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This book covers the latest research on porous materials at the submicron scale and inspires readers to better understand the porosity of materials, as well as to develop innovative new materials. A comprehensive range of materials are covered, including carbon-based and organic-based porous materials, porous anodic alumina, silica, and titania-based sol-gel materials. The fabrication, characterization, and applications of these materials are all explored, with applications ranging from sensors, thermoelectrics, catalysis, energy storage, to photovoltaics. Also of practical use for readers are chapters that describe the basics of porous silicon fabrication and its use in optical sensing and drug delivery applications; how thermal transport is affected in porous materials; how to model diffusion in porous materials; and a unique chapter on an innovative spectroscopic technique used to characterize materials' porosity. This is an ideal book for graduate students, researchers, and professionals who work with porous materials.
Approximately four million years of human history has passed. We have been using materials to make a variety of tools. The first materials used were naturally occurring materials such as animal bones, stones, wood etc.; and some of these familiar materials are porous. Porous materials are so familiar that they are sometimes forgotten or ignored. The taste experience of ice cream is created not only by adjusting ingre dients, but also by including air as an ingredient, i.e. pores that give the smooth texture of ice cream. This book is designed to describe and explain about pores, the synthesis of materials with pores (porous materials), and applications of porous materi als. This book is intended for engineers and scientists of different disciplines and specialities, and is expected to be useful in the design and synthesis of porous materials for existing as well as potential new applications. Let us rediscover pores. K. Ishizaki, S. Komameni and M. Nanko January 1998 1 Introduction 1.1 WHAT ARE POROUS MATERIALS? Porous materials are dermed as solids containing pores. Figure 1.1 shows different porous materials. Generally speaking, porous materials have a porosity of 0.2-0.95. The porosity means the fraction of pore volume to the total volume. Porous materials have been used in various applications from daily necessities, such as purifying drinking water by activated carbon or porous ceramics, to uses in modern industries, for example removing dusts from high purity process gases for semiconductor production.
The first comprehensive textbook on the timely and rapidly developing topic of inorganic porous materials This is the first textbook to completely cover a broad range of inorganic porous materials. It introduces the reader to the development of functional porous inorganic materials, from the synthetic zeolites in the 50’s, to today’s hybrid materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and related networks. It also provides the necessary background to understand how porous materials are organized, characterized, and applied in adsorption, catalysis, and many other domains. Additionally, the book explains characterization and application from the materials scientist viewpoint, giving the reader a practical approach on the characterization and application of the respective materials. Introduction to Inorganic Porous Materials begins by describing the basic concepts of porosity and the different types of pores, surfaces, and amorphous versus crystalline materials, before introducing readers to nature’s porous materials. It then goes on to cover everything from adsorption and catalysis to amorphous materials such as silica to inorganic carbons and Periodic Mesoporous Organosilicas (PMOs). It discusses the synthesis and applications of MOFs and the broad family of COFs. It concludes with a look at future prospects and emerging trends in the field. The only complete book of its kind to cover the wide variety of inorganic and hybrid porous materials A comprehensive reference and outstanding tool for any course on inorganic porous materials, heterogeneous catalysis, and adsorption Gives students and investigators the opportunity to learn about porous materials, how to characterize them, and understand how they can be applied in different fields Introduction to Inorganic Porous Materials is an excellent book for students and professionals of inorganic chemistry and materials science with an interest in porous materials, functional inorganic materials, heterogeneous catalysis and adsorption, and solid state characterization techniques.
In the past few decades, the increasingly routine use of advanced structural probes for studying the structure and dynamics of the solid state has led to some dramatic developments in the field of porous solids. These materials are fundamental in a diverse range of applications, such as shape-selective catalysts for energy-efficient organic transformations, new media for pollutant removal, and gas storage materials for energy technologies. Porosity in inorganic materials may range from the nano-scale to the macro-scale, and the drive towards particular properties remains the goal in this fast-developing area of research. Covering some of the key families of inorganic solids that are currently being studied, Porous Materials discusses: Metal Organic Frameworks Materials Mesoporous Silicates Ordered Porous Crystalline Transition Metal Oxides Recent Developments in Templated Porous Carbon Materials Synthetic Silicate Zeolites: Diverse Materials Accessible Through Geoinspiration Additional volumes in the Inorganic Materials Series: Low-Dimensional Solids | Molecular Materials | Functional Oxides | Energy Materials
This book provides a comprehensive and concise description of most important aspects of experimental and theoretical investigations of porous materials and powders, with the use and application of these materials in different fields of science, technology, national economy and environment. It allows the reader to understand the basic regularities of heat and mass transfer and adsorption occurring in qualitatively different porous materials and products, and allows the reader to optimize the functional properties of porous and powdered products and materials. Written in an straightforward and transparent manner, this book is accessible to both experts and those without specialist knowledge, and it is further elucidated by drawings, schemes and photographs. Porous materials and powders with different pore sizes are used in many areas of industry, geology, agriculture and science. These areas include (i) a variety of devices and supplies; (ii) thermal insulation and building materials; (iii) oil-bearing geological, gas-bearing and water-bearing rocks; and (iv) biological objects. Structural Properties of Porous Materials and Powders Used in Different Fields of Science and Technology is intended for a wide-ranging audience specializing in different fields of science and engineering including engineers, geologists, geophysicists, oil and gas producers, agronomists, physiologists, pharmacists, researchers, teachers and students.
