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Organogermanium Compounds Understand the chemistry of organogermanium compounds with this thorough and cutting-edge reference Discovered comparatively late in the history of chemistry, germanium has become one of the most technology-critical elements in modern industry. Germanium and its inorganic and organic derivatives found widespread applications in fiber- and infrared-optics, electronics, polymerization catalysis, solar electric technology, nanotechnology, chemotherapy, and more. Organogermanium compounds containing carbon to germanium chemical bonds, have applications in microelectronics, medicinal and health industries, and beyond. Organogermanium Compounds: Theory, Experiment, and Applications, 2 Volume Set provides a comprehensive review of this class of compounds in two thorough volumes. It covers all modern aspects of these critically important compounds, including theoretical, synthetic, physico-chemical, and applied research. Reflecting the latest breakthroughs in this rapidly growing field, this book promises to serve as the high-level reference for those readers who are interested in organogermanium chemistry. Organogermanium Compounds readers will also find: 19 chapters produced by leading global experts Descriptions of pivotal historical achievements in organogermanium research Coverage of the latest computational, synthetic, and applied breakthroughs Organogermanium Compounds is a critical reference for researchers and professionals in a wide range of academic and industrial fields working with these fascinating compounds. This will also be helpful for university and college students, at both graduate and undergraduate levels.
This is the first book to deal with C-Ge, C-Sn and C-Pb bonds asfunctional groups. This concept helps to better understand thechemistry of these compounds, which find an increasing amount ofapplications. The volume concentrates on analytical aspects, and onsafety and toxicology in the environment. This volume is now available in electronic format from BooksOnline.
Discovered comparatively late in the history of chemistry, germanium has become one of the most technology-critical elements in modern industry. Germanium and its inorganic and organic derivatives found widespread applications in fiber- and infrared-optics, electronics, polymerization catalysis, solar electric technology, nanotechnology, chemotherapy, and more. Organogermanium compounds containing carbon to germanium chemical bonds, have applications in microelectronics, medicinal and health industries, and beyond. Organogermanium Compounds: Theory, Experiment, and Applications, 2 Volume Set provides a comprehensive review of this class of compounds in two thorough volumes. It covers all modern aspects of these critically important compounds, including theoretical, synthetic, physico-chemical, and applied research. Reflecting the latest breakthroughs in this rapidly growing field, this book promises to serve as the high-level reference for those readers who are interested in organogermanium chemistry.
Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
This is the first book to deal with C-Ge, C-Sn and C-Pb bonds asfunctional groups. This concept helps to better understand thechemistry of these compounds, which find an increasing amount ofapplications. The volume concentrates on analytical aspects, and onsafety and toxicology in the environment. This volume is now available in electronic format from BooksOnline.
Organic compounds of Ge, Sn, and Pb have many properties that can be useful for such things as microbiocides, pesticides, anticancer treatments, octane number enhancers, and anti-foaming agents. This supplementary volume covers the most recent advances in the fields of photochemistry and structural chemistry. The authors also discuss the complex formation of these compounds. Written by key researchers in the field A supplement to The Chemistry of Organic Germanium Provides organic chemists with an invaluable reference source
Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.
Pergamon Texts in Inorganic Chemistry, Volume 14: The Chemistry of Germanium, Tin, and Lead focuses on the properties, characteristics, transformations, and reactions of lead, germanium, and tin. The book focuses on germanium and compounds of Ge(I) and Ge(II). Discussions focus on germanium(II) compounds of phosphorus and arsenic, germanium(II) imide and nitride, monohalides, analytical determination, biological activity, chemical behavior of germanium, and production and industrial use of germanium. The text then elaborates on organogermanium compounds, complexes of germanium(IV), and tin. Topics include nuclear magnetic resonance, chemical properties of tin metal, isotopes of tin, occurrence and distribution of tin, and fluorogermanates and chlorogermanates. The manuscript takes a look at nuclear magnetic resonance, extraction, industrial and commercial utilization, toxicity, and chemical properties of metallic lead. The publication is a vital source of data for researchers interested in the chemistry of lead, germanium, and tin.