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Borne out of the current widespread interest in the pollution of water bodies, this book explores the latest research concerning the photochemical fate of organic pollutants in surface water. The main objective is to give insight into both the functioning of ecosystems and the behaviour of emerging pollutants in those ecosystems. Particular importance is dedicated to techniques that can be used in the field and in the laboratory for the detection of pollutants and of their transformation intermediates. The inclusion of photochemical processes that have not gained previous coverage will afford the reader novel insights, whilst the focus on modelling and transformation intermediates will ensure the title's relevance to academics, the chemical manufacturing industries and environmental assessment experts alike.
Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.
Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada
Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.
Providing critical reviews of recent advances in photochemistry including organic and computational aspects, the latest volume in the Series reflects the current interests in this area. It also includes a series of highlights on molecular devices, global artificial photosynthesis, silicon nanoparticles, solar energy conversion, organic heterogeneous photocatalysis and photochemistry in surface-water environments. Volume 44 of the annual Specialist Periodical Reports: Photochemistry is essential reading for anyone wishing to keep up with the literature on photochemistry and its applications.
Pesticides in ground, surface and drinking water are a hot topic under continuing discussion. This complete and authoritative volume draws together information on all key issues on the fate and behaviour of pesticides in water systems. The scope of the practice-oriented contributions and the eminence of contributing authors make it an important source for researchers and practitioners in the plant protection and crop science field.
This monograph features what happens when light meets molecules. This edited volume contains contributions from an international array of contributors, and it is divided into sections representing a selection of carefully focussed and connected photochemistry topics: energy, technology, medicine, environmental sciences, and art. In each section one or more chapters illustrates relevant aspects of each field, such as artificial photosynthesis and solar energy conversion (energy), light emitting devices and photochromic dyes (technology), and photodynamic therapy and solar filters (medicine). Aimed at students of all levels and researchers active in photochemistry.
Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environ mental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities of waste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.
Globally, 2.1 billion people live without access to safe water, and about 159 million people collect their drinking water directly from surface water sources. This issue is particularly prominent in water-stressed areas, such as India, which has a rural population of around 700 million, 63 million of whom do not have access to clean water. Contaminants of Emerging Concern (CECs), of both a chemical and biological nature, are increasingly being detected in wastewater effluents around the world. Chemical CECs include pollutants such as pharmaceuticals and personal care products, pesticides, hormones, and endocrine disruptors, and biological CECs include antibiotic resistant bacteria, pathogenic protozoans, and viruses. New technologies to remove the contaminants from water are urgently needed and photochemical approaches offer an exciting array of possibilities. Covering chemical analysis, molecular biology methods and computational approaches important for the elucidation of mechanisms and evaluation of photochemical processes, this book presents advanced photochemical processes for the removal of CECs from water. Readers will find chapters on advanced photochemical treatment prototypes and pilot plants, and discussions on translation from lab to field-scale implementation. Examples include highly transparent materials, integrated membranes, adsorbents, and photocatalysts for enhancing the photochemical processes by direct sunlight induced reactions, photo-Fenton, and photo-electrochemical reactions. Discussing both the advantages and disadvantages of these technologies, this book is a great resource both for academics researching photocatalytic processes and for water treatment professionals.
Marine dissolved organic matter (DOM) is a complex mixture of molecules found throughout the world's oceans. It plays a key role in the export, distribution, and sequestration of carbon in the oceanic water column, posited to be a source of atmospheric climate regulation. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, focuses on the chemical constituents of DOM and its biogeochemical, biological, and ecological significance in the global ocean, and provides a single, unique source for the references, information, and informed judgments of the community of marine biogeochemists. Presented by some of the world's leading scientists, this revised edition reports on the major advances in this area and includes new chapters covering the role of DOM in ancient ocean carbon cycles, the long term stability of marine DOM, the biophysical dynamics of DOM, fluvial DOM qualities and fate, and the Mediterranean Sea. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, is an extremely useful resource that helps people interested in the largest pool of active carbon on the planet (DOC) get a firm grounding on the general paradigms and many of the relevant references on this topic. - Features up-to-date knowledge of DOM, including five new chapters - The only published work to synthesize recent research on dissolved organic carbon in the Mediterranean Sea - Includes chapters that address inputs from freshwater terrestrial DOM