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Rubber elasticity is an important sub-field of polymer science. This book is in many ways a sequel to the authors' previous, more introductory book, Rubberlike Elasticity: A Molecular Primer (Wiley-Interscience, 1988), and will in some respects replace the now classic book by L.R.G. Treloar, The Physics of Rubber Elasticity (Oxford, 1975). The present book has much in common with its predecessor, in particular its strong emphasis on molecular concepts and theories. Similarly, only equilibrium properties are covered in any detail. Though this book treats much of the same subject matter, it is a more comprehensive, more up-to-date, and somewhat more sophisticated treatment.
The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.
An Updated Edition of the Classic Text Polymers constitute the basis for the plastics, rubber, adhesives, fiber, and coating industries. The Fourth Edition of Introduction to Physical Polymer Science acknowledges the industrial success of polymers and the advancements made in the field while continuing to deliver the comprehensive introduction to polymer science that made its predecessors classic texts. The Fourth Edition continues its coverage of amorphous and crystalline materials, glass transitions, rubber elasticity, and mechanical behavior, and offers updated discussions of polymer blends, composites, and interfaces, as well as such basics as molecular weight determination. Thus, interrelationships among molecular structure, morphology, and mechanical behavior of polymers continue to provide much of the value of the book. Newly introduced topics include: Nanocomposites, including carbon nanotubes and exfoliated montmorillonite clays The structure, motions, and functions of DNA and proteins, as well as the interfaces of polymeric biomaterials with living organisms The glass transition behavior of nano-thin plastic films In addition, new sections have been included on fire retardancy, friction and wear, optical tweezers, and more. Introduction to Physical Polymer Science, Fourth Edition provides both an essential introduction to the field as well as an entry point to the latest research and developments in polymer science and engineering, making it an indispensable text for chemistry, chemical engineering, materials science and engineering, and polymer science and engineering students and professionals.
This book focuses on characterization of organic coatings by different testing methods and understanding of structure formation and materials properties. The knowledge of protective organic coatings and current test methods is based largely on empirical experience. This book aims at explaining the coating property changes during film drying and curing in terms of chemical and physical transformations. Current test methods are reviewed with emphasis on understanding their physical basis and expressing the test results in terms of comparable physical quantities. In general, this book provides readers a deeper understanding of the binder design, coating film formation process, properties build-up, appearance and defect formation, and automotive paint application. It also suggests manifold ways to improving the coatings performance. This book is designed for coating professionals to gain deeper understanding of characterization techniques and to select the right ones to solve their coating problems. It is ideal for both experienced and early career scientists and engineers. Also, it is useful for graduate students in the general area of protective coatings.
Chemistry, Manufacture and Applications of Natural Rubber, Second Edition presents the latest advances in the processing, properties and advanced applications of natural rubber (NR), drawing on state-of-the-art research in the field. Chapters cover manufacturing, processing and properties of natural rubber, describing biosynthesis, vulcanization for improved performance, strain-induced crystallization, self-reinforcement, rheology and mechanochemistry for processing, computer simulation of properties, scattering techniques and stabilizing agents. Applications covered include natural rubber, carbon allotropes, eco-friendly soft bio-composites using NR matrices and marine products, the use of NR for high functionality such as shape memory, NR for the tire industry, and natural rubber latex with advanced applications. This is an essential resource for academic researchers, scientists and (post)graduate students in rubber science, polymer science, materials science and engineering, and chemistry. In industry, this book enables professionals, R&D, and producers across the natural rubber, tire, rubber and elastomer industries, as well as across industries looking to use natural rubber products, to understand and utilize natural rubber for cutting-edge applications. - Explains the latest manufacture and processing techniques for natural rubber (NR) with enhanced properties - Explores novel applications of natural rubber across a range of industries, including current and potential uses - Discusses resources and utilization, and considers sustainable future development of natural rubber
Due to their unique properties, rubber materials are found in multiple engineering applications such as tires, engine mounts, shock absorbers, flexible joints, seals, etc. Nevertheless, the complex nature of the behavior of such material makes it difficult to accurately model and predict the performance of these units. The challenge to correctly reproduce the observed characteristics of rubber elements necessitates detailed experimental investigations, development of accurate constitutive models, validation of techniques to identify material parameters and efficient numerical methods. Aspects regarding fatigue and damage in elastomers are not to be left aside, as they influence the durability of the products. State-of-the-art technology in terms of constitutive modeling, numerical implementation, damage and fatigue resistance are strongly represented in these Proceedings, along with insights into advanced elastomers to be used in novel applications. Topics included in this volume are: Ageing, Friction and abrasion, Adhesion, Swelling, Continuum mechanical models and numerical implementation, Hyperelasticity, Micro-mechanical approaches, Fracture and fatigue, Mullins effect, Strain induced crystallization, Thermal effects, Reinforcement and vulcanization, Design and applications, Smart elastomers. Constitutive Models for Rubber VIII is of interest not only for undergraduates, postgraduates, academics and researchers in the discipline, but also for all those design and development engineers in the industry.
