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Perspectives in Supramolecular Chemistry relates recent developments and new exciting approaches in supramolecular chemistry. The series covers all areas from theoretical and modelling aspects through organic and inorganic chemistry and biochemistry to materials, solid-state and polymer sciences reflecting the many and varied applications of supramolecular structures in modern chemistry. From the early days of supramolecular chemistry the field has been associated with possible applications. This is not surprising as the design of new molecules, and later of assemblies of molecules, is often function-driven. Now, after three decades of supramolecular chemistry, David Reinhoudt has brought together a collection of reviews to reflect on the applications that have actually been achieved. The first applications in molecular recognition are now established technologies in analytical chemistry, separation science and medicine. More recently, developments have taken place in material design and these concepts are also discussed here. Contents * Self-Assembling Systems on Scales from Nanometers to Millimeters: Design and Discovery * Dendritic Architectures * Supramolecular Structures with Macromolecules * Chemosensors: Synthetic Receptors in Analytical Sensing Applications * Selective Ion Recognition with Durable Sensors * Ion Separations in Membrane and Solid Phase Extraction Systems * Porphyrin- and Expanded Pophyrin-Based Diagnostic and Therapeutic Agents Supramolecular Materials and Technologies illustrates the achievements and advances that supramolecular chemistry has made in many fields from organic chemistry to materials science and from analytical chemistry to molecular biology.
Supra-materials Nanoarchitectonics provides the latest information on design at the nanoscale, presenting a range of the new challenges that arise as the manipulation techniques that work at the macro- and micro-scale do not work at the nanoscale. The term nanoarchitectonics, coined by Japan's National Institute for Materials Science (NIMS), describes the organized interactions required at the nanoscale, replacing the traditional structure-building approach used in materials design. Nanoarchitectonics approaches material design via a profound understanding of the interactions between individual nanostructures and their organization. As the nanoarchitectonics paradigm fits well with the discipline of supramolecular chemistry, this book brings together these two approaches to demonstrate the potential of supramolecular nanoarchitectonics in the development of new materials, both at the nano- and macro-scale. - Written by the team that coined the term nanoarchitectonics, providing a detailed explanation of the approach and techniques of supramolecular nanoarchitectonics - Demystifies materials design via organized interactions at the nanoscale - Explains this new paradigm via practical scientific techniques
A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.
Advanced Supramolecular Nanoarchitectonics provides the latest information on design at the nanoscale, presenting a range of the new challenges that arise when the manipulation techniques that work at the macro- and micro-scale do not work at the nanoscale. Nanoarchitectonics approaches material design via a profound understanding of the interactions between individual nanostructures and their organization. This book presents the more advanced features of this research paradigm, focusing on the materials fabrication of self-defined nanostructures and demonstrating possible applications of these fabricated materials. - Written by the team that coined the term nanoarchitectonics, providing a detailed explanation of the approach and techniques of supramolecular nanoarchitectonics - Focuses on the fabrication of materials with defined structures via organized interactions at the nanoscale - Demonstrates current and potential applications of nanoarchitected materials
In the last decade, much progress has been made in these materials. This book presents a highly coherent coverage of supramolecular, photosensitive and electroactive materials, namely those that have been extensively investigated for applications in fields of electronic and photonic technologies. This extensive reference provides broad coverage of on different types of materials, their processing, spectroscopic characterization, physical properties and device applications.The implications reach from molecular recognition in synthetic and natural complexes to exciting new applications in chemical technologies, materials, nanostructures, functional materials, new generation catalysts, signal transducers, medical and biomedical applications and novel separation techniques. All these applications rely on supramolecular properties such as molecular recognition, molecular information, and tailored molecular assemblies.This book is aimed to present a highly coherent coverage of supramolecular, photosenstive and electroactive materials and their applications in electronic and photonic technologies. The research behind these materials constitute some of the most actively pursued fields of science.Key Features* Covers supramolecular photosensitive and electroactive materials* Provides recent developments on metallophthalocyanines and polydiacetylenes* Include various types of supramolecular materials, their processing, fabrication, physical properties and device applications* Role of polyimides in microelectronic and tribology* Describes Photosynthetic and respiratory proteins, Dendrimers* A very special topic presented in a timely manner and in a format
For years, concepts and models relevant to the fields of molecular electronics and organic electronics have been invented in parallel, slowing down progress in the field. This book illustrates how synthetic chemists, materials scientists, physicists, and device engineers can work together to reach their desired, shared goals, and provides the knowledge and intellectual basis for this venture. Supramolecular Materials for Opto-Electronics covers the basic principles of building supramolecular organic systems that fulfil the requirements of the targeted opto-electronic function; specific material properties based on the fundamental synthesis and assembly processes; and provides an overview of the current uses of supramolecular materials in opto-electronic devices. To conclude, a “what’s next” section provides an outlook on the future of the field, outlining the ways overarching work between research disciplines can be utilised. Postgraduate researchers and academics will appreciate the fundamental insight into concepts and practices of supramolecular systems for opto-electronic device integration.
