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With the rapid growth of energy electronics market, search for novel nanomaterials for efficient and eco-friendly energy conversion and storage has become an important task for manufacturers. Graphene, a two-dimensional carbon nanomaterial, has been widely applied in energy area due to its unique electric, chemical and physical properties. The atomic-scale and layered structures facilitate the integration of graphene into three-dimensional structures and heterostructures, thus opening a new world for rational design. This thesis consists of five chapters. After the first introduction chapter, the second chapter describes nitrogen-doped nanoporous graphene, which was synthesized on the zeolite-Y template with a tunable nitrogen content. The N-doped nanoporous graphene exhibits promising catalyzing performance in oxygen reduction reaction and is comparable to commercial Pt/C. In the third chapter, graphene networks was fabricated on sputtering-coated Cu to form a freestanding thin film. The films can be easily transferred onto various substrates, such as PDMS and Si wafer, which can be integrated into flexible and transparent electrochemical-double-layer supercapacitors (EDLC) to offer an opportunity for fabricating the wearable devices. In the fourth chapter, a nitrogen doped graphene-CNT-graphene ordered structure is designed on the anodic aluminum oxide substrate, which, as electrodes in a double-layer supercapacitor, exhibits the high capacity and long-term stability. The completely controllable graphene-CNT-graphene structures provide a chance to achieve ordered three-dimensional graphene hybrids for the first time. Finally, in the last chapter, molybdenum disulfide decorated three-dimensional graphene heterostructure is realized. The hybrids can serve as anodes in lithium-ion battery to exhibit a high capacity, excellent rate capability, and long cycle life.
Suitable for readers from broad backgrounds, Graphene: Energy Storage and Conversion Applications describes the fundamentals and cutting-edge applications of graphene-based materials for energy storage and conversion systems. It provides an overview of recent advancements in specific energy technologies, such as lithium ion batteries, supercapacitors, fuel cells, solar cells, lithium sulfur batteries, and lithium air batteries. It also considers the outlook of industrial applications in the near future. Offering a brief introduction to the major synthesis methods of graphene, the text details the latest academic and commercial research and developments, covering all potential avenues for graphene’s use in energy-related areas.
Templated Fabrication of Graphene-Based aterials for Energy Applications An illuminating look at the latest research on graphene-based materials and their applications in energy In Templated Fabrication of Graphene-Based Materials for Energy Applications, a team of distinguished materials scientists delivers a unique and topical exploration of a versatile fabrication method used to create high-quality graphene and composites. The book offers a three-part approach to current topics in graphene fabrication. The first part introduces graphene-based materials and is followed by cutting-edge discussions of template methods used in the preparation of graphene-based materials. The editors conclude with the latest research in the area of graphene-based materials applications in various energy-related pursuits. Readers will find relevant content that refers to original research conducted by the editors themselves, as well as work from up-and-coming and established researchers that explores the most interesting horizons in the study of graphene-based materials. The book also provides: A thorough introduction to graphene, including its history and physical properties An in-depth analysis of current graphene synthesis strategies, including the classification of graphene preparations Expansive discussions of various kinds of template methods for graphene production, including the study of porous metals and the preparation of graphene in large quantities Comprehensive explorations of the applications of various graphene-based materials, including lithium-ion batteries, lithium-sulfur batteries, and supercapacitors Perfect for materials scientists, electrochemists, and solid-state physicists, Templated Fabrication of Graphene-Based Materials for Energy Applications will also earn a place in the libraries of physical chemists and professionals in the electrotechnical industry.
This book provides a comprehensive overview of the synthesis, properties, and emerging applications of 3D graphene. It begins with an introduction to 3D graphene and covers the methods for synthesizing and printing 3D graphene. The book explores the characteristics of 3D graphene, including its morphology, surface area, and porosity, and the techniques used for characterizing it. Architectural and chemical aspects of 3D graphene for emerging applications are discussed, including energy storage, environmental remediation, and biosensing. The book reviews recent advancements in 3D graphene for electrochemical sensors, biosensors, and optical sensors, as well as its use in flexible sensors. It also covers the use of graphene-based materials for the remediation of hydrogen sulfide gas and the removal of inorganic pollutants and pharmaceutical residues. The book further explores the use of 3D graphene in metal-ion and metal-air batteries, flexible and wearable batteries, and high-performance supercapacitors. It also covers its use in photovoltaics, fuel cells, and as electrocatalysts and photocatalysts for water splitting. Additionally, the book discusses the use of 3D graphene in flexible electronics, capacitive de-ionization of water, and theranostic applications. Finally, the book addresses the toxicity, stability, recycling, and risk assessments of 3D graphene, providing a comprehensive understanding of the material's safety and sustainability considerations. Overall, this book is a valuable resource for researchers, engineers, and students interested in the synthesis, properties, and applications of 3D graphene.