This cutting-edge reference clearly explains pharmaceutical transport phenomena, demonstrating applications ranging from drug or nutrient uptake into vesicle or cell suspensions, drug dissolution and absorption across biological membranes, whole body kinetics, and drug release from polymer reservoirs and matrices to heat and mass transport in freeze-drying and hygroscopicity. Focuses on practical applications of drug delivery from a physical and mechanistic perspective, highlighting biological systems. Written by more than 30 international authorities in the field, Transport Processes in Pharmaceutical Systems discusses the crucial relationship between the transport process and thermodynamic factors analyzes the dynamics of diffusion at liquid-liquid, liquid-solid, and liquid-cultured cell interfaces covers prodrug design for improving membrane transport addresses the effects of external stimuli in altering some natural and synthetic polymer matrices examines properties of hydrogels, including synthesis, swelling degree, swelling kinetics, permeability, biocompatibility, and biodegradability presents mass transfer of drugs and pharmacokinetics based on mass balance descriptions and more! Containing over 1000 references and more than 1100 equations, drawings, photographs, micrographs, and tables, Transport Processes in Pharmaceutical Systems is a must-read resource for research pharmacists, pharmaceutical scientists and chemists, chemical engineers, physical chemists, and upper-level undergraduate and graduate students in these disciplines.
Written by expert contributors from the academic and industrial sectors, this book presents traditional and modern approaches to polymer characterization and analysis. The emphasis is on pragmatics, problem solving and property determination; real-world applications provide a context for key concepts. The characterizations focus on organic polymer and polymer product microstructure and composition. - Approaches molecular characterization and analysis of polymers from the viewpoint of problem-solving and polymer property characterization, rather than from a technique championing approach - Focuses on providing a means to ascertaining the optimum approach or technique(s) to solve a problem/measure a property, and thereby develop an analytical competence in the molecular characterization and analysis of real-world polymer products - Provides background on polymer chemistry and microstructure, discussions of polymer chain, morphology, degradation, and product failure and additive analysis, and considers the supporting roles of modeling and high-throughput analysis
Elastomers and rubberlike materials form a critical component in diverse applications that range from tyres to biomimetics and are used in chemical, biomedical, mechanical and electrical engineering. This updated and expanded edition provides an elementary introduction to the physical and molecular concepts governing elastic behaviour, with a particular focus on elastomers. The coverage of fundamental principles has been greatly extended and fully revised, with analogies to more familiar systems such as gases, producing an engaging approach to these phenomena. Dedicated chapters on novel uses of elastomers, covering bioelastomers, filled elastomers and liquid crystalline elastomers, illustrate the established and emerging applications at the forefront of physical science. With a list of experiments and demonstrations, problem sets and solutions, this is a self-contained introduction to the topic for graduate students, researchers and industrialists working in the applied fields of physics and chemistry, polymer science and engineering.
The unique properties of elastomeric materials offer numerous advantages in many engineering applications. Elastomeric units are used as couplings or mountings between rigid components, for example in shock absorbers, vibration insulators, flexible joints, seals and suspensions, etc. However, the complicated nature of the behaviour of such material makes it difficult to accurately predict the performance of these units using finite element modelling, for example. It is imperative that constitutive models accurately capture relevant aspects of mechanical behaviour. The latest developments concerning constitutive modelling of rubber is collected in these Proceedings. Topics included in this volume are, Hyperelastic models, Strength, fracture & fatigue, Dynamic properties & the Fletcher-Gent effect, Micro-mechanical & statistical approaches, Stress softening, iscoelasticity, Filler reinforcement, and Tyres, fibre & cord reinforced rubber.