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This book provides a detailed, wide ranging and up-to-date review of all aspects of the chemistry of the elements arsenic, antimony and bismuth. The chapters are written by an international team of authors each of whom is both active and expert in their particular field. The coverage includes chapters on general properties and periodicity, the elements themselves, inorganic derivatives of the elements, co-ordination and solution chemistry, organocompounds, organotransition metal compounds, environmental and medicinal aspects and analytical methods. This volume will be of particular value to graduate and postgraduate chemists and materials scientists in both industry and academia who are concerned with any aspect of the chemistry of these three elements and will also be an essential addition to the reference section of any chemistry library.
Arsenic, antimony and bismuth, three related elements of group 15, are all found in trace quantities in nature and have interesting biological properties and uses. While arsenic is most well known as a poison - and indeed the contamination of groundwater by arsenic is becoming a major health problem in Asia - it also has uses for the treatment of blood cancer and has long been used in traditional chinese medicine. Antimony and bismuth compounds are used in the clinic for the treatment of parasitic and bacterial infections. Biological Chemistry of Arsenic, Antimony and Bismuth is an essential overview of the biological chemistry of these three elements, with contributions from an international panel of experts. Topics covered include: chemistry of As, Sb and Bi biological chemistry of arsenic biological chemistry of Sb and Bi arsenic and antimony speciation in environmental and biological samples arsenic in traditional chinese medicine arsenic in aquifers biomethylation of As, Sb and Bi uptake of metalloids by cells bismuth complexes of porphyrins and their potential in medical applications Helicobacter pylori and bismuth metabolism of arsenic trioxide in blood of the acute promyelocytic leukemia patients anticancer properties of As, Sb and Bi radio-Bi in cancer therapy genotoxicity of As, Sb and Bi metallomics as a new technique for As, Sb and Bi metalloproteomics for As, Sb and Bi Biological Chemistry of Arsenic, Antimony and Bismuth conveys the essential aspects of the bioinorganic chemistry of these three elements, making this book a valuable complement to more general bioinorganic chemistry texts and more specialized topical reviews. It will find a place on the bookshelves of practitioners, researchers and students working in bioinorganic chemistry and medicinal chemistry.
Pergamon Texts in Inorganic Chemistry, Volume 2: The Chemistry of Arsenic, Antimony and Bismuth focuses on the physical and chemical properties of arsenic, antimony, and bismuth. This book discusses the alloys and intermetallic compounds; general aspects of the chemistry of arsenic; salts of antimony and bismuth; and organometallic compounds. The complexes of Arsenic(V), Antimony(V), and Bismuth(V), and mixed valency compounds and mechanisms of redox reactions are also elaborated. This text describes the chemical and physical properties of compounds, such as hydrides EH3, halides EX3, oxides E2O3, halides EX5, sulfides E2S5, oxides E2O5, and related oxyacids. This publication is intended for chemical engineering students and chemists researching on the characteristics of arsenic, antimony, and bismuth.
This is a complete and authoritative reference text on an evolving field. Over 200 international scientists have written over 340 separate topics on different aspects of geochemistry including organics, trace elements, isotopes, high and low temperature geochemistry, and ore deposits, to name just a few.
The organic synthetic chemistry of the Group V elements, arsenic, antimony and bismuth are dealt with in this volume in the respected Patai series. Internationally known contributors have written chapters on topics such as the analytical, theoretical, environmental and synthetic chemistry of the organometallic compounds of these elements.
Endlich ein Fachbuch, das die Theorie, Methoden und die verschiedenen Arten von Metall-Ionen-Komplexen in Wasser (Hydrolyse) umfassend behandelt. Geschrieben wurde dieses Referenzwerk von einem Kernchemiker aus dem Hochschulbereich und einem Geochemiker aus der Industrie. Behandelt werden Kationen- und Anionen-Komplexe sowie die Metall-Ionen-Hydrolyse, zu der zunächst Hintergrundinformationen geliefert werden, bevor eine Beschreibung der Dissoziation von Wasser, aller verschiedenen Hydrolysekomplexe und Verbindungen von Metall und Wasser folgt. Ein Muss für Wissenschaftler im universitären Umfeld und in der Industrie, die sich mit diesem interdisziplinären Thema beschäftigen.
Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics of inorganic chemistry, including organometallic chemistry and radiochemistry, from a pharmaceutical perspective. Written for students of pharmacy and pharmacology, pharmaceutical sciences, medicinal chemistry and other health-care related subjects, this accessible text introduces chemical principles with relevant pharmaceutical examples rather than as stand-alone concepts, allowing students to see the relevance of this subject for their future professions. It includes exercises and case studies.
Famous for its history of numerous element discoverers, Sweden is the origin of this comprehensive encylopedia of the elements. It provides both an important database for professionals as well as detailed reading ranging from historical facts, discoverers' portraits, colour plates of mineral types, natural occurrences, and industrial figures to winning and refining processes, biological roles and applications in modern chemistry, engineering and industry. Elemental data is presented in fact tables which include numerous physical and thermodynamic properties, isotope lists, radiation absorption characteristics, NMR parameters, and others. Further pertinent data is supplied in additional tables throughout the text. Published in Swedish in three volumes from 1998 to 2000, the contents have been revised and expanded by the author for this English edition.