This book introduces the synthesis and modification of 3D hierarchical porous graphene materials and presents various applications of it. By directly constructing a 3D graphene framework with sp2 hybridization and hierarchical porosity, this book is aimed to bridge the gap between 2D ideal nanostructure and 3D practical materials by systematically studying the growth mechanism, synthetic methodology, customized application, and system promotion of 3D hierarchical porous graphene (hpG) materials. The achievements presented offer a valuable contribution to the fundamental research and the industrial development of graphene with significantly improved performance and also inspire further research into various nanomaterials beyond graphene.
The fifth volume in a series of handbooks on graphene research and applications Graphene is a valuable nanomaterial used in technology. The Handbook of Graphene: Graphene in Energy, Healthcare, and Environmental Applications is the fifth volume in the handbook series. The book's topics include: graphene nanomaterials in energy and environment applications and graphene used as nanolubricant. Within the handbook, three-dimensional graphene materials are discussed, as are synthesis and applications in electrocatalysts and electrochemical sensors. The battery topics cover: graphene and graphene-based hybrid composites for advanced rechargeable battery electrodes; graphene-based materials for advanced lithium-ion batteries; graphene-based materials for supercapacitors and conductive additives of lithium ion batteries. The book's graphene-based sensor information addresses flexible actuators, sensors, and supercapacitors.
The book presents a comprehensive review of graphene-based supercapacitor technology. It focusses on synthesis, characterization, fundamental properties and promising applications of graphene materials and various types of graphene-based composites. The wide range of applications include electric power systems of portable electronics, hybrid-electric vehicles, mobile phones etc. Keywords: Graphene, Energy Storage Materials, Supercapacitors, Micro-Supercapacitors, Self-Healable Supercapacitors, Graphene-Based ZnO Nanocomposites, Defect Engineered Graphene Materials, Electric Power Systems.
The considerable interest in graphene and 2D materials is sparking intense research on layered materials due to their unexpected physical, electronic, chemical, and optical properties. This book will provide a comprehensive overview of the recent and state-of-the-art research progress on layered materials for energy storage and other applications. With a brief introduction to layered materials, the chapters of this book gather various fascinating topics such as electrocatalysis for fuel cells, lithium-ion batteries, sodium-ion batteries, photovoltaic devices, thermoelectric devices, supercapacitors and water splitting. Unique aspects of layered materials in these fields, including novel synthesis and functionalization methods, particular physicochemical properties and consequently enhanced performance are addressed. Challenges and perspectives for layered materials in these fields will also be presented. With contributions from key researchers, Layered Materials for Energy Storage and Conversion will be of interest to students, researchers and engineers worldwide who want a basic overview of the latest progress and future directions.
This first book dedicated to the topic provides an up-to-date account of the many opportunities graphene offers for robust, workable energy generation and storage devices. Following a brief overview of the fundamentals of graphene, including the main synthesis techniques, characterization methods and properties, the first part goes on to deal with graphene for energy storage applications, such as lithium-ion batteries, supercapacitors and hydrogen storage. The second part is concerned with graphene-based energy-generation devices, in particular conventional as well as microbial and enzymatic fuel cells, with chapters on graphene photovoltaics rounding off the book. Throughout, device architectures are not only discussed on a laboratory scale, but also ways for upscaling to an industrial level, including manufacturing processes and quality control. By bridging academic research and industrial development this is invaluable reading for materials scientists, physical chemists, electrochemists, solid state physicists, and those working in the electrotechnical industry.
With escalating global population, increased consumption of fossil fuels, spiralling energy demand, rapid environmental degradation and global climate change, energy and environmental issues are receiving considerable attention worldwide from the purview of sustainable development. In order to address these complex and interlinked challenges, the development of new materials for affordable green energy technologies (batteries, supercapacitors, fuel cells and solar cells) and environmental remediation methods (adsorption, photocatalysis, separation, and sensing) is essential. Three-dimensional graphene-based macrostructures (3D GBMs) are of great interest in these applications given their large surface area and adaptable surface chemistry. Graphene-based 3D Macrostructures for Clean Energy and Environmental Applications provides a critical and comprehensive account of the recent advances in the development and potential applications of high performance 3D GBMs for tackling global energy and environmental issues in a sustainable manner. Particular attention is paid to the fabrication schemes, modulation of physiochemical properties, and their integration into practical devices, and the roles of surface chemistry and pore morphology, as well as their interplay, on the overall performance of 3D GBMs are examined. With contributions from authors around the world this book is a useful resource for both environmental scientists interested in sustainable energy and remediation solutions and materials scientists interested in applications for 3D GMBs.