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Intermolecular and Surface Forces describes the role of various intermolecular and interparticle forces in determining the properties of simple systems such as gases, liquids and solids, with a special focus on more complex colloidal, polymeric and biological systems. The book provides a thorough foundation in theories and concepts of intermolecular forces, allowing researchers and students to recognize which forces are important in any particular system, as well as how to control these forces. This third edition is expanded into three sections and contains five new chapters over the previous edition. - Starts from the basics and builds up to more complex systems - Covers all aspects of intermolecular and interparticle forces both at the fundamental and applied levels - Multidisciplinary approach: bringing together and unifying phenomena from different fields - This new edition has an expanded Part III and new chapters on non-equilibrium (dynamic) interactions, and tribology (friction forces)
This monograph is devoted to long-range surface forces sig nificant far beyond a single monolayer and felt over tens or even hundreds of molecular layers adjacent to an interface. The transi tion from the concept of short-range effects that reigned earlier to the concept of long-range forces simultaneously signified the transition from a two-dimensional world to a three-dimensional one, incomparably richer in physicochemical phenomena. This transition took many years and evolved through many steps. It began with the Gouy-Chapman theory of diffuse ionic atmospheres, which together with London's theory of molecular forces was used as a basis for the development (beginning in 1937) of the DLVO theory of stability of lyophobic colloids. Further elaboration of the theory involved the introduction of new types of force, and a generalization (in 1954) to the case of interaction between unlike particles (hetero coagulation). This theory is fundamental in such large-scale prac tical problems as flotation, water treatment, dyeing, soil science, microbiology, and interaction between biological cells. This book is the first comprehensive monograph devoted to sur face forces. This fact makes it easier to attract the reader's interest; yet, the reader's demands become all the more difficult to satisfy completely. Indeed, the research that we review and analyze here covers about 50 years of work. Much data has been amassed, so that the main problem was a careful selection and an alysis.
A general introduction to surface and interfacial forces, perfectly combining theoretical concepts, experimental techniques and practical applications. In this completely updated edition all the chapters have been thoroughly revised and extended to cover new developments and approaches with around 15% new content. A large part of the book is devoted to surface forces between solid surfaces in liquid media, and while a basic knowledge of colloid and interface science is helpful, it is not essential since all important concepts are explained and the theoretical concepts can be understood with an intermediate knowledge of mathematics. A number of exercises with solutions and the end-of-chapter summaries of the most important equations, facts and phenomena serve as additional tools to strengthen the acquired knowledge and allow for self-study. The result is a readily accessible text that helps to foster an understanding of the intricacies of this highly relevant topic.
This book describes intermolecular and interparticle forces in determining the properties of systems such as gases, liquids and solids and of colloidal, polymeric and biological systems. The text includes developments on surface-force measurements, solvation and structural forces, hydration and hydrophobic forces, and ion-correlation forces.
This reference describes the role of various intermolecular and interparticle forces in determining the properties of simple systems such as gases, liquids and solids, with a special focus on more complex colloidal, polymeric and biological systems. The book provides a thorough foundation in theories and concepts of intermolecular forces, allowing researchers and students to recognize which forces are important in any particular system, as well as how to control these forces. This third edition is expanded into three sections and contains five new chapters over the previous edition. - Starts from the basics and builds up to more complex systems - Covers all aspects of intermolecular and interparticle forces both at the fundamental and applied levels - Multidisciplinary approach: bringing together and unifying phenomena from different fields - This new edition has an expanded Part III and new chapters on non-equilibrium (dynamic) interactions, and tribology (friction forces)
A general introduction to surface and interfacial forces, perfectly combining theoretical concepts, experimental techniques and practical applications. In this completely updated edition all the chapters have been thoroughly revised and extended to cover new developments and approaches with around 15% new content. A large part of the book is devoted to surface forces between solid surfaces in liquid media, and while a basic knowledge of colloid and interface science is helpful, it is not essential since all important concepts are explained and the theoretical concepts can be understood with an intermediate knowledge of mathematics. A number of exercises with solutions and the end-of-chapter summaries of the most important equations, facts and phenomena serve as additional tools to strengthen the acquired knowledge and allow for self-study. The result is a readily accessible text that helps to foster an understanding of the intricacies of this highly relevant topic.
This book focuses on the emerging class of new materials characterized by ultra-fine microstrucures. The NATO ASI which produced this book was the first international scientific meeting devoted to a discussion of the mechanical properties and deformation behavior of materials having grain sizes down to a few nanometers. Topics covered include superplasticity, tribology, and the supermodulus effect. Review chapters cover a variety of other themes including synthesis, characterization, thermodynamic stability, and general physical properties. Much of the work is concerned with the issue of how far conventional techniques and concepts can be extended toward atomic scale probing. Another key issue concerns the structure of nanocrystalline materials, in particular, what is the structure and composition of the internal boundaries. These ultra-fine microstructures have proved to challenge even the finest probes that the materials science community has today.
This systematic introduction to the topic includes theoretical concepts to help readers understand and predict surface forces, while also integrating experimental techniques and practical applications with up-to-date examples plus motivating exercises. Starting with intermolecular forces, the authors discuss different surfaces forces, with a major part devoted to surface forces between solid surfaces in liquid media. In addition, they cover surface forces between liquid-vapor interfaces and between liquid-liquid interfaces.
Activity in the arena of surface chemistry and adhesion aspects in cosmetics is substantial, but the information is scattered in many diverse publications media and no book exists which discusses surface chemistry and adhesion in cosmetics in unified manner. This book containing 15 chapters written by eminent researchers from academia and industry is divided into three parts: Part 1: General Topics; Part 2: Surface Chemistry Aspects; and Part 3: Wetting and Adhesion Aspects. The topics covered include: Lip biophysical properties and characterization; use of advanced silicone materials in long-lasting cosmetics; non-aqueous dispersions of acrylate copolymers in lipsticks; cosmetic oils in Lipstick structure; chemical structure of the hair surface, surface forces and interactions; AFM for hair surface characterization; application of AFM in characterizing hair, skin and cosmetic deposition; SIMS as a surface analysis method for hair, skin and cosmetics; surface tensiometry approach to characterize cosmetic products; spreading of hairsprays on hair; color transfer from long-wear face foundation products; interaction of polyelectrolytes and surfactants on hair surfaces; cosmetic adhesion to facial skin; and adhesion aspects in semi-permanent mascara; lipstick adhesion measurement.