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In my research, I have performed many characterization and fabrication experiments that are based on tools of analytical chemistry, materials chemistry, and surface science. My research projects are as follows. (1) Fabrication of transparent polymer templates for nanostructured amorphous silicon photovoltaics was done using low-cost nanoimprint lithography of polydimethylsiloxane. This approach provides a test bed for absorption studies in nanostructured film geometries and should result in improved light capturing designs in thin-film solar cells. Nanopatterned polymer films were characterized by scanning electron microscopy and optical measurements. (2) A straightforward method for fabricating freely suspended, thin, carbon nanotube (CNT) membranes infiltrated with polymers was developed. This process is a new approach for making thin, reinforced, smooth films or membranes with high concentrations of CNTs, which may lead to higher performance materials. Characterization of the film and membrane was performed via scanning electron microscopy and atomic force microscopy. (3) Laser activation-modification of semiconductor surfaces (LAMSS) was carried out on silicon with a series of 1-alkenes. A key finding from this study is that the degree of surface functionalization in a LAMSS spot appears to decrease radially from the center of the spot. These laser spots were studied by time of flight secondary ion mass spectrometry (ToF-SIMS), and the resulting spectra were analyzed using a series of chemometrics methods. (4) A large ToF-SIMS data set from multiple coal samples spanning a wide range of coal properties was subjected to a chemometrics analysis. This analysis separates the spectra into clusters that correspond to measurements from classical combustion analyses. Thus ToF-SIMS appears to be a promising technique for analysis of this important fuel. (5) Several experiments on carbon nanotube processing were performed in my research, including carbon nanotube sheet formation, carbon nanotube purification, carbon nanotube dispersion, and carbon nanotube functionalization. X-ray photoelectron spectroscopy was a key characterization tool for many of these experiments.
Manufacturing of Nanocomposites with Engineering Plastics collates recent research findings on the manufacturing, properties, and applications of nanocomposites with engineering plastics in one comprehensive volume. The book specifically examines topics of engineering plastics, rheology, thermo-mechanical properties, wear, flame retardancy, modeling, filler surface modification, and more. It represents a ready reference for managers and scholars working in the areas of polymer and nanocomposite materials science, both in industry and academia, and provides introductory information for people new to the field. Provides a comprehensive review of the most recent research findings A single one-stop ready reference that assimilates knowledge on the development of nanocomposites with engineering plastics Contributions from leading experts in the field Provides examples of applications that will help with material selection Chapters are designed to provide not only introductory information, but also to lead the reader to more advanced characterization tools
Polymer nanocomposites are a class of material with a great deal of promise for potential applications in various industries ranging from construction to aerospace. The main difference between polymeric nanocomposites and conventional composites is the filler that is being used for reinforcement. In the nanocomposites the reinforcement is on the order of nanometer that leads to a very different final macroscopic property. Due to this unique feature polymeric nanocomposites have been studied exclusively in the last decade using various nanofillers such as minerals, sheets or fibers. This books focuses on the preparation and property analysis of polymer nanocomposites with CNTs (fibers) as nano fillers. The book has been divided into three sections. The first section deals with fabrication and property analysis of new carbon nanotube structures. The second section deals with preparation and characterization of polymer composites with CNTs followed by the various applications of polymers with CNTs in the third section.
Papers presented at the Seventeenth International Symposium on Processing and Fabrication of Advanced Material XVII, held at New Delhi during 15-17 December 2008.
ABSTRACT: The design, fabrication, and characterization of polymer-carbon nanotube (CNT) composites have generated a significant amount of attention in the fields of materials science and polymer chemistry. The challenge in fabricating composites that exploit the unique properties of the CNT and the ideal processing ability and low cost of the polymer is in achieving a uniform dispersion of the filler in the polymer matrix. This body of work focuses on (1) techniques employed to disperse CNTs into a polymer matrix and (2) the effects of CNTs on the mechanical and electrical properties of the polymer. Poly (methyl methacrylate) (PMMA), an amorphous polymer, and poly (4-methyl-1-pentene) (P4M1P), a semi crystalline polymer, were chosen as the matrices. Non-functionalized single-walled carbon nanotubes and soot (unpurified carbon nanotubes) were chosen as the filler material.
