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This is the most updated, comprehensive collection of monographs on all aspects of photochemistry and photophysics related to natural and synthetic, inorganic, organic, and biological supramolecular systems. Supramolecular Photochemistry: Controlling Photochemical Processes addresses reactions in crystals, organized assemblies, monolayers, zeolites, clays, silica, micelles, polymers, dendrimers, organic hosts, supramolecular structures, organic glass, proteins and DNA, and applications of photosystems in confined media. This landmark publication describes the past, present, and future of this growing interdisciplinary area.
Addressing critical aspects of computational modeling in photochemistry, Molecular Methods in Photochemistry is designed to familiarize researchers and practitioners with state-of-the-art computational methods to predict the reactivity of excited molecules. It provides practical guidelines and examples for the modeling of excited states and describ
With contributions from 24 international authorities, Synthetic Organic Photochemistry offers a leading-edge presentation of the most recent and in-demand applications of photochemical methodologies. Outlining a wide assortment of reaction types entailing cycloadditions, cyclizations, isomerizations, rearrangements, and other organic syntheses, thi
Focuses on complex naturally occurring and synthetic supramolecular arrays. The text describes applications of photochemistry in cystalline organic matrices; covers two-component crystals - crystalline molecular compounds, mixed crystals and simple mechanical mixtures - in solid and liquid phases; assesses photoinduced fragmentation of carbon-heteroatom bonds; and more.
Featuring contributions from leading experts, Organic Photochemistry and Photophysics is a unique resource that addresses the organic photochemistry and photophysical behavior in aromatic molecules, thiocarbonyls, selected porphyrins, and metalloporphyrins. The book presents theories pertaining to radiative and radiationless transitions. It
The intellectual and utilitarian opportunities that lie at the frontiers of chemistry have been recently emphasized by the Pimentel Report. Such report recommends that in the field of chemical research priority should be given to "understanding chemical reactivity" and proposes initiatives aimed at the clarification of factors that control the rates of reaction and the development of new synthetic pathways for chemical change. In the broad field of chemical reactivity, a discipline that has grown with an extraordinary rate is photochemistry. Since the knowledge of the photochemical properties at the molecular level has made a substantial progress in the last few years, there is currently a trend to study more and more complex photochemical systems. In particular, an emerging and rapidly expanding branch of photochemistry is that concerning studies of assemblies of molecular components properly combined so as to obtain light-induced functions (supramolecular photochemistry). Although much of the current work in supramolecular photochemistry is fundamental in nature, it is clear that progress in this field will be most rewarding for several applications concerning the interaction of light with matter. In particular, it will allow us to pursue research aimed at the photochemical conversion of solar energy by means of artificial systems and to make progress towards futuristic branches of science called "photonics" (photo-generated electron migration processes on a molecular basis) and "chemionics" (design of components, circuitry, and information treatment at the molecular level).
Focusing on complex naturally-occurring and synthetic supramolecular arrays, this work describes the mechanism by which transition metal complexes bind to DNA and how the DNA scaffold modifies the photochemical and photophysical properties to bound complexes. It includes details of photoinduced electron transfer between intercalated molecules, and examines thermally and photochemically induced electron transfer in supramolecular assemblies consisting of inorganic molecular building blocks.
The Exploration of Supramolecular Systems and Nanostructures by Photochemical Techniques provides a comprehensive view of the most commonly used photochemical and photophysical techniques and their applications to the study of supramolecular systems. Optical inputs are extremely powerful in the study of nanostructures since they can be used both to “read” the state of the system and to provide it energy to work. After a brief introduction to the realm of photochemistry, electronically excited state formation and the different pathways of excited state deactivation, the book focuses on the theoretical basis and the practical aspects related to the most widely used photophysical and photochemical techniques, from absorption to time-resolved emission techniques with polarized light. Each chapter illustrates an example of the application of that particular technique to the study of a supramolecular system. The Exploration of Supramolecular Systems and Nanostructures by Photochemical Techniques not only discusses the latest advances of the field of supramolecular photochemistry but it also offers technical and operative details useful in the laboratory. It is therefore suitable for both the novice and the expert.
The second edition of "Analytical Methods in Supramolecular Chemistry" comes in two volumes and covers a broad range of modern methods and techniques now used for investigating supramolecular systems, e. g. NMR spectroscopy, mass spectrometry, extraction methods, crystallography, single molecule spectroscopy, electrochemisty, and many more. In this second edition, tutorial inserts have been introduced, making the book also suitable as supplementary reading for courses on supramolecular chemistry. All chapters have been revised and updated and four new chapters have been added. A must-have handbook for Organic and Analytical Chemists, Spectroscopists, Materials Scientists, and Ph.D. Students in Chemistry. From reviews of the first edition: "This timely book should have its place in laboratories dealing with supramolecular objects. It will be a source of reference for graduate students and more experienced researchers and could induce new ideas on the use of techniques other than those usually used in the laboratory." Journal of the American Chemical Society (2008) VOL. 130, NO. 1 doi: 10.1021/ja0769649 "The book as a whole or single chapters will stimulate the reader to widen his horizon in chemistry and will help him to have new ideas in his research." Anal Bioanal Chem (2007) 389:2039-2040 DOI: 10.1007/s00216-007-1677-1
Ein Lehrbuch eines exzellenten Autorenteams mit wissenschaftlicher Erfahrung und der Kompetenz im Schreiben didaktischer Texte zu allen Facetten der Photochemie und Photophysik: Grundlagen sowie ausgewählte Beispielen moderner Anwendungen und aus der heutigen Forschung.