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Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.
This popular and comprehensive textbook provides all the basic information on inorganic chemistry that undergraduates need to know. For this sixth edition, the contents have undergone a complete revision to reflect progress in areas of research, new and modified techniques and their applications, and use of software packages. Introduction to Modern Inorganic Chemistry begins by explaining the electronic structure and properties of atoms, then describes the principles of bonding in diatomic and polyatomic covalent molecules, the solid state, and solution chemistry. Further on in the book, the general properties of the periodic table are studied along with specific elements and groups such as hydrogen, the 's' elements, the lanthanides, the actinides, the transition metals, and the "p" block. Simple and advanced examples are mixed throughout to increase the depth of students' understanding. This edition has a completely new layout including revised artwork, case study boxes, technical notes, and examples. All of the problems have been revised and extended and include notes to assist with approaches and solutions. It is an excellent tool to help students see how inorganic chemistry applies to medicine, the environment, and biological topics.
This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.
With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.