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Symmetry of Many-Electron Systems discusses the group-theoretical methods applied to physical and chemical problems. Group theory allows an individual to analyze qualitatively the elements of a certain system in scope. The text evaluates the characteristics of the Schrodinger equations. It is proved that some groups of continuous transformation from the Lie groups are useful in identifying conditions and in developing wavefunctions. A section of the book is devoted to the utilization of group-theoretical methods in quantal calculations on many-electron systems. The focus is on the use of group-theoretical methods to the classification and calculation of states of molecule. A chapter of the book gives a comprehensive discussion of the fractional parentage method. This application is used in atomic and nuclear spectroscopy. The method of employing coordinate wave functions is explained. The standard Young-Yamanouchi orthogonal representation is presented completely. The book will provide useful guides for physicists, chemists, engineers, students, and researchers in the field of physics.
This book is a self-contained advanced textbook on the mathematical-physical aspects of quantum many-body systems, which begins with a pedagogical presentation of the necessary background information before moving on to subjects of active research, including topological phases of matter. The book explores in detail selected topics in quantum spin systems and lattice electron systems, namely, long-range order and spontaneous symmetry breaking in the antiferromagnetic Heisenberg model in two or higher dimensions (Part I), Haldane phenomena in antiferromagnetic quantum spin chains and related topics in topological phases of quantum matter (Part II), and the origin of magnetism in various versions of the Hubbard model (Part III). Each of these topics represents certain nontrivial phenomena or features that are invariably encountered in a variety of quantum many-body systems, including quantum field theory, condensed matter systems, cold atoms, and artificial quantum systems designed for future quantum computers. The book’s main focus is on universal properties of quantum many-body systems. The book includes roughly 50 problems with detailed solutions. The reader only requires elementary linear algebra and calculus to comprehend the material and work through the problems. Given its scope and format, the book is suitable both for self-study and as a textbook for graduate or advanced undergraduate classes.
This volume continues the series of proceedings of summer schools on theoretical physics related to various aspects of the structure of condensed matter, and to appropriate mathematical methods for an adequate description. Three main topics are covered: (i) symmetric and unitary groups versus electron correlations in multicentre systems; (ii) conformal symmetries, the Bethe ansatz and quantum groups; (iii) paradoxes of statistics, space-time, and time quantum mechanics. Problems considered in previous schools are merged with some new developments, like statistics with continuous Young diagrams, the existence and structure of energy bands in solids with fullerenes, membranes and some coverings of graphite sheets, or vortex condensates with quantum counterparts of Maxwell lows.
The contents survey the achievements and research problems connected with an adequate description of condensed matter structure, its phases and other properties in terms of appropriate mathematical tools. The focus is on the following topics: Action of groups on sets and broken symmetries; Racah-Wigner approach to vibrations, electronic states, correlations and superconductivity in multicenter systems; crystallography and its extension.
A century after his birth, Ettore Majorana is rightfully considered one of the greatest physicists of the first half of the last century. With this volume the Italian Physical Society presents a collection of Ettore Majorana's scientific papers in the original language and, for the first time -- with three exceptions -- translated into English. Each paper is then followed by a comment in English of an expert in the scientific field.
This is the first book to provide comprehensive treatment of the use of the symmetric group in quantum chemical structures of atoms, molecules, and solids. It begins with the conventional Slater determinant approach and proceeds to the basics of the symmetric group and the construction of spin eigenfunctions. The heart of the book is in the chapter dealing with spin-free quantum chemistry showing the great interpretation value of this method. The last three chapters include the unitary group approach, the symmetric group approach, and the spin-coupled valence bond method. An extensive bibliography concludes the book.
Multiplets of Transition-Metal Ions in Crystals provides information pertinent to ligand field theory. This book discusses the fundamentals of quantum mechanics and the theory of atomic spectra. Comprised of 10 chapters, this book starts with an overview of the qualitative nature of the splitting of the energy level as well as the angular behavior of the wavefunctions. This text then examines the problem of obtaining the energy eigenvalues and eigenstates of the two-electron systems, in which two electrons are accommodated in the t2g and eg shells in a variety of ways. Other chapters discuss the ligand-field potential, which is invariant to any symmetry operation in the group to which symmetry of the system belongs. This book discusses as well the approximate method of expressing molecular orbitals (MO) by a suitable linear combination of atomic orbitals (AO). The final chapter discusses the MO in molecules and the self-consistent field theory of Hartree–Fock. This book is a valuable resource for research physicists, chemists, electronic engineers, and graduate students.
"Unabridged republication of the second edition of the work, originally published in the Pure and applied physics series by Academic Press, Inc., New York, in 1972"--Title page verso.
This volume continues the series of proceedings of summer schools on theoretical physics related to various aspects of the structure of condensed matter, and to appropriate mathematical methods for an adequate description. Three main topics are covered: (i) symmetric and unitary groups versus electron correlations in multicentre systems; (ii) conformal symmetries, the Bethe ansatz and quantum groups; (iii) paradoxes of statistics, space-time, and time quantum mechanics. Problems considered in previous schools are merged with some new developments, like statistics with continuous Young diagrams, the existence and structure of energy bands in solids with fullerenes, membranes and some coverings of graphite sheets, or vortex condensates with quantum counterparts of Maxwell lows.