon of time.The aim of the present study is to summarize and formulate in a concise but clear form the trends and approaches to the concept of time from a broad interdisciplinary perspective exposing tersely the complementary approaches and theories of time in the context of thermodynamics, statistical physics, cosmology, theory of information, biology and biophysics, including the problem of time and aging. Various approaches to the problem show that time is an extraordinarily interdisciplinary and multifaceted underlying notion which plays an extremely important role in various natural complex processes.
Density functional theory (DFT) provides the most widely used models for simulating molecules and materials based on the fundamental laws of quantum mechanics. It plays a central role in a huge spectrum of applications in chemistry, physics, and materials science.Quantum mechanics describes a system of N interacting particles in the physical 3-dimensional space by a partial differential equation in 3N spatial variables. The standard numerical methods thus incur an exponential increase of computational effort with N, a phenomenon known as the curse of dimensionality; in practice these methods already fail beyond N=2. DFT overcomes this problem by 1) reformulating the N-body problem involving functions of 3N variables in terms of the density, a function of 3 variables, 2) approximating it by a pioneering hybrid approach which keeps important ab initio contributions and re-models the remainder in a data-driven way. This book intends to be an accessible, yet state-of-art text on DFT for graduate students and researchers in applied and computational mathematics, physics, chemistry, and materials science. It introduces and reviews the main models of DFT, covering their derivation and mathematical properties, numerical treatment, and applications.
The book provides a pedagogic and comprehensive introduction to homogenization theory with a special focus on problems set for non-periodic media. The presentation encompasses both deterministic and probabilistic settings. It also mixes the most abstract aspects with some more practical aspects regarding the numerical approaches necessary to simulate such multiscale problems. Based on lecture courses of the authors, the book is suitable for graduate students of mathematics and engineering.
This book is a new edition of Volumes 3 and 4 of Walter Thirring’s famous textbook on mathematical physics. The first part is devoted to quantum mechanics and especially to its applications to scattering theory, atoms and molecules. The second part deals with quantum statistical mechanics examining fundamental concepts like entropy, ergodicity and thermodynamic functions.