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This book is designed to critically review experimental findings on ionic polymers and colloidal particles and to prove a theoretical framework based on the Poisson-Boltzmann approach. Structure formation in ionic polymer solutions has attracted attention since the days of H. Staudinger and J. D. Bernal. An independent study on ionic colloidal dispersions with microscopy provided a compelling evidence of structure formation. Recent technical developments have made it possible to accumulate relevant information for both ionic polymers and colloidal particles in dilute systems. The outstanding phenomenon experimentally found is microscopic inhomogeneity in the solute distribution in macroscopically homogeneous systems.To account for the observation, the present authors have invoked the existence of the counterion-mediated attraction between similarly charged solute species, in addition to the widely accepted electrostatic repulsion.
The formation and evolution of complex dynamical structures is one of the most exciting areas of nonlinear physics. Such pattern formation problems are common in practically all systems involving a large number of interacting components. Here, the basic problem is to understand how competing physical forces can shape stable geometries and to explain why nature prefers just these. Motivation for the intensive study of pattern formation phenomena during the past few years derives from an increasing appreciation of the remarkable diversity of behaviour encountered in nonlinear systems and of universal features shared by entire classes of nonlinear processes. As physics copes with ever more ambi tious problems in pattern formation, summarizing our present state of knowledge becomes a pressing issue. This volume presents an overview of selected topics in this field of current interest. It deals with theoretical models of pattern formation and with simulations that bridge the gap between theory and experiment. The book is a product of the International Symposium on the Physics of Structure Formation, held from October 27 through November 2, 1986, at the Institute for Information Sciences of the University of Tiibingen. The symposium brought together a group of distinguished scientists from various disciplines to exchange ideas about recent advances in pattern formation in the physical sciences, and also to introduce young scientists to the fi
The book presents Russian experience in researching and developing theoretical and experimental problems of heavy concrete elements and constructions with functionally gradient structure, manufactured by using mechanical and electromagnetic vibrations, and broadly utilized in different areas of industry. Original theoretical, experimental and numerical methods are developed for the analysis and design of the aggregate and local characteristics of vibrated, centrifuged and vibro-centrifuged concrete rings and columns. The promising experimental techniques and results presented in this volume have been supported by Russian patents and used for improvement of reinforced concrete products.
This thesis presents studies on the interaction of soft materials like surfactants and proteins with hard silica nanomaterials. Due to its interdisciplinary nature it combines concepts from the fields of physical chemistry, nanoscience and materials science, yielding to fundamental insights into the structure-directing forces operating at the nano-scale. It is shown that the morphology of surfactant micellar aggregates adsorbed at the surface of nanoparticles and inside tubular nanopores can be tuned on demand by the co-adsorption of a surface modifier. The interaction of globular proteins with silica nanoparticles is dominated by electrostatic interactions and can be controlled by pH and ionic strength, while the bridging of nanoparticles by adsorbed protein molecules leads to large-scale hybrid aggregates of protein with the nanoparticles. Concepts emerging from the role of electrostatic interactions in the hetero-aggregation of nanoparticles with protein molecules are used for the co-assembly of charged microbeads into linear clusters and chains of controllable length.
The book contains methodology for evaluating formation processes for multi-component systems based on the understanding of spatial-energy parameter, as well as vast computation and informative material.
Polymeric Membrane Formation by Phase Inversion brings together for the first time analysis of all the four main phase inversion techniques. Effective parameters in each technique are covered together with the methodologies needed to prepare advanced membranes for specific separations in both liquid and gas phases. Roll-to-roll casting, spinning hollow fiber, and electrospinning nanofibers are presented, along with an analysis of the impact of solvent toxicity, membrane production, and the source of raw materials on the environment. Describing a road map for designing different morphological characteristics to prepare specific membranes for special applications, the merits and disadvantages of each method are thoroughly explored and outlined along with the sustainability, scalability and economic perspectives of membrane formation. Providing easy reference for academic and industry professionals working in membrane engineering this is an essential resource. - Analyzes membrane formation by phase inversion and modeling - Includes state-of-the-art membrane formation methods and related characterization techniques - Discusses solvent toxicity and sustainability issues of membrane production
First Published in 2018. Routledge is an imprint of Taylor & Francis, an Informa company.
Nanocomposite Structures and Dispersions deals with the preparation of gelled, branched and crosslinked nanostructured polymers in the solution free radical polymerization and controlled/living radical polymerization and polymer and composite nanoparticles and nanostructures in disperse systems, the kinetics of direct and inverse disperse polymerizations (microemulsion, miniemulsion, emulsion, dispersion and suspension polymerization), the bottom-up approach building of functionalized nanoparticles, modelling of radical microemulsion polymerization, the characterization of traditional and non-traditional polymer dispersions, the collective properties of nanomaterials and their (bio)applications.This book is designed to bridge that gap and offers several unique features. First, it is written as an introduction to and survey of nanomaterials with a careful balance between basics and advanced topics. Thus, it is suitable for both beginners and experts, including graduate and upper-level undergraduate students. Second, it strives to balance the colloidal aspects of nanomaterials with physical principles. Third, the book highlights nanomaterial based architectures including composite or hybrid conjugates rather than only isolated nanoparticles. A number of ligands have been utilized to biodecorate the polymer and composite nanocarriers. Finally, the book provides an in depth discussion of important examples of reaction mechanisms of bottom-up building of functionalized nanoparticles, or potential applications of nanoarchitectures, ranging from physical to chemical and biological systems. - Free radical (controlled) polymerization, branching, crosslinking and gelling - Kinetics and mechanism of polymer nanoparticles formation - Modelling of radical polymerization in disperse systems - Polymer, composite and metal nanoparticles, nanostructures and nanomaterials - Smart nanostructures, biodecorated particles, nanocarriers and therapeutics
Delineating the huge strides taken in cosmology in the past ten years, this much-anticipated second edition of Malcolm Longair's highly appreciated textbook has been extensively and thoroughly updated. It tells the story of modern astrophysical cosmology from the perspective of one of its most important and fundamental problems – how did the galaxies come about? Longair uses this approach to introduce the whole of what may be called "classical cosmology". What’s more, he describes how the study of the origin of galaxies and larger-scale structures in the Universe has provided us with direct information about the physics of the very early Universe.