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In this two-volume handbook, the editors Norbert Krause and A. Stephen K. Hashmi present all the important aspects and facts related to this hot topic. The treatment covers the whole range from the synthesis and classification via reactions right up to possible applications in the synthesis of natural products and drugs. With their excellent contributions an international team of outstanding authors highlight the multifarious uses and classes of allenes, making this an indispensable work for every organic chemist. From the Table of Contents: SYNTHESIS OF ALLENES Synthesis of Allenes by Isomerization Reactions Metal-Mediated Synthesis of Allenes Transition-Metal-Catalyzed Synthesis of Allenes Enantioselective Synthesis of Allenes SPECIAL CLASSES OF ALLENES Allenic Hydrocarbons - Preparation and Use in Organic Synthesis Cyclic Allenes Acceptor-Substituted Allenes Donor-Substituted Allenes Synthesis and Reactions of Allenylmetal Reagents REACTIONS OF ALLENES Ionic Additions to Allenes Fundamentals and Application of Free Radical Addition to Allenes Cycloadditions of Allenes Cyclizations of Allenes Transitions-Metal-Catalyzed Cross Couplings of Allenes Transitions-Metal-Catalyzed Cycloisomerizations of Allenes Transition-Metal-Catalyzed Addition/Cycloadditions of Allenes Oxidation of Allenes APPLICATIONS Allenic Natural Products and Phamaceuticals Allenes in Natural Product Synthesis Enyne-Allenes
The most complete resource in functional group chemistry Patai's Chemistry of Functional Groups is one of chemistry's landmark book series in organic chemistry. An indispensible resource for the organic chemist, this is the most comprehensive reference available in functional group chemistry. Founded in 1964 by the late Professor Saul Patai, the aim of Patai's Chemistry of Functional Groups is to cover all the aspects of the chemistry of an important functional group in each volume, with the emphasis not only on the functional group but on the whole molecule.
Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook. As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.
Organic Chemistry provides a comprehensive discussion of the basic principles of organic chemistry in their relation to a host of other fields in both physical and biological sciences. This book is written based on the premise that there are no shortcuts in organic chemistry, and that understanding and mastery cannot be achieved without devoting adequate time and attention to the theories and concepts of the discipline. It lays emphasis on connecting the basic principles of organic chemistry to real world challenges that require analysis, not just recall. This text covers topics ranging from structure and bonding in organic compounds to functional groups and their properties; identification of functional groups by infrared spectroscopy; organic reaction mechanisms; structures and reactions of alkanes and cycloalkanes; nucleophilic substitution and elimination reactions; conjugated alkenes and allylic systems; electrophilic aromatic substitution; carboxylic acids; and synthetic polymers. Throughout the book, principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the text and real world applications. There are extensive examples of biological relevance, along with a chapter on organometallic chemistry not found in other standard references. This book will be of interest to chemists, life scientists, food scientists, pharmacists, and students in the physical and life sciences. Contains extensive examples of biological relevance Includes an important chapter on organometallic chemistry not found in other standard references Extended, illustrated glossary Appendices on thermodynamics, kinetics, and transition state theory