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A guide to modifying and functionalizing the surfaces of polymers Surface Modification of Polymers is an essential guide to the myriad methods that can be employed to modify and functionalize the surfaces of polymers. The functionalization of polymer surfaces is often required for applications in sensors, membranes, medicinal devices, and others. The contributors?noted experts on the topic?describe the polymer surface in detail and discuss the internal and external factors that influence surface properties. This comprehensive guide to the most important methods for the introduction of new functionalities is an authoritative resource for everyone working in the field. This book explores many applications, including the plasma polymerization technique, organic surface functionalization by initiated chemical vapor deposition, photoinduced functionalization on polymer surfaces, functionalization of polymers by hydrolysis, aminolysis, reduction, oxidation, surface modification of nanoparticles, and many more. Inside, readers will find information on various applications in the biomedical field, food science, and membrane science. This important book: -Offers a range of polymer functionalization methods for biomedical applications, water filtration membranes, and food science -Contains discussions of the key surface modification methods, including plasma and chemical techniques, as well as applications for nanotechnology, environmental filtration, food science, and biomedicine -Includes contributions from a team of international renowned experts Written for polymer chemists, materials scientists, plasma physicists, analytical chemists, surface physicists, and surface chemists, Surface Modification of Polymers offers a comprehensive and application-oriented review of the important functionalization methods with a special focus on biomedical applications, membrane science, and food science.
Medical Nanotechnology and Nanomedicine introduces non-experts to the world of nanomedicine and its evolving organizational infrastructure. Considering the fluid nature of nano breakthroughs and the delicate balance between benefits and consequences as they apply to medicine, readers at all levels will gain a practical, understandable base of information on these developments so that they may take the greatest advantage of them. This practical reference investigates the impact of nanotechnology on applications in medicine and biomedical sciences, and the broader societal and economic effects. Eschewing technological details, it focuses on enhancing awareness of the business, regulatory, and administrative aspects of medical applications. It gives readers a critical, balanced, and realistic evaluation of existing nanomedicine developments and future prospects and provides an ideal foundation upon which to plan and make decisions.
This book contains selected contributions on surface modification to improve the properties of solid materials. The surface properties are tailored either by functionalization, etching, or deposition of a thin coating. Functionalization is achieved by a brief treatment with non-equilibrium gaseous plasma containing suitable radicals that interact chemically with the material surface and thus enable the formation of rather stable functional groups. Etching is performed in order to modify the surface morphology. The etching parameters are selected in such a way that a rich morphology of the surfaces is achieved spontaneously on the sub-micrometer scale, without using masks. The combination of adequate surface morphology and functionalization of materials leads to superior surface properties which are particularly beneficial for the desired response upon incubation with biological matter. Alternatively, the materials are coated with a suitable thin film that is useful in various applications from food to aerospace industries.
Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.
Comprising one volume of Functional and Modified Polymeric Materials, Two-Volume Set, this well-organized collection of papers by Professor Eli Ruckenstein and co-workers focuses on functional and modified polymeric materials prepared mainly through solution polymerization and surface polymerization. Although solution polymerization has been broadly utilized for the preparation of polymeric materials, the book shows significant approaches to special classes of polymeric materials including functional polymers by living ionic polymerization, degradable and decrosslinkable polymers, semi- and interpenetrating polymer network pervaporation membranes, and soluble conducting polymers. It also focuses on preparing and modifying conductive surface of polymer or polymer-based materials.
The method of CVD (chemical vapor deposition) is a versatile technique to fabricate high-quality thin films and structured surfaces in the nanometer regime from the vapor phase. Already widely used for the deposition of inorganic materials in the semiconductor industry, CVD has become the method of choice in many applications to process polymers as well. This highly scalable technique allows for synthesizing high-purity, defect-free films and for systematically tuning their chemical, mechanical and physical properties. In addition, vapor phase processing is critical for the deposition of insoluble materials including fluoropolymers, electrically conductive polymers, and highly crosslinked organic networks. Furthermore, CVD enables the coating of substrates which would otherwise dissolve or swell upon exposure to solvents. The scope of the book encompasses CVD polymerization processes which directly translate the chemical mechanisms of traditional polymer synthesis and organic synthesis in homogeneous liquids into heterogeneous processes for the modification of solid surfaces. The book is structured into four parts, complemented by an introductory overview of the diverse process strategies for CVD of polymeric materials. The first part on the fundamentals of CVD polymers is followed by a detailed coverage of the materials chemistry of CVD polymers, including the main synthesis mechanisms and the resultant classes of materials. The third part focuses on the applications of these materials such as membrane modification and device fabrication. The final part discusses the potential for scale-up and commercialization of CVD polymers.
The surface of textiles offers an important platform for functional modifications in order to meet special requirements for a variety of applications. The surface modification of textiles may be achieved by various techniques ranging from traditional solution treatment to biological approaches. This book reviews fundamental issues relating to textile surfaces and their characterisation and explores the exciting opportunities for surface modification of a range of different textiles.Introductory chapters review some important surface modification techniques employed for improved functional behaviour of textiles and the various surface characterisation methods available. Further chapters examine the different types of surface modification suitable for textiles, ranging from the use of plasma treatments and physical vapour deposition to the use of nanoparticles. Concluding chapters discuss surface modification strategies for various applications of textiles.Surface modification of textiles is a valuable resource for chemists, surface scientists, textile technologists, fibre scientists, textile engineers and textile students. - Reviews fundamental issues relating to textiles surfaces and their characterisation - Examines various types of surface modification suitable for textiles, including plasma treatments and nanoparticles - Discusses surface modification strategies for textile applications such as expansion into technical textile applications
A review of the various methodologies for the surface treatment of different types of inorganic spherical and fibrous fillers, describing ball milling, cationic polymerization, vapor phase grafting, plasma treatment and UV irradiation in detail. In addition, the book connects the resulting composite properties to the modified filler surface properties, thus allowing for a purposeful, application-oriented composite design.
Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Biodegradable and Biocompatible Polymer Composites: Processing, Properties and Applications begins by discussing the current state-of-the-art, new challenges and opportunities for various biodegradable and biocompatible polymer composite systems. Interfacial characterization of composites and the structure-property relationships in various composite systems are explained in detail via a theoretical model. Processing techniques for various macro and nanocomposite systems and the influence of processing parameters on properties of the composite are also reviewed in detail. The characterization of microstructure, elastic, visco-elastic, static and dynamic mechanical, thermal, rheological, optical, and electrical properties are highlighted, as are a broad range of applications. The book is a useful reference resource for both researchers and engineers working in composites materials science, biotechnology and nanotechnology, and is also useful for students attending chemistry, physics, and materials science and engineering courses. - Presents recent outcomes and highlights the going importance of biodegradable and biocompatible polymer composites and their impact on the environment - Analyzes all the main processing techniques, characterization and applications of biodegradable composites - Written by leading international experts working in the field of biodegradable and biocompatible polymer composites - Covers a broad range of application fields, including medical and pharmaceutical, agricultural, packaging and transport