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This book deals with one of the most attractive fields in material science and technology research. In fact, the concept of organic–inorganic hybrid materials is applied to a wide variety of approaches that include materials with inorganic and/or organic nature with respect to their matrices and/or dispersed phase. The present book compiles one editorial and eleven approaches to the topic, and intends to provide a transversal idea about what the field of the so-called organic–inorganic hybrid materials means in actual scientific scenarios. In any case, the role is pointed out of the interphase between the components as the critical aspect to consider, as a way to enhance and understand these components in order to design materials with "tailor-made" organized structures considering the increasing nano-, meso-, micro- and macro-scales.
This completely updated and expanded second edition stands as a comprehensive knowledgebase on both the fundamentals and applications of this important materials processing method. The diverse, international team of contributing authors of this reference clarify in extensive detail properties and applications of sol-gel science and technology as it pertains to the production of substances, active and non-active, including optical, electronic, chemical, sensor, bio- and structural materials. Essential to a wide range of manufacturing industries, the compilation divides into the three complementary sections: Sol-Gel Processing, devoted to general aspects of processing and recently developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, and photocatalysts; Characterization of Sol-Gel Materials and Products, presenting contributions that highlight the notion that useful materials are only produced when characterization is tied to processing, such as determination of structure by NMR, in-situ characterization of the sol-gel reaction process, determination of microstructure of oxide gels, characterization of porous structure of gels by the surface measurements, and characterization of organic-inorganic hybrid; and Applications of Sol-Gel Technology, covering applications such as the sol-gel method used in processing of bulk silica glasses, bulk porous gels prepared by sol-gel method, application of sol-gel method to fabrication of glass and ceramic fibers, reflective and antireflective coating films, application of sol-gel method to formation of photocatalytic coating films, and application of sol-gel method to bioactive coating films. The comprehensive scope and integrated treatment of topics make this reference volume ideal for R&D scientists and engineers across a wide range of disciplines and professional interests.
Sol-Gel processing methods, first used historically for decorative and constructional materials, were extensively developed in the last century for applications such as glasses, ceramics, catalysts, coatings, composites and fibres. Today they are reaching their full potential, enabling the preparation of new generations of advanced materials not easily accessible by other methods yet using mild, low-energy conditions. The topic is therefore increasingly included in advanced undergraduate, MSc and PhD programmes in the areas of chemistry, physics and materials science. This concise introductory text, written at the advanced undergraduate/first-year postgraduate level, is also suitable as an introduction to the development, mechanisms, chemistry, characterisation methods and applications of the technique. It provides readers with an extensive yet concise grounding in the theory of each area of the subject and details the real and potential applications and the future prospects of sol-gel chemistry.
Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others
This book on solid state chemistry presents studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids. Research areas include: bonding in solids, crystal chemistry, crystal growth mechanisms, diffusion epitaxy, high-pressure processes, magnetic properties of materials, optical characterisation of materials, order-disorder, phase equilibria and transformation mechanisms, reactions at surfaces, statistical mechanics of defect interactions, structural studies and transport phenomena.
Sol-Gel Techniques for Glass Producers and Users provides technological information, descriptions and characterizations of prototypes, or products already on the market, and illustrates advantages and disadvantages of the sol-gel process in comparison to other methods. The first chapter entitled "Wet Chemical Technology" gives a summary of the basic principles of the sol-gel chemistry. The most promising applications are related to coatings. Chapter 2 describes the various "Wet Chemical Coating Technologies" from glass cleaning to many deposition and post-coating treatment techniques. These include patterning of coatings through direct or indirect techniques which have became very important and for which the sol-gel processing is particularly well adapted. Chapter 3 entitled "Bulk Glass Technologies" reports on the preparation of special glasses for different applications. Chapter 4 entitled "Coatings and Materials Properties" describes the properties of the different coatings and the sol-gel materials, fibers and powders. The chapter also includes a section dedicated to the characterization techniques especially applied to sol-gel coatings and products.
A comprehensive and up-to-date overview of the major mineral and organic fillers for plastics, their production, structure and properties, as well as their applications in terms of primary and secondary functions. Edited and co-authored by Professor Marino Xanthos with contributions by international experts from industry and academia, this book presents methods of mixing/incorporation technologies, surface treatments and modifications for enhanced functionality, an analysis of parameters affecting filler performance and a presentation of current and emerging applications. Additionally, the novel classification according to modification of specific polymer properties rather than filler chemical composition provides a better understanding of the relationships between processing, structure and properties of products containing functional fillers and the identification of new markets and applications. For engineers, scientists and technologists involved in the important sector of polymer composites.
This book covers the latest advances in polymer-inorganic nanocomposites, with particular focus on high-added-value applications in fields including electronics, optics, magnetism and biotechnology. The unique focus of this book is on electronic, optical, magnetic and biomedical applications of hybrid nanocomposites. Coverage includes: Synthesis methods and issues and production scale-up; Characterization methods; Electronic applications; Optical applications and Photonics; Magnetic applications; and Biomedical applications. The book offers readers a solid grasp of the state of the art, and of current challenges in non-traditional applications of hybrid nanocomposites.