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The Analytical Chemistry of Indium is a compilation of information on the analytical chemistry of indium, a metal that is important in optical and electronics industries and a component of certain alloys. The monograph aims to provide factual material available on the analytical chemistry of indium. The book gives an overview of the history and chemical properties of the element indium. Methods for the detection, separation, and determination of indium, including special methods for its determination in industrial and natural products are likewise discussed and evaluated. The text will be of good use to chemists, physicists, materials engineers, researchers, and students.
Boron has all the best tunes. That may well be the first impression of the Group 13 elements. The chemical literature fosters the impression not only in the primary journals, but also in asteady outflowofbooks focussing more or less closely on boron and its compounds. The same preoccupation with boron is apparent in the coverage received by the Group 13 elements in the comprehensive and regularly updated volume of the Gmelin Handbook. Yet such an imbalance cannot be explained by any inherent lack ofvariety, interest or consequence in the 'heavier elements. Aluminium is the most abundant metal in the earth's crust; in the industrialised world the metal is second only to iron in its usage, and its compounds can justifiably be said to touch our lives daily - to the potential detriment of those and other lives, some would argue. From being chemical curios, gallium and indium have now gained considerably prominence as sources of compound semiconductors like gallium arsenide and indium antimonide. Nor is there any want ofincident in the chemistriesofthe heavier Group 13 elements. In their redox, coordination and structural properties, there is to be found music indeed, notable not always for its harmony but invariably for its richness and variety. Thisbook seeks to redress the balance with a definitive, wide-rangingand up-to-date review of the chemistry of the Group 13 metals aluminium, gallium, indium and thallium.
Analysis of rocks and minerals often requires a specific approach, especially when determining rare and scattered elements, the content of which can be extremely low. This volume presents the main principles of analytical techniques most commonly used in the determination of the chemical composition of minerals and rocks. Special attention is given to methodological features and analytical schemes of various minerals, methods of mineral stripping and use of hybrid methods of analysis.
Analytical Chemistry of Zirconium and Hafnium compiles literature on the characterization and analysis of zirconium and hafnium. Various methods in studying the properties of the featured elements are presented in this book. This book also discusses the aqueous solutions of zirconium and hafnium. It then explains the methods such as dissolution of ores and alloys, detection and identification, and gravimetric determinations. This text further examines the titrimetric, electrometric, and absorptiometric methods, as well as methods of separations using ion-exchange and using solvent extraction, along with separation of hafnium from zirconium. The latter part of this text presents methods such as spectrographic analyses, X-ray analyses, and neutron activation analysis and separation of tracers. This book will come in handy for chemists and chemistry students, as well as for others interested in studying zirconium and hafnium.
Describes general aspects of metals in clinical chemistry focusing not only on the physiology of metal ions and their analytical determination in biological materials, but also on their geochemical distribution, technical uses and environmental effects.
International Series of Monographs in Analytical Chemistry, Volume 47: Analytical Chemistry of Molybdenum and Tungsten describes the chemical and instrumental methods of analysis of molybdenum and tungsten. This book is composed of 15 chapters that particularly consider detailed methods for determining these metals in typical samples and their alloys by both classical and modern techniques. The opening chapters discuss the history, occurrence, physico-chemical properties, and applications of molybdenum and tungsten. The succeeding chapters deal with the metals’ sampling, decomposition, separation, and qualitative detection. Considerable chapters are devoted to various chemical and instrumental methods for their analysis, including gravimetry, titrimetry, colorimetry, polarography, amperometry, coulometry, emission and atomic absorption spectroscopy, X-ray spectrophotometry, mass spectrometry, and radiochemical methods. The concluding chapter examines the determination of impurities and alloying elements. This book will prove useful to analytical and inorganic chemists, as well as analytical and inorganic chemistry students.
Analytical Chemistry of Organic Halogen Compounds presents the procedures applied in the analysis of organic halogen compounds. This book is composed of eight chapters that discuss the methods involved in the production and application of organic halogen compounds and in overcoming contamination problems caused by these compounds. After briefly dealing with the preparation, characteristics, and reactions of organic halogen compounds, this book goes on discussing the fundamental concepts of methods for the detection of halogens in organic compounds, namely, chlorine, bromine, iodine, and fluorine. The following chapter describes the characteristic features, advantages, and disadvantages of ultramicro and submicro chemical methods. A chapter also examines the qualitative and quantitative studies of organic halogen compounds based on the thermal and chemical stability of these compounds. The concluding chapters discuss the interference or interfering effects of halogens and their elimination in the determination of other elements. A list of physical constants of organic halogen compounds of general pharmaceutical and industrial significance is provided. This book is an ideal source for analytical chemists and other workers who are interested in the theoretical bases of the methods.
Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.