Non-covalent interactions, which are the heart of supramolecular chemistry are also the basis of most important functions of living systems. The ability to apply supramolecular chemistry principles to the life sciences, such as designing synthetic host compounds to selectively interact within biological targets, has gained wide appeal due the vast number of potential applications. Supramolecular Systems for Biomedical Fields provides in sixteen chapters a comprehensive overview of these applications. Each chapter covers a specific topic and is written by internationally renowned experts in that area. Sensing of bioactive inorganic ions and organic substrates is the focus of several contributions, as well as interactions with proteins and nucleic acids. Specific chapters are devoted to cyclodextrins, calixarenes and cucurbiturils as most frequently used receptors, including applications such as drug delivery and protection, gene transfer and others. Other chapters address the use of combinatorial libraries, molecular imprinting techniques, enzyme assays, supramolecular gels, bioimaging, drug activation, photodynamic therapy, and antitumour metal complexes. This timely publication will appeal to graduate students and researchers from chemical, pharmaceutical, biological, and medicinal fields interested in the supramolecular chemistry of biological systems and their practical potentials.
Supramolecular catalysis is involved in assimilation or growth of biological products and it has advantages over conventional catalysis in dealing with systems beyond molecules to mimic the biological catalytic processes. Principles and Advances in Supramolecular Catalysis shows how a supramolecular catalytic reaction proceeds and how interactions among molecules provide vessels or specific binding sites to carry out chemical reactions. The utilities of such catalytic reactions in waste, hazard management, medicine, food, etc. are explained in this book. The book focuses on examples to provide a fundamental basis so that, in the future, supramolecular catalytic reactions are utilised in the field of chemical, biological, biophysical sciences and technologies. Features: Discusses fundamental and interdisciplinary aspects of supramolecular catalysis Narrates mechano-chemical and stimuli-guided supramolecular catalytic reactions Divulges the intriguing aspects of self-replications and self-assembling performed through supramolecular catalysis Incorporates supramolecular catalytic reactions of metal-organic frameworks as artificial metalloenzymes
Materials Nanoarchitectonics: From Integrated Molecular Systems to Advanced Devices provides the latest information on the design and molecular manipulation of self-organized hierarchically structured systems using tailor-made nanoscale materials as structural and functional units. The book is organized into three main sections that focus on molecular design of building blocks and hybrid materials, formation of nanostructures, and applications and devices. Bringing together emerging materials, synthetic aspects, nanostructure strategies, and applications, the book aims to support further progress, by offering different perspectives and a strong interdisciplinary approach to this rapidly growing area of innovation. This is an extremely valuable resource for researchers, advanced students, and scientists in industry, with an interest in nanoarchitectonics, nanostructures, and nanomaterials, or across the areas of nanotechnology, chemistry, surface science, polymer science, electrical engineering, physics, chemical engineering, and materials science. - Offers a nanoarchitectonic perspective on emerging fields, such as metal-organic frameworks, porous polymer materials, or biomimetic nanostructures - Discusses different approaches to utilizing "soft chemistry" as a source for hierarchically organized materials - Offers an interdisciplinary approach to the design and construction of integrated chemical nano systems - Discusses novel approaches towards the creation of complex multiscale architectures
The fundamentals of "supramolecular chemistry" to the latest developments on the subject are covered by this book. It sets out to explain the topic in a relatively easy way. The basic concepts of molecular recognition chemistry are included. Molecules with fascinating shapes and functions such as fullerenes, carbon nanotubes, dendrimers, rotaxane, and catenane, and molecular assemblies are also explained. Thereafter applications of supermolecules to nanotechnology are introduced with many examples of molecular devices. The last part of the book describes biological supermolecules and their mimics. Though simply explained undergraduate and graduate students in Chemistry will be able to use aspects of this work as an advanced textbook.