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This two volume set presents gas-phase kinetic data published in the lieterature between 1978 and 1982, inclusive. The data are organized according to the class of bimolecular or termolecular reactions. For each reaction, the table entry includes Arrhenius parameters and rate constants, experimetnal temperature, type of kinetic system, and a reference to a set of footnotes containing additional experimental details and any reference reacdion and their rate constants.
Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.
The handbook presents spectra to be utilized for the detection and measurement of new constituents in the earth's atmosphere and to obtain data for common minor species with large gas amounts in the absorption cell (such as CH/sub 4/ and N/sub 2/O). These results can be applied in the identification of absorption features in atmospheric spectra determined over long atmospheric paths. The spectra were recorded with Fourier Transform Spectrometers which are more precise than grating spectrometers. Each molecule spectrum was plotted on two scales: a condensed scale covering the range from 75 to 300/cm in one frame, and an expanded view covering 20 or 10/cm per frame. Each plot contains the name of the molecule, chemical formula, the gas pressure, cell length, and estimated resolution of the spectrum.
This annual series on organic reaction mechanisms research provides concise, comprehensive coverage of the year's literature as well as discussions of important results, each volume is extensively referenced to previous volumes and primary journals. This the 37th book in the series will survey research on organic reaction mechanisms described in the literature between December 1999 to November 2000. As in previous volumes new mechanisms for the synthesis of all types of organic compounds will be included as well as such mechanisms as addition and elimination reactions, nucleophilic and electrophilic aromatic substitutions and molecular arrangements.
Sulfur in the Atmosphere covers the proceedings of the International Symposium held in Dubrovnik, Yugoslavia on September 7-14, 1977. The text focuses on the processes involved in the transfer of sulfur through the atmospheric environment, particularly noting its distribution in space in gas, liquid, and solid phases. The book first offers information on the properties of sulfur and the processes involved in its determination, as well as measurement methods, chemical transformations, dry and wet deposition, and aerosol dynamics. The publication also looks at water-soluble sulfur compounds in aerosols, chemical properties of tropospheric sulfur aerosols, and sampling and analysis of atmospheric sulfates and related species. The text examines the techniques involved in the identification of chemical composition of aerosol sulfur compounds. Topics include thermal volatilization, thermometric methods, wet chemical identification, and laser Raman spectroscopy. The publication also reviews the calculation of long term sulfur deposition in Europe; transmission of sulfur dioxide on local, regional, and continental scale; and airborne sampling system for the monitoring of plume. The book is a dependable source of data for readers interested in the transfer of sulfur through the atmospheric environment.
Index to Reviews, Symposia Volumes and Monographs in Organic Chemistry for the Period 1940-1960 presents a resume of published monographs, reviews, and symposia lectures in organic chemistry. The editors adopted the plan of listings by symposia volume or journal, backed up by the total subject and author indexes. In this way the user can readily locate a particular article through the author index or the subject index; or should he recall that an article appeared in a particular source, the chronological listing in that source can be scanned quickly. The Index gives a convenient overview of the accomplishments of organic chemists during this very prolific period of the growth of the field. Frequently, several articles on the same or similar subject appear, hence the historical perspective can be sensed by rapid evaluation of the reviews selected. This Index will be useful to research workers, teachers and students. It will also assist editors and authors to select specific areas which require critical review.
The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1978 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1978. The 14th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.