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Electron-optical methods and their applicability; Interpretation of Electron Micrographs and Electron-Diffraction Patterns; Specimen Preparation; Kaolin Minerals; Serpentine Minerals; Smectites; Micas and Related Minerals; Palygorskite and Sepiolite; Hormites; Chlorites and Interstratified Minerals; Silica Minerals and Diatoms; Oxides of Iron, Aluminium, and Manganese; Other Minerals in Clay; Imogolite.
Characterization of reference clay mineral standards was accomplished by use of the scanning electron microscope (SEM), X-ray diffraction, and energy dispersive X-ray analysis. Experiments were conducted to determine the reactions between these clay minerals and lime which was used as a soil stabilizing agent. Examination of clay minerals visually by use of the SEM offers a partial examination of the irreactivity with soil stabilizing agents. Both surface area and surface roughness increase while there is an apparent decrease in the crystallinity of the clay minerals examined in the following order; Kaolinite group, Illite group, and Montmorillonite group. Reactions were studied of several soil clay minerals with various proportions of Ca(OH)2 and both with and without contact with the air. The major product of the reactions is calcite with smaller amounts of the material 3CaO . Al2O3 . CaCO3 . LlH2O. Scanning electron microscopy of the reacted materials shows a rough, 'corroded' surface on the clays as well as the formation of small single crystals of calcite and Ca(OH)2. Experimental studies showed that the problems of swelling soils can be alleviated by a double application Ca(OH)2 under proper moisture conditions. (Author).
This book on Applied Clay Mineralogy is comprehensive. It covers the structure, composition, and physical and chemical properties of kaolinite, halloysite, ball clays; bentonites including sodium montmorillonite, calcium montmorillonite, and hectorite; and palygorskite and sepiolite. There is also a short chapter on common clays which are used for making structural clay products and lightweight aggregate. The location and geology of the major clay deposits that are marketed worldwide and regionally include kaolins from the United States, Southwest England, Brazil, and the Czech Republic along with halloysite from New Zealand and ball clays from the US, England, Germany, and Ukraine. Bentonites from the U.S. and Europe are included along with palygorskite and sepiolite from the U.S., China, Senegal, and Spain. The mining and processing of the various clays are described. Extensive discussions of the many applications of the clays are included. The appendices cover the important laboratory tests that are used to identify and evaluate the various types of clay. Many figures are included covering electron micrographs, processing flow sheets, stratigraphy, and location maps. * Provides the structure and composition of clay minerals, as well as their phyisical and chemical properties * Discusses pplications for Kaolin, Bentonite, Palygorskite and Sepiolite * Contains appendixes of laboratory tests and procedures, as well as a test for common clays
Volume 27 of Reviews in Mineralogy provides a background to the TEM as a mineralogical tool, to give an introduction to the principles underlying its operation, and to explore mineralogical applications and ways in which electron microscopy can augment our knowledge of mineral structures, chemistry, and origin. Much time will be devoted to mineralogical applications. It provides sufficient information to allow mineralogists and petrologists to have an informed understanding of the data produced by transmission electron microscopy and to have enough knowledge and experience to undertake initial studies on their own. The opening chapters cover the principles of electron microscopy and chemical analysis using the TEM; while the following chapters consider mineralogical, petrological, and geochemical applications and their implications, for both low- and high-temperature geological environments. The Mineralogical Society of America sponsored a short courses in conjunction with their annual meetings with the Geological Society of America, and this volume represents the proceedings of the eighteenth in the sequence. This TEM course was convened October 23-25, 1992, at Hueston Woods State Park, College Comer, Ohio.