This four-volume handbook gives a state-of-the-art overview of porous materials, from synthesis and characterization and simulation all the way to manufacturing and industrial applications. The editors, coming from academia and industry, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 37 expert authors in 14 chapters, they construct the story of porous carbons, ceramics, zeolites and polymers from varied viewpoints: surface and colloidal science, materials science, chemical engineering, and energy engineering. Volumes 1 and 2 cover the fundamentals of preparation, characterisation, and simulation of porous materials. Working from the fundamentals all the way to the practicalities of industrial production processes, the subjects include hierarchical materials, in situ and operando characterisation using NMR, X-Ray scattering and tomography, state-of-the-art molecular simulations of adsorption and diffusion in crystalline nanoporous materials, as well as the emerging areas of bio-artificing and drug delivery. Volume 3 focuses on porous materials in industrial separation applications, including adsorption separation, membrane separation, and osmotic distillation. Finally, and highly relevant to tomorrow's energy challenges, Volume 4 explains the energy engineering aspects of applying porous materials in supercapacitors, fuel cells, batteries, electrolysers and sub-surface energy applications.The text contains many high-quality colourful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with porous materials.Related Link(s)
This book is written in honor of Prof. Francisco Rodriguez-Reinoso, who has made significant contributions in the area of porous materials such as active carbons and graphenes. It details the preparation of porous materials, including carbonaceous, zeolitic, and siliceous materials, MOFs, aerogels, and xerogels, describing the characterization techniques and the interpretation of the results, and highlighting common errors that can occur during the process. This book subsequently presents the use of modeling based on thermodynamics to describe the materials. Lastly, it illustrates a number of current environmental protection applications in the context of both water and air.
This thesis focuses on porous monolithic materials that are not in the forms of particles, fibers, or films. In particular, the synthetic strategy of porous monolithic materials via the sol–gel method accompanied by phase separation, which is characterized as the non-templating method for tailoring well-defined macropores, is described from the basics to actual synthesis. Porous materials are attracting more and more attention in various fields such as electronics, energy storage, catalysis, sensing, adsorbents, biomedical science, and separation science. To date, many efforts have been made to synthesize porous materials in various chemical compositions—organics, inorganics including metals, glasses and ceramics, and organic-inorganic hybrids. Also demonstrated in this thesis are the potential applications of synthesized porous monolithic materials to separation media as well as to electrodes for electric double-layer capacitors (EDLCs) and Li-ion batteries (LIBs). This work is ideal for graduate students in materials science and is also useful to engineers or scientists seeking basic knowledge of porous monolithic materials.
Porous media exist in different modern materials. It presents great surface areas with small pore size distribution. These types of materials with controllable and adjustable pore diameters are given considerable attention due to their suitable properties and applications in several fields. Porous materials have many applications in our daily life. We use different types of porous materials to clean our drinking water, for instance. This new research-oriented volume focuses on exploring the wide range of porous materials. In this new volume, original contributions from international authors along with case studies on the synthesis, design, characterization, and applications of different types of porous materials and solids are presented in detail. The book covers different types of porous materials in the broad sense by considering experimental and theoretical aspects of materials science related to porous materials and solids. The book aims to help approach characterizing a particular types of materials for more in-depth analysis. This book is divided into three parts to determine the best techniques for solving particular porous materials problems, and in each part, the fabrication and characterization of porous materials are explored with applications, describing new methodologies to gain the required information along with limitations of various methods. To make this new title a practical reference book for research students and for engineers and scientists of different disciplines working with porous materials and solids, the editors have selected a very comprehensive range of case studies as well, designed to cover the basic concepts of porosity. These case studies also describe different types of pores and surfaces for readers.
The development of porous materials has attracted the attention of the research community for years. Porosity characteristics have specific impacts on the material properties and materials that are applied in many areas, such as pollutant removal, CO2 capture, energy storage, catalytic oxidation and reduction processes, the conversion of biomass to biofuels, and drug delivery. Examples of porous materials are activated carbons, clays, and zeolites. The aim of this book is to collect the recent advances and progress regarding porous materials and their applications in the environmental area.