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There is considerable interest in the intrinsically multiscale structure and dynamics of complex electronic oxides, especially since these materials include those of technological importance, such as colossal magnetoresistance manganites and cuprate high temperature superconductors. Current microscopies, such as diffuse X-ray and inelastic neutron scattering, electromagnetic and acoustic response, NMR and scanning tunneling microscope probes, have revealed static and dynamic multiscale patterns in charge positioning, lattice structure and magnetic orientation, that respond to both external stress and magnetic field. These self-organized patterns include charge and orbital ordering; stripes in strain/spin; and labyrinth-like conductance modulations. The materials exhibit nanoscale phase segregation and mesoscale inhomogeneous clustering, and their phase transitions can have a percolative character.This volume presents experimental and theoretical work on these exciting new developments in condensed matter physics and materials science.
Proceedings of the Baroda Workshop on Nanomaterials, Magnetic Ions and Magnetic Semiconductors studied mostly by Hyperfine Interactions (IWNMS 2004), held in Baroda, India, 10-14 February, 2004. Researchers and graduate students interested in the application of hyperfine interaction techniques, mostly Mössbauer Effect and Perturbed Angular Correlations, to the fast developing fields of magnetic nanomaterials, magnetic ions and magnetic semiconductors will find this volume indispensable. The volume also addresses to the application of synchrotron radiation and ion beams to these systems.
Phase separation has become a fascinating subject in the discussion of cuprate superconductors. All these materials have layered structures containing CU02 planes as the most important building blocks. They are coupled only weakly so that the electronic properties show a nearly two-dimensional behaviour. Due to correlations the undoped compounds are insulators of the Mott Hubbard type exhibiting long-range antiferromagnetic order. Upon doping a rich scenario of physical phenomena appears: Even at low hole concentra tions the antiferromagnetic ordering temperature is reduced drastically and spin-glass behaviour as well as a hopping type conductivity can be observed. Further doping leads to metallic-like conductivity and below Tc to super conductivity. In this doping regime antiferromagnetic fluctuations are still observed. At very high charge carrier densities superconductivity is lost and the systems show pure metallic conduction without ,magnetic correlations. One of the most interesting phenomena in high-T c research is the interplay between magnetism and conductivity or superconductivity. Especially the behaviour of charge carriers in the antiferromagnetic background raises a number of open questions. Two scenarios become possible: the carriers tend to delocalize over the whole crystal forming a homogeneous state with band-like structure or they separate into hole-rich (conducting, superconducting) and hole-poor (insulating, antiferromagnetic) phases leading to an inhomogeneous structure.
This book highlights the achievements of the self-taught inventor, scientist, manufacturer and entrepreneur, Stanford R Ovshinsky. This remarkable individual could, without special training, compete with the well-funded establishments of learning and industry in the second half of the last century and leave us an incredible legacy of brilliant innovations with a lasting impact on our lives. His achievements extend over amazingly diverse fields and have or are prone to create new industries of great societal value.The phase change memories of commonly used rewritable CDs and DVDs as well as of new flash memories are his invention; so are the Ni Metal hydride batteries which are the enabling batteries for electric and hybrid/electric vehicles. The future hydrogen economy will utilize his efficient and safe hydrogen storage alloys. He has developed light and ultralight photovoltaic solar panels for converting sunlight into electricity and built the largest manufacturing facility for thin film flexible solar roofing materials. A common theme of his inventions is the synthesis of new materials utilizing novel aspects of structural and compositional disorder.The book explains for each of Ovshinsky''s innovations the essence of his pioneering ideas and inventions. These introductions are followed by a selection of Ovshinsky''s seminal publications and, for each subject category, a list of his patents which reveal the inventive mind of this unusually creative person. Ovshinsky''s example of gaining a deep understanding of the science underlying his inventions, his perseverance as well as his ability to attract and inspire talented collaborators will be a role model for entrepreneurs of this century.
The Advanced Study Institute on Synthesis, Functional Properties and Applications of Nanostructures, held at the Knossos Royal Village, Heraklion, Crete, Greece, July 26, 2002 - August 4, 2002, successfully reviewed the state-of-the-art of nanostructures and nanotechnology. It was concluded that Nanotechnology is widely agreed to be the research focus that will lead to the next generation of breakthroughs in science and engineering. There are three cornerstones to the expectation that Nanotechnology will yield revolutionary advances in understanding and application: • Breakthroughs in properties that arise from materials fabricated from the nanoscale. • Synergistic behavior that arise from the combination of disparate types of materials (soft vs. hard, organic vs. inorganic, chemical vs. biological vs. solid state) at the nanoscale. • Exploitation of natural (e.g. chemical and biological) assembly mechanisms that can accomplish structural control at the nanoscale. It is expected that this will lead to paradigms for assembling bio-inspired functional systems that accomplish desirable properties that are either unavailable or prohibitively expensive using top-down approaches.
Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc./a
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Ferroelectric materials have been and still are widely used in many applications, that have moved from sonar towards breakthrough technologies such as memories or optical devices. This book is a part of a four volume collection (covering material aspects, physical effects, characterization and modeling, and applications) and focuses on the characterization of ferroelectric materials, including structural, electrical and multiphysic aspects, as well as innovative techniques for modeling and predicting the performance of these devices using phenomenological approaches and nonlinear methods. Hence, the aim of this book is to provide an up-to-date review of recent scientific findings and recent advances in the field of ferroelectric system characterization and modeling, allowing a deep understanding of ferroelectricity.
During the last two decades, remarkable and often spectacularprogress has been made in the methodological and instrumentalaspects of x–ray absorption and emission spectroscopy. Thisprogress includes considerable technological improvements in thedesign and production of detectors especially with the developmentand expansion of large-scale synchrotron reactors All this hasresulted in improved analytical performance and new applications,as well as in the perspective of a dramatic enhancement in thepotential of x–ray based analysis techniques for the nearfuture. This comprehensive two-volume treatise features articlesthat explain the phenomena and describe examples of X–rayabsorption and emission applications in several fields, includingchemistry, biochemistry, catalysis, amorphous and liquid systems,synchrotron radiation, and surface phenomena. Contributors explainthe underlying theory, how to set up X–ray absorptionexperiments, and how to analyze the details of the resultingspectra. X-Ray Absorption and X-ray Emission Spectroscopy: Theory andApplications: Combines the theory, instrumentation and applications of x-rayabsorption and emission spectroscopies which offer uniquediagnostics to study almost any object in the Universe. Is the go-to reference book in the subject for all researchersacross multi-disciplines since intense beams from modern sourceshave revolutionized x-ray science in recent years Is relevant to students, postdocurates and researchers workingon x-rays and related synchrotron sources and applications inmaterials, physics, medicine, environment/geology, andbiomedical materials