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Neoglycoconjugates are not only useful for the basic understanding of protein-carbohydrate interactions, but they have many practical applications as well. They are powerful reagents in many cell biology studies and excellent tools for the isolation and characterization of animal and plant lectins, separation of cells, as well as for the targeting of drugs, artificial vaccines, and diagnostic reagents. Volume 247 and its companion Volume 242 contain many practical methods on how to prepare and use neoglycoconjugates. Volume 242 deals with synthesis and 247 with biomedical applications.
This monograph/reference focuses on those subjects that are considered essential to an understanding of inorganic photochemistry. Graduate students with a background in physical chemistry will find that the quantum mechanical treatments related to the principles of spectroscopy and chemical dynamics are readily accessible. And professionals will find that the tabulated data, equations, and general information makes this book an essential complement to the journal literature required in the daily planning of photochemical work. Chapters cover the nature of light and the uncertainty principle, detection of intermediates, elements of inorganic spectroscopy, kinetics of photoluminescence, photoredox reactions, ligand field photochemistry, and elements of organometallic photochemistry. Extensive appendixes cover physical constants and conversion factors for photochemical work, character tables for symmetry groups, vibrational motions, description of the chemical bonding in coordination complexes, charge transfer transitions, and Born cycles related to charge transfer processes.
PHOTOPHYSICAL PROCESSES - ENERGY LEVELS AND SPECTRA; KINETICS OF PHOTOPHYSICAL PROCESSES; CHARGE - TRANSFER PHOTOCHEMISTRY; SUBSTITUTIONAL PHOTOCHEMISTRY OF FIRST - ROW TRANSITION ELEMENTS; PHOCHEMISTRY OF THE HEAVIER ELEMENTS; PHOTOCHEMISTRY OF CARBONYL COMPLEXES; PHOTOCHEMISTRY OF 1,3 - DIKETONATE CHELATES; THE PHOTOLYSIS OF SIMPLE INORGANIC IONS IN SOLUTION; PHOTOCHEMISTRY IN THE SOLID STATE; PHOTOCHROMISM AND CHEMILUMINESCENCE.
This book will describe Ruthenium complexes as chemotherapeutic agent specifically at tumor site. It has been the most challenging task in the area of cancer therapy. Nanoparticles are now emerging as the most effective alternative to traditional chemotherapeutic approach. Nanoparticles have been shown to be useful in this respect. However, in view of organ system complicacies, instead of using nanoparticles as a delivery tool, it will be more appropriate to synthesize a drug of nanoparticle size that can use blood transport mechanism to reach the tumor site and regress cancer. Due to less toxicity and effective bio-distribution, ruthenium (Ru) complexes are of much current interest. Additionally, lumiscent Ru-complexes can be synthesized in nanoparticle size and can be directly traced at tissue level. The book will contain the synthesis, characterization, and applications of various Ruthenium complexes as chemotherapeutic agents. The book will also cover the introduction to chemotherapy, classification of Ru- complexes with respect to their oxidation states and geometry, Ruthenium complexes of nano size: shape and binding- selectivity, binding of ruthenium complexes with DNA, DNA cleavage studies and cytotoxicity. The present book will be more beneficial to researchers, scientists and biomedical. Current book will empower specially to younger generation to create a new world of ruthenium chemistry in material science as well as in medicines. This book will be also beneficial to national/international research laboratories, and academia with interest in the area of coordination chemistry more especially to the Ruthenium compounds and its applications.
Green Chemistry is an inventive science based on fundamental research towards the development of new sustainable chemical processes. There is a great need to create a new type of chemistry focused on a new production system, in order to prepare the younger generation to get a greener future. The globalization pushes the chemistry community to adopt ethical issues. In this prospect Green Chemistry can achieve the approval of the society by teaching students to be confident in science and at the same time by convincing people that it is possible to attain technological development with respect and care for the environment we live in. This is why it is of foremost importance that education and fundamental research remain strictly connected, so that democracy and development can grow and progress side by side. This book has been prepared to extend the knowledge of Green Chemistry not disregarding, however, the industrial interest. It is the result of the effort to put together and share the expertise of leading practitioners in the field of Green Chemistry. The Interuniversity Consortium ‘Chemistry for the Environment’ is a non-profit organisation established in 1993 in Italy. At present it includes 31 member universities and 80 research units.
This book summarizes the results of studies on charge transfer photochemistry of metal complexes of the past few years. The material covered is organized in such a manner that each chapter discusses the photoredox properties of complexes of a series of metals which belong to the same column of the periodic table, including both transition metals and main group metals (for those that show photoactivity). Foremostly, the book covers photoinduced processes in which the primary step is a charge transfer reaction of the excited metal complex. It is concerned primarily with in-depth descriptions and discussions of the photochemistry of complexes themselves, with less emphasis on theoretical discussions. This book is aimed at professional photochemical researchers as well as students and chemists who are interested in organometallic and inorganic metal complexes and plan to become familiar with their charge transfer photochemistry.
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Polypyridyl and porphyrin complexes demonstrate an excitingly rich photochemistry. These systems have important applications in photocatalysis, photochemical conversion and storage of solar energy, and photosynthesis. The book covers the basic concepts of inorganic electronic spectroscopy and photochemistry and then discusses excited state production, relaxation, and photochemical reactions. Covers two important series of complexes in comprehensive surveys Written to serve researchers who need a rapid entry into the field Presents concepts and techniques useful to advanced students