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An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals?enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.
Recent years have seen huge growth in the area of sustainable chemistry. In order to meet the chemical needs of the global population whilst minimising impacts on health and the environment it is essential to keep reconsidering and improving synthetic processes. Sustainable Organic Synthesis is a comprehensive collection of contributions, provided by specialists in Green Chemistry, covering topics ranging from catalytic approaches to benign and alternative reaction media, and innovative and more efficient technologies.
Energy crises and global warming pose serious challenges to researchers in their attempt to develop a sustainable society for the future. Solar energy conversion is a remarkable, clean, and sustainable way to nullify the effects of fossil fuels. The findings of photocatalytic hydrogen production (PCHP) by Fujishima and Honda propose that “water will be the coal for the future”. Hydrogen is a carbon-free clean fuel with a high specific energy of combustion. Titanium oxide (TiO2), graphitic-carbon nitride (g-C3N4) and cadmium sulfide (CdS) are three pillars of water splitting photocatalysts owing to their superior electronic and optical properties. Tremendous research efforts have been made in recent years to fabricate visible or solar-light, active photocatalysts. The significant features of various oxide, sulfide, and carbon based photocatalysts for cost-effective hydrogen production are presented in this Special Issue. The insights of sacrificial agents on the hydrogen production efficiency of catalysts are also presented in this issue.
Focussing on catalysis through non-endangered metals, this book is an important reference for researchers working in catalysis and green chemistry.
Focussing on catalysis through non-endangered metals, this book is an important reference for researchers working in catalysis and green chemistry.
Focussing on catalysis without metals or other endangered elements, this book is an important reference for researchers working in catalysis and green chemistry.
Manganese Catalysis in Organic Synthesis A must-read reference for anyone interested in catalyst design and sustainable organic synthesis In Manganese Catalysis in Organic Synthesis, distinguished researcher Jean-Baptiste Sortais delivers an insightful and robust overview of the use of manganese in homogenous catalysis. The editor includes papers from authoritative academics describing the organometallic precursors used to develop manganese catalysts and covers critical applications in organic synthesis, including reduction to oxidation reactions, C-C, C-N, C-X bond formation reactions, cross-coupling reactions, C-H bond activation to dihydroxylation and epoxidation reactions. Manganese Catalysis in Organic Synthesis is a practical resource for every organic chemist in academia and industry with an interest in non-noble metal catalysis, organic synthesis, and sustainable chemistry. It is intuitively and clearly organized, covering the most important synthetic procedures using homogenous manganese catalysts. It is also the ideal companion to works like Cobalt Catalysis in Organic Synthesis, Nickel Catalysis in Organic Synthesis, and Iron Complexes in Catalysis. Readers will also enjoy: Thorough introductions to organometallic manganese compounds in organic synthesis and manganese-catalyzed hydrogenation and hydrogen transfer reactions A comprehensive exploration of manganese-catalyzed hydrogen borrowing reactions and dehydrogenative coupling reactions Practical discussions of manganese-catalyzed hydrosilylation and hydroboration reactions and manganese-catalyzed electro- and photocatalysis transformations In-depth examinations of manganese-catalyzed C-H oxygenation reactions and manganese-catalyzed organometallic C-H activation Insightful treatments of manganese-catalyzed cross-coupling processes and manganese(III) acetate mediated cyclizations Perfect for catalytic, organic, and pharmaceutical chemists, Manganese Catalysis in Organic Synthesis deserves a place in the libraries of researchers and professionals interested in catalyst design and sustainable organic synthesis.
"Electrocatalysts: From Fundamentals to Recent Advances. In the quest for sustainable hydrogen production, the challenge remains to identify new electrocatalysts for water electrolysis. While noble metals are the most effective catalysts for water splitting-a promising pathway to sustainable hydrogen production-they are expensive and scarce. Hence, there is a need to find environmentally friendly, earth abundant, highly stable, and economically viable alternatives. This book provides current state-of-the-art knowledge of a wide range of noble metal-free electrocatalysts for energy applications. Volume 2 reviews noble metal-free electrocatalysts for energy applications: thin films, metal-organic frameworks, metal hydroxides, and transition metal-doped nanocarbon-based electrocatalysts. Some emerging materials, such as perovskites and covalent organic framework-based electrocatalysts, are covered in detail, along with phosphide-based electrocatalysts and advances in electrocatalysts for flexible devices."--
It is well-established that organic synthetic processes have been at the core of the chemical industry for hundreds of years, in the production of organic compounds with a wide range of applications. However, we are becoming increasingly aware of the hazardous substances used and generated by these chemical processes. The field of organic synthesis has undergone profound changes to switch to equally efficient, but more sustainable processes that avoid the extensive use of toxic and hazardous reagents and solvents, harsh reaction conditions and expensive and sophisticated catalysts. Explaining methods for carrying out chemical syntheses without the use of catalysts, this book shows how avoiding catalysts during synthesis can mean less use of toxic chemicals, environmentally damaging chemicals or endangered elements and lower costs. It is an important reference for chemists involved in organic synthesis, as well as for green chemists.