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Most conventional cryogenic refrigerators and liquefiers operate with pure fluids, the major exception being natural gas liquefiers that use mixed refrigerant processes. The fundamental aspects of mixed refrigerant processes, though very innovative, have not received the due attention in open literature in view of commercial interests. Hundreds of patents exist on different aspects of mixed refrigerant processes. However, it is difficult to piece together the existing information to choose an appropriate process and an optimum composition or a given application. The aim of the book is to teach (a.) the need for refrigerant mixtures, (b.) the type of mixtures that can be used for different refrigeration and liquefaction applications, (c.) the different processes that can be used and (d.) the methods to be adopted for choosing the components of a mixture and their concentration for different applications.
This book offers a practical introduction to helium refrigeration engineering, taking a logical and structured approach to the design, building, commissioning, operation and maintenance of refrigeration systems. It begins with a short refresher of cryogenic principles, and a review of the theory of heat exchangers, allowing the reader to understand the importance of the heat exchanger role in the various thermodynamic cycle structures. The cycles are considered from the simplest (Joule Thomson) to the most complicated ones for the very large refrigeration plants and, finally, those operating at temperatures lower than 4.5 K. The focus then turns to the operation, ability and limitations of the main components, including room temperature cycle screw compressors, heat exchangers, cryogenic expansion turbines, cryogenic centrifugal compressors and circulators. The book also describes the basic principles of process control and studies the operating situations of helium plants, with emphasis on high level efficiency. A major issue is helium purity, and the book explains why helium is polluted, how to purify it and then how to check its purity, to ensure that all components are filled with pure helium prior to starting. Although the intention of the book is not to design thermodynamic cycles, it is of interest to a designer or operator of a cryogenic system to perform some simplified calculations to get an idea of how components or systems are behaving. Throughout the book, such calculations are generally performed using Microsoft® Excel and the Gaspak® or Hepak® software.
The last two years have witnessed a continuation in the breakthrough shift toward pulse tube cryocoolers for long-life, high-reliability cryocooler applications. New this year are papers de scribing the development of very large pulse tube cryocoolers to provide up to 1500 watts of cooling for industrial applications such as cooling the superconducting magnets of Mag-lev trains, coolmg superconducting cables for the power mdustry, and liquefymg natural gas. Pulse tube coolers can be driven by several competing compressor technologies. One class of pulse tube coolers is referred to as "Stirling type" because they are based on the linear Oxford Stirling-cooler type compressor; these generally provide coolmg m the 30 to 100 K temperature range and operate ^t frequencies from 30 to 60 Hz. A second type of pulse tube cooler is the so-called "Gifford-McMahon type. " Pulse tube coolers of this type use a G-M type compressor and lower frequency operation (~1 Hz) to achieve temperatures in the 2 to 10 K temperature range. The third type of pulse tube cooler is driven by a thermoacoustic oscillator, a heat engine that functions well in remote environments where electricity is not readily available. All three types are described, and in total, nearly half of this proceedings covers new developments in the pulse tube arena. Complementing the work on low-temperature pulse tube and Gifford-McMahon cryocoolers is substantial continued progress on rare earth regenerator materials.