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Based on a highly successful PPI advanced technical course given by the author, this book combines the applied and fundamental aspects of reactive extrusion.
Developments in machinery, materials and applications are outlined in the cond104 of commercial considerations and advances in fundamental understanding. The principles and benefits of polymer modification and blending via reactive extrusion are explained. A b257 of novel techniques which have developed out of the major reactive processes are also described. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
This volume covers advanced polymer processing operations and is designed to provide a description of some of the latest industry developments for unique products and fabrication methods. Contributors for this volume are from both industry and academia from the international community. This book contains nine chapters covering advanced processing applications and technologies.
Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.
Experts in rheology and polymer processing present up-to-date, fundamental and applied information on the rheological properties of polymers, in particular those relevant to processing, contributing to the physical understanding and the mathematical modelling of polymer processing sequences. Basic concepts of non-Newtonian fluid mechanics, micro-rheological modelling and constitutive modelling are reviewed, and rheological measurements are described. Topics with practical relevance are debated, such as linear viscoelasticity, converging and diverging flows, and the rheology of multiphase systems. Approximation methods are discussed for the computer modelling of polymer melt flow. Subsequently, polymer processing technologies are studied from both simulation and engineering perspectives. Mixing, crystallization and reactive processing aspects are also included. Audience: An integrated and complete view of polymer processing and rheology, important to institutions and individuals engaged in the characterisation, testing, compounding, modification and processing of polymeric materials. Can also support academic polymer processing engineering programs.
This study shows the impact resistance of polypropylene toughened by an ethylene-propylene elastomer. The objective was to modify polystyrene with linear thermoplastic elastomer of styrene-isoprene-styrene triblock copolymer and polystyrene with ethylene-propylene rubber by weight by melt blending.
The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process—these in turn cause changes in performance and properties. Material selection and control of the reaction are essential to acheive optimal performance. The second edition of Reactive Polymers Fundamentals and Applications introduces engineers and scientists to the range of reactive polymers available, explains the reactions that take place, and details applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, and applications and uses. The initial chapters are devoted to individual resin types (e.g. epoxides, cyanacrylates, etc.); followed by more general chapters on topics such as reactive extrusion and dental applications. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers, and case studies. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are all covered as well. - Most comprehensive source of information about reactive polymers - Covers basics as well as most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites, and fluorosilicones - Indispensable guide for engineers and advanced students alike—providing extensive literature and patent review
In recent years, much attention has been focused on biodegradable polymers from renewable resources. Due to its availability and low cost, starch is a promising candidate among biopolymers for use in biodegradable packaging materials and for other purposes. Starch-Based Polymeric Materials and Nanocomposites: Chemistry, Processing, and Applications presents the latest developments in starch chemistry, rheology, starch derivatives, starch-based nanocomposites, and their applications. Topics discussed include: The chemistry, microstructure, processing, and enzymatic degradation of starch The importance and role of starch as a gelling agent Plasticization and the role of plasticizers Various rheological techniques applied to starch-related products and the characteristics of starch dispersions Polymeric aspects of reactive extrusion (REX) and its use on starch and other biopolymers Cyclodextrins (CDs) and their industrial applications, and CD-based supramole and polymers The potential of starch in food packaging, edible packaging, feedstock for bioproducts, and industrial and consumer products The theoretical basis and derivation of the mathematical model for multicomponent systems and its solution algorithm The book also explores recent progress in biodegradable starch-based hybrids and nanomaterials and the incorporation of nanoparticles in starches to enhance their mechanical and thermal properties. The book concludes by discussing the use of biopolymeric nanoparticles (BNPs) in drug delivery and life cycle assessment (LCA) of starch-based polymeric materials for packaging and allied applications. With contributions from leading experts in academia and industry, this volume demonstrates the versatility of starch and its potential in a variety of applications.
Distinguishing among blends, alloys and other types of combinations, clarifying terminology and presenting data on new processes and materials, this work present up-to-date and effective compounding techniques for polymers. It offers extensive analyses on the challenging questions that surround miscibility, compatibility, dynamic processing, interaction/phase behaviour, and computer simulations for predicting behaviours of polymer mixture and interaction.