The book series "Polymer Nano-, Micro- and Macrocomposites" provides complete and comprehensive information on all important aspects of polymer composite research and development, including, but not limited to, synthesis, filler modification, modeling, characterization as well as application and commercialization issues. Each book focuses on a particular topic and gives a balanced in-depth overview of the respective subfield of polymer composite science and its relation to industrial applications. With the books the readers obtain dedicated resources with infomation relevant to their research, thereby helping to save time and money. In this first volume in the series, authors from leading academic institutions and companies share their first-hand knowledge of nanotube-surface enhancements for use in polymer composites. All the important methods for the functionalization of nanotube fillers, including polymer wrapping, non-covalent modification with nanoparticles, silica layers or entrapped micelles, chemically induced growth of multilayers, techniques based on covalent bonding, such as polmer or quantum dot attachment, and direct polymerization approaches are covered.
Surface modification is a good way to introduce desired physical, chemical or biological properties to materials without changing the characteristics of the bulk. Modifying polymer surfaces has drawn much attention because this process gives the potential to further increase the versatility of polymer materials. My work focuses on using colloidal nanoparticles to functionalize polyamide water treatment membranes and polycarbonate plastic sheets with nanoparticles with different purposes. Specifically, modifying polyamide membranes with colloidal copper nanoparticles or positively charged silica are described in the first part of this thesis. Coating polycarbonate sheets with positively charged silica nanoparticles is discussed in the second part. Fabrication and characterization of these nanoparticle functionalized substrates will be emphasized.
Carbon Nanotube-Reinforced Polymers: From Nanoscale to Macroscale addresses the advances in nanotechnology that have led to the development of a new class of composite materials known as CNT-reinforced polymers. The low density and high aspect ratio, together with their exceptional mechanical, electrical and thermal properties, render carbon nanotubes as a good reinforcing agent for composites. In addition, these simulation and modeling techniques play a significant role in characterizing their properties and understanding their mechanical behavior, and are thus discussed and demonstrated in this comprehensive book that presents the state-of-the-art research in the field of modeling, characterization and processing. The book separates the theoretical studies on the mechanical properties of CNTs and their composites into atomistic modeling and continuum mechanics-based approaches, including both analytical and numerical ones, along with multi-scale modeling techniques. Different efforts have been done in this field to address the mechanical behavior of isolated CNTs and their composites by numerous researchers, signaling that this area of study is ongoing. Explains modeling approaches to carbon nanotubes, together with their application, strengths and limitations Outlines the properties of different carbon nanotube-based composites, exploring how they are used in the mechanical and structural components Analyzes the behavior of carbon nanotube-based composites in different conditions
New hybrid materials from the grafting of polystyrene on the surface of nitrogen doped carbon nanotube were synthesized. These chemically modified nanotubes were further used in the fabrication of polymer based nanocomposites. In these works, we studied the impact of the polymer grafted nanotubes on the electrical and mechanical properties of a polystyrene (PS) and a poly (butadiene-co-styrene) (PSBS) matrices. The grafted nanotubes have a better dispersion in a PS matrix as compared to the as received ones. Nevertheless, this kind of functionalization does not lower the percolation threshold since the grafted polymer layer electrically isolates the nanotubes each others. On the other hand, the mechanical reinforcement (PS matrix) increases when the nanotubes are polymer grafted. Furthermore, a stronger mechanical reinforcement is observed for large strain deformation. Concerning the nano-structured PSBS matrix, we observed a stronger mechanical reinforcement as compared to the PS matrix. The PS grafted nanotubes permit to connect the PS nano-domains of the matrix and consequently forms a percolating rigid network with a very low threshold (PC
In addition to the cAFM patterned surfaces, full monolayers of undecylenic acid methyl ester (SAM-1) and undec-10-enoic acid 2-bromoethyl ester (SAM-2) were grown on H:Si(111) substrates using ultraviolet light. The structure and chemistry of the monolayers were characterized using AFM, TOF SIMS, X-ray photoelectron spectroscopy (XPS), X-ray reflectivity (XRR), X-ray standing waves (XSW), and X-ray fluorescence (XRF). These combined analyses provide evidence that SAM-1 and SAM-2 form dense monolayers with areal densities corresponding to 50% and 57% of the Si(111) surface bonds. XPS and XSW analyses of SAM-2 reveal that Br abstraction by reactive silicon dangling bonds competes with olefin addition to the surface so that 0.48 monolayer (ML) of a total Br coverage of 0.58 ML is bound to the Si(111) lattice position.