Layered materials, because of their particular atomic arrangement, are commonly 2characterized by physical and chemical properties of great interest in numerous technological and environmental processes and applications, as better detailed in the body of this volume. Most of these properties play a significant role in Earth sciences, environmental sciences, technology, biotechnology, material sciences and many other scientific areas. The surface properties of layered materials control important interaction processes, such as coagulation, aggregation, sedimentation, filtration, catalysis and ionic transport in porous media. Layered minerals also control many aspects of Earths rheology, i.e. the movement of geological masses, at least as far down as the lower crust. Given this frameset, it should be no surprise that the extremely large field of investigation of these materials can, and in most of the cases must, be approached from several different viewpoints. However, providing full coverage of the immense literature devoted to all the topics above may be impractical, if not impossible. Nevertheless, providing our students, to whom this book is addressed, with fundamental knowledge on different disciplines and providing examples demonstrating the application of these foundations in their daily research, is feasible and certainly useful.
Interpretation of Micromorphological Features of Soils and Regoliths, Second Edition, provides researchers and students with a tool for interpreting features observed in soil thin sections and through submicroscopic studies. After an introduction and general overview, micromorphological aspects of regoliths (e.g., saprolites, transported materials) are highlighted, followed by a systematic and coherent discussion of the micromorphological expression of various pedogenic processes. The book is written by an international team of experts in the field, using a uniform set of concepts and terminology, making it a valuable interdisciplinary reference work. The following topics are treated: freeze-thaw features, redoximorphic features, calcareous and gypsiferous formations, textural features, spodic and oxic horizons, volcanic materials, organic matter, surface horizons, laterites, surface crusts, salt minerals, biogenic and pedogenic siliceous materials, other authigenic silicates, phosphates, sulphidic and sulphuric materials, and features related to faunal activity. The last chapters address anthropogenic features,archaeological materials and palaeosoils. - Updates the first exhaustive publication on interpretation of micromorphological features, with some new chapters and with a larger number of additional references - Covers related topics, making micromorphology more attractive and accessible for geomorphologists, archaeologists and quaternary geologists Includes thematic treatment of a range of soil micromorphology fields and broadens its applications - Features input from a multi-disciplinary team, ensuring thorough coverage of topics related to soil science, archaeology and geomorphology
Origin and Mineralogy of Clays, the first of two volumes, lays the groundwork for a thorough study of clays in the environment. The second volume will deal with environmental interaction. Going from soils to sediments to diagenesis and hydrothermal alteration, the book covers the whole spectrum of clays. The chapters on surface environments are of great relevance in regard to environmental problems in soils, rivers and lake-ocean situations, showing the greatest interaction between living species and the chemicals in their habitat. The book is of interest to scientists and students working on environmental issues.
The meeting was organized by a local university committee and 205 delegates from 35 countries took part. European participation was low due to the economic crisis experienced by national air lines. During the conference, the AIPEA medals were awarded to Gerhard Lagaly and Tom Pinnavaia. This volume of the Conference Proceedings contains 85 out of a total of 235 oral presentations and posters presented at the following symposia: Teaching Clay Mineralogy, Clays in Hydrothermal Deposits, Clays in Ceramics, Clays in Petroleum Exploration and Production, Clay Barriers, and Waste Management, as well as in the following general sessions of the Conference: Clays in Geology, Clay Minerals and Environment, Soil Mineralogy, Methods, Crystal Chemistry Structure and Synthesis, and Clays in Industry.
Volume 46 of Reviews in Mineralogy and Geochemistry covers the international meeting on "Advances on Micas (Problems, Methods, Applications in Geodynamics)" convened in Rome in 2000. The topics of this meeting were the crystalchemical, petrological, and historical aspects of the micas. Thirteen invited plenary lectures, which consisted mostly of reviews, are presented in expanded detail in this volume. Contents: Mica crystal chemistry and the influence of pressure, temperature, and solid solution on atomistic models Behavior of micas at high pressure and high temperature Structural features of micas Crystallographic basis of polytypism and twinning in micas Investigation of micas using advanced transmission electron microscopy Optical and Mössbauer spectroscopy of iron in micas Infrared spectroscopy of micas X-ray absorption spectroscopy of the micas Constraints on studies of metamorphic K-Na white micas Modal spaces for pelitic schists Phyllosilicates in very low-grade metamorphism: Transformation to micas Historical perspective
Palygorskite-Sepiolite