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Since Dr. Disiich of Germany prepared a glass lens by the sol-gel method around 1970, sol-gel science and technology has continued to develop. Since then this field has seen remarkable technical developments as well as a broadening of the applications of sol-gel science and technology. There is a growing need for a comprehensive reference that treats both the fundamentals and the applications, and this is the aim of "Handbook of Sol-Gel Science and Technology."The primary purpose of sol-gel science and technology is to produce materials, active and non-active including optical, electronic, chemical, sensor, bio- and structural materials. This means that sol-gel science and technology is related to all kinds of manufacturing industries. Thus Volume 1, "Sol-Gel Processing," is devoted to general aspects of processing. Newly developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, photocatalysts will be covered. Topics in this volume include: Volume 2, "Characterization of Sol-Gel Materials and Products, "highlights the important fact that useful materials are only produced when characterization is tied to processing. Furthermore, characterization is essential to the understanding of nanostructured materials, and sol-gel technology is a most important technology in this new field. Since nanomaterials display their functional property based on their nano- and micro-structure, "characterization" is very important. Topics found in Volume 2 include: Sol-gel technology is a versatile technology, making it possible to produce a wide variety of materials and to provide existing substances with novel properties. This technology was applied to producingnovel materials, for example organic-inorganic hybrids, which are quite difficult to make by other fabricating techniques, and it was also applied to producing materials based on high temperature superconducting oxides. "Applications of Sol-Gel Technology," (Volume 3), will cover applications such as:
The sol-gel method is a powerful route of synthesis used worldwide. It produces bulk, nano- and mesostructured sol-gel materials, which can encapsulate metallic and magnetic nanoparticles, non-linear azochromophores, perovskites, organic dyes, biological molecules, etc.. This can have interesting applications for catalysis, photocatalysis; drug delivery for treatment of neurodegenerative diseases such as cancer, Parkinson's and Azheimer's. In this book, valuable contributions related to novel materials synthesized by the sol-gel route are provided. The effect of the sol-gel method to synthesize these materials with potential properties is described, and how the variation of the parameters during the synthesis influences their design and allows to adjust their properties according to the desired application is discussed.
During my professional career, I developed a strong interest in sol-gel technology, and worked on both xerogel and aerogel systems. My fascination with aerogels has driven me to explore their commercial potential, which is currently an important component of my company's business plan. Together with my co-workers, I have also worked on the preparation of controlled PZT and silica xerogels as well as thin film coatings of metals by the sol-gel technology, These experiences convinced me of the tremendous potentials of this technology. A conviction that is shared by many scientists, engineers, and business leaders around the globe. Many sol-gel derived products are already articles of commerce. However, to expand the commercial potential of sol-gel technology, two challenges must be met: (1) the quality of sol-gel derived products must continue to meet or exceed the quality of competing products, (2) the production cost of sol-gel products (specially aerogels) must continued to decline. A key to lowering the costs of sol-gel products is finding inexpensive precursors.
Sol-Gel processing methods, first used historically for decorative and constructional materials, were extensively developed in the last century for applications such as glasses, ceramics, catalysts, coatings, composites and fibres. Today they are reaching their full potential, enabling the preparation of new generations of advanced materials not easily accessible by other methods yet using mild, low-energy conditions. The topic is therefore increasingly included in advanced undergraduate, MSc and PhD programmes in the areas of chemistry, physics and materials science. This concise introductory text, written at the advanced undergraduate/first-year postgraduate level, is also suitable as an introduction to the development, mechanisms, chemistry, characterisation methods and applications of the technique. It provides readers with an extensive yet concise grounding in the theory of each area of the subject and details the real and potential applications and the future prospects of sol-gel chemistry.
Recent advances in nanotechnology have paved the way for the development of new smart materials. The term "smart ceramics" refers to ceramic materials fabricated from ultrafine particles. They have attracted the attention of researchers and scientists thanks to their potential to manipulate the length scale in the nanorange, leading to better and some unusual material properties. Smart ceramics ensure control of particle size, surface contamination, and degree of agglomeration. They play a crucial role in challenging applications such as bone surgery (e.g., the development of substitutes for load-bearing bone parts) and in biomedical science, especially in tissue engineering, dental applications, and drug and antigen delivery using modified ceramics. Porous nanostructured ceramics have potential use in both simple and complex applications, such as bioimaging, sensors, paints and pigments, optics, and electronics, because of their surface- and size-dependent properties. For the synthesis of smart ceramics, the sol-gel route has been mainly utilized because of its ability to produce a large variety of compositions and to ensure homogeneous mixing of the constituent particles at low temperature. This book describes the innovations in technologies through the development of functionalized ceramic materials for various applications. It also describes recent and expected challenges, along with their potential solutions, in advanced techniques for the synthesis and characterization of nanostructured ceramics and their composites: bioceramics, bioactive ceramics, multifunctional nanoceramics, transparent ceramics, nanocore shells, nanowires, thin films, nanotubes, and nanorods. The applications include the environment, health care, electrochemical sensors, high-temperature superconductors, nuclear reactor fuels, electrical insulators, refractory materials, electrical transformers, and magnetic core memory. The book will benefit researchers, scientists, engineers, and technologists working in the industry and in national and international research laboratories; academics who are interested in traditional and advanced smart ceramic composites; and students pursuing their postgraduate, graduate, and undergraduate degrees in smart ceramics, nanomaterials, nanoscience, and engineering.
Since Dr. Disiich of Germany prepared a glass lens by the sol-gel method around 1970, sol-gel science and technology has continued to develop. Since then this field has seen remarkable technical developments as well as a broadening of the applications of sol-gel science and technology. There is a growing need for a comprehensive reference that treats both the fundamentals and the applications, and this is the aim of "Handbook of Sol-Gel Science and Technology."The primary purpose of sol-gel science and technology is to produce materials, active and non-active including optical, electronic, chemical, sensor, bio- and structural materials. This means that sol-gel science and technology is related to all kinds of manufacturing industries. Thus Volume 1, "Sol-Gel Processing," is devoted to general aspects of processing. Newly developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, photocatalysts will be covered. Topics in this volume include: Volume 2, "Characterization of Sol-Gel Materials and Products, "highlights the important fact that useful materials are only produced when characterization is tied to processing. Furthermore, characterization is essential to the understanding of nanostructured materials, and sol-gel technology is a most important technology in this new field. Since nanomaterials display their functional property based on their nano- and micro-structure, "characterization" is very important. Topics found in Volume 2 include: Sol-gel technology is a versatile technology, making it possible to produce a wide variety of materials and to provide existing substances with novel properties. This technology was applied to producingnovel materials, for example organic-inorganic hybrids, which are quite difficult to make by other fabricating techniques, and it was also applied to producing materials based on high temperature superconducting oxides. "Applications of Sol-Gel Technology," (Volume 3), will cover applications such as:
This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.
This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.