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A must-have resource to the booming field of sulfur-containing polymers Sulfur-Containing Polymers is a state-of-the-art text that offers a synthesis of the various sulfur-containing polymers from low-cost sulfur resources such as elemental sulfur, carbon disulfide (CS2), carbonyl sulfide (COS) and mercaptan. With contributions from noted experts on the topic, the book presents an in-depth understanding of the mechanisms related to the synthesis of sulfur-containing polymers. The book also includes a review of the various types of sulfur-containing polymers, such as: poly(thioester)s, poly(thioether)s and poly(thiocarbonate)s and poly(thiourethane)s with linear or hyperbranched (dendrimer) architectures. The expert authors provide the fundamentals on the structure-property relationship and applications of sulfur-containing polymers. Designed to be beneficial for both research and application-oriented chemists and engineers, the book contains the most recent research and developments of sulfur-containing polymers. This important book: Offers the first comprehensive handbook on the topic Contains state-of-the-art research on synthesis of sulfur containing polymers from low-cost sulfur-containing compounds Examines the synthesis, mechanism, structure properties, and applications of various types of sulful-containing polymers Includes contributions from well-known experts Written for polymer chemists, materials scientists, chemists in industry, biochemists, and chemical engineers, Sulfur-Containing Polymers offers a groundbreaking text to the field with inforamtion on the most recent research.
This book deals with the organic chemistry of polymers which find technological use as adhesives, fibres, paints, plastics and rubbers. For the most part, only polymers which are of commercial significance are considered and the primary aim of the book is to relate theoretical aspects to industrial practice. The book is mainly intended for use by students in technical institutions and universities who are specializing in polymer science and by graduates who require an introduction to this field. Several excellent books have recently appeared dealing with the physical chemistry of polymers but the organic chemistry of polymers has not received so much attention. In recognition of this situation and because the two aspects of polymer chemistry are often taught separately, this book deals specifically with organic chemistry and topics of physical chemistry have been omitted. Also, in this way the book has been kept to a reasonable size. This is not to say that integration of the two areas of polymer science is undesirable; on the contrary, it is of the utmost importance that the inter-relationship should b~ appreciated. I wish to record my thanks to my colleagues with whom I have had many helpful discussions, particularly Mrs S. L. Radchenko. I also thank Miss E. Friesen for obtaining many books and articles on my behalf and Mr H. Harms for encouragement and assistance. I am also grateful to Mrs M. Stevens who skilfully prepared the manuscript. Department of Chemical and Metallurgical Technology, Ryerson Polytechnical Institute, K. J. S.
Approaching the material from a chemistry and engineering perspective, High Performance Polymers presents the most reliable and current data available about state-of-the-art polymerization, fabrication, and application methods of high performance industrial polymers. Chapters are arranged according to the chemical constitution of the individual classes, beginning with main chain carbon-carbon polymers and leading to ether-containing, sulfur-containing, and so on. Each chapter follows an easily readable template, provides a brief overview and history of the polymer, and continues on to such sub-topics as monomers; polymerization and fabrication; properties; fabrication methods; special additives; applications; suppliers and commercial grades; safety; and environmental impact and recycling. High Performance Polymers brings a wealth of up-to-date, high performance polymer data to you library, in a format that allows for either a fast fact-check or more detailed study. In this new edition the data has been fully updated to reflect all developments since 2008, particularly in the topics of monomers, synthesis of polymers, special polymer types, and fields of application. - Presents the state-of-the-art polymerization, fabrication and application methods of high performance industrial polymers - Provides fundamental information for practicing engineers working in industries that develop advanced applications (including electronics, automotive and medical) - Discusses environmental impact and recycling of polymers
Sulfur, Energy, and Environment is a guide to the properties of sulfur; its three important compounds; and a review of the production, use, and recovery of sulfur in relation to energy production and environmental protection. After a brief introduction to the history of sulfur, the chemical properties of the element and some important compounds are reviewed, using common analytical methods. Sulfur is a strategic chemical in many modern applications and may make headway into high-volume non-chemical uses as it is being modified according to our changing technology and needs. The sources of sulfur and where it frequently occurs is explained. This discussion is followed by citing reviews of the four most important cycles, that is, the global sulfur cycle, hydrosphere, atmospheric sulfur budget, and the anthropogenic sulfur cycle. Sulfur production methods, coal combustion chemistry, and flue gas desulfurization are then described. The many uses of sulfur are described, including in medicine, agriculture, chemical industry, and the plastic industry. However, throughout the production of sulfur, problems affecting the environment occur, so environmental control and legislation are also discussed. Finally, the trends of sulfur research, production, use and recovery, role of chemistry, and the future overall area where science, energy, chemistry, and the environment exist together are presented. Chemists and chemistry students, industrialists, and environmental planners will find this guide to sulfur helpful. Lecturers in chemistry and researchers in the many fields of application of sulfur will likewise benefit from it.
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
This book describes advances in synthesis, processing, and technology of environmentally friendly polymers generated from renewable resources. With contents based on a wide range of functional monomers and contributions from eminent researchers, this volume demonstrates the design, synthesis, properties and applications of plant oil based polymers, presenting an elaborate review of acid mediated polymerization techniques for the generation of green polymers. Chemical engineers are provided with state-of-the-art information that acts to further progress research in this direction.
The book covers silicon, phosphorus, sulfur, tin and germanium based inorganic polymers. It also includes chapters on organometallic polymers, transition metal based coordination polymers and geopolymers. The book is ideal for students and career starters in the industry.