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Fullerenes and nanotubes are two classes of carbon structures or allotropes, which were discovered about 17 years ago. Since that time, many chemical derivatives have been synthesized using fullerenes and nanotubes as building blocks. Particularly promising was the theory that the chemical properties of fullerenes, and certain derivatives, made them likely candidates for anticancer drugs, inhibitors of viruses such as HIV, or even as anti-bacterials. Their cyctotoxicity can also be controlled by specific circumstances. In addition, the funtionalization of nanotubes has not only produced relatively simple derivatives, but also complex hybrids with biological macromolecules, which show unique supramolecular architecture and which are promising in many medical applications. The application of fullerenes and nanotubes in medicine is at the frontier of our knowledge, thus the work in this field represents the basis for future novel developments.
Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.
In this handbook, the leading experts in the field presents important and fundamental aspects of the organic and organometallic chemistry of fullerenes. Naturally they also cover the applications in material and medicinal science for these fascinating molecules. Completely self-contained, the book is logically arranged such that information is easy to retrieve, and the style lends itself to effortless reading and to learning more about the chemical properties of this family of molecules. A definitive "must" for everyone working in this ever-expanding sphere.
Yanfei Shen and Takashi Nakanishi Exotic Self-Organized Fullerene Materials Based on Uncommon Hydrophobic–Amphiphilic Approach Yuming Zhao and Guang Chen C60 Fullerene Amphiphiles as Supramolecular Building Blocks for Organized and Well-Defined Nano scale Objects Anna Troeger, Vito Sgobba and Dirk M. Guldi Multilayer Assembly for Solar Energy Conversion Delphine Felder-Flesch Self- or Induced Organization of [60]Fullerene Hexakisadducts Andrés de la Escosura, Olga Trukhina, and Tomás Torres Dual Role of Phthalocyanines in Carbon Nano structure-Based Organic Photovoltaics Riccardo Marega, Davide Giust and Davide Bonifazi Supramolecular Chemistry of Carbon Nano tubes at Interfaces: Toward Applications Stephanie Frankenberger, Johanna A. Januszewski and Rik R. Tykwinski Oligomers from sp-Hybridized Carbon: Cumulenes and Polyynes.
The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.
The papers included in this issue of ECS Transactions were originally presented in the symposia ¿Electron Transfer and Applications of Fullerene and Nanostructured Materials, in Honor of David Schuster¿, ¿Molecular and Supramolecular Chemistry of Fullerenes and Carbon Nanotubes¿, ¿Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes¿, ¿Carbon Nanotubes and Nanostructures: Applications and Devices¿, ¿Solid-State Physics¿, ¿Porphyrins and Supramolecular Assemblies¿, and ¿Metallic and Semiconductor Nanoparticles¿, held during the 211th meeting of The Electrochemical Society, in Chicago, IL.
The papers included in this issue of ECS Transactions were originally presented in the symposia ¿Electron Transfer and Applications of Fullerene and Nanostructured Materials¿, ¿Molecular and Supramolecular Chemistry of Fullerenes and Carbon Nanotubes¿, ¿Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes¿, ¿Carbon Nanotubes and Nanostructures: Applications and Devices¿, ¿Energetics and Structure and Solid-State Physics¿, ¿Carbon Nanotubes and Nanostructures: Medicine and Biology¿, and ¿Porphyrins and Supramolecular Assemblies¿ held during the 213th meeting of The Electrochemical Society, in Phoenix, Arizona from May 18 to 23, 2008.
The seventh and eighth volumes of Handbook of Carbon Nano Materials focus on novel properties and applications of nanocarbons, viz., graphene, nanotube and fullerene. The books provide a comprehensive overview of the author's work, and significant discoveries and pioneering contributions from other groups. Specific applications cover latest developments in graphene synthesis, CVD of carbon nanomaterials, multifunctional carbon nanostructures, chemical manipulation, energy conversion and storage, nanotube micellar surface chemistry, and biosensor development. This is a highly useful book for graduate students, as well as beginning and senior researchers.
The fundamentals of "supramolecular chemistry" to the latest developments on the subject are covered by this book. It sets out to explain the topic in a relatively easy way. The basic concepts of molecular recognition chemistry are included. Molecules with fascinating shapes and functions such as fullerenes, carbon nanotubes, dendrimers, rotaxane, and catenane, and molecular assemblies are also explained. Thereafter applications of supermolecules to nanotechnology are introduced with many examples of molecular devices. The last part of the book describes biological supermolecules and their mimics. Though simply explained undergraduate and graduate students in Chemistry will be able to use aspects of this work as an advanced